- Oil spill
An oil spill is the release of a liquid petroleum hydrocarbon into the environment, especially marine areas, due to human activity, and is a form of pollution. The term is mostly used to describe marine oil spills, where oil is released into the ocean or coastal waters. Oil spills may be due to releases of crude oil from tankers, offshore platforms, drilling rigs and wells, as well as spills of refined petroleum products (such as gasoline, diesel) and their by-products, heavier fuels used by large ships such as bunker fuel, or the spill of any oily refuse or waste oil. Another significant route by which oil enters the marine environment is through natural oil seeps.
Oil spills can be controlled by chemical dispersion, combustion, mechanical containment, and/or adsorption. Spills may take weeks, months or even years to clean up.
The oil penetrates into the structure of the plumage of birds and animals, reducing its insulating ability, thus making the birds more vulnerable to temperature fluctuations and much less buoyant in the water. It also impairs or disables birds' flight abilities to forage and escape from predators. As they attempt to preen, birds typically ingest oil that covers their feathers, causing kidney damage, altered liver function, and digestive tract irritation. This and the limited foraging ability quickly causes dehydration and metabolic imbalances. Hormonal balance alteration including changes in luteinizing protein can also result in some birds exposed to petroleum.
Most birds affected by an oil spill die unless there is human intervention. Some studies have suggested that, even after cleaning, less than 1% of oil soaked birds survive., though it can also exceed 90% as in the case of the Treasure oil spill. Heavily furred marine mammals exposed to oil spills are affected in similar ways as seabirds. Oil coats the fur of Sea otters and seals, reducing its insulation abilities and leading to body temperature fluctuations and hypothermia. Ingestion of the oil causes dehydration and impaired digestions. Because oil floats on top of water, less sunlight penetrates into the water, limiting the photosynthesis of marine plants and phytoplankton. This, as well as decreasing the fauna populations, affects the food chain in the ecosystem. There are three kinds of oil-consuming bacteria. Sulfate-reducing bacteria (SRB) and acid-producing bacteria are anaerobic, while general aerobic bacteria (GAB) are aerobic. These bacteria occur naturally and will act to remove oil from an ecosystem, and their biomass will tend to replace other populations in the food chain. Oil may also cause the death of an animal by entering the animal’s lungs or liver. The animal will then be poisoned by the oil. Oil also can kill an animal by blinding it. The animal will not be able to see and be aware of their predators. If they are not aware of other animals, they may be eaten.
Cleanup and recovery
Cleanup and recovery from an oil spill is difficult and depends upon many factors, including the type of oil spilled, the temperature of the water (affecting evaporation and biodegradation), and the types of shorelines and beaches involved.
Methods for cleaning up include:
- Bioremediation: use of microorganisms or biological agents to break down or remove oil.
- Bioremediation Accelerator: Oleophilic, hydrophobic chemical, containing no bacteria, which chemically and physically bonds to both soluble and insoluble hydrocarbons. The bioremedation accelerator acts as a herding agent in water and on the surface, floating molecules to the surface of the water, including solubles such as phenols and BTEX, forming gel-like agglomerations. Undetectable levels of hydrocarbons can be obtained in produced water and manageable water columns. By overspraying sheen with bioremediation accelerator, sheen is eliminated within minutes. Whether applied on land or on water, the nutrient-rich emulsion creates a bloom of local, indigenous, pre-existing, hydrocarbon-consuming bacteria. Those specific bacteria break down the hydrocarbons into water and carbon dioxide, with EPA tests showing 98% of alkanes biodegraded in 28 days; and aromatics being biodegraded 200 times faster than in nature they also sometimes use the hydrofireboom to clean the oil up by taking it away from most of the oil and burning it.
- Controlled burning can effectively reduce the amount of oil in water, if done properly. But it can only be done in low wind, and can cause air pollution.
- Dispersants act as detergents, clustering around oil globules and allowing them to be carried away in the water. This improves the surface aesthetically, and mobilizes the oil. Smaller oil droplets, scattered by currents, may cause less harm and may degrade more easily. But the dispersed oil droplets infiltrate into deeper water and can lethally contaminate coral. Recent research indicates that some dispersants are toxic to corals.
- Watch and wait: in some cases, natural attenuation of oil may be most appropriate, due to the invasive nature of facilitated methods of remediation, particularly in ecologically sensitive areas such as wetlands.
- Dredging: for oils dispersed with detergents and other oils denser than water.
- Skimming: Requires calm waters
- Solidifying: Solidifiers are composed of dry hydrophobic polymers that both adsorb and absorb. They clean up oil spills by changing the physical state of spilled oil from liquid to a semi-solid or a rubber-like material that floats on water. Solidifiers are insoluble in water, therefore the removal of the solidified oil is easy and the oil will not leach out. Solidifiers have been proven to be relatively non-toxic to aquatic and wild life and have been proven to suppress harmful vapors commonly associated with hydrocarbons such as Benzene, Xylene, Methyl Ethyl, Acetone and Naphtha. The reaction time for solidification of oil is controlled by the surf area or size of the polymer as well as the viscosity of the oil. Some solidifier product manufactures claim the solidified oil can be disposed of in landfills, recycled as an additive in asphalt or rubber products, or burned as a low ash fuel. A solidifier called C.I.Agent (manufactured by C.I.Agent Solutions of Louisville, Kentucky) is being used by BP in granular form as well as in Marine and Sheen Booms on Dauphin Island, AL and Fort Morgan, MS to aid in the Deepwater Horizon oil spill cleanup.
- Vacuum and centrifuge: oil can be sucked up along with the water, and then a centrifuge can be used to separate the oil from the water - allowing a tanker to be filled with near pure oil. Usually, the water is returned to the sea, making the process more efficient, but allowing small amounts of oil to go back as well. This issue has hampered the use of centrifuges due to a United States regulation limiting the amount of oil in water returned to the sea.
Equipment used includes:
- Booms: large floating barriers that round up oil and lift the oil off the water
- Skimmers: skim the oil
- Sorbents: large absorbents that absorb oil
- Chemical and biological agents: helps to break down the oil
- Vacuums: remove oil from beaches and water surface
- Shovels and other road equipments: typically used to clean up oil on beaches
- Secondary containment - methods to prevent releases of oil or hydrocarbons into environment.
- Oil Spill Prevention Containment and Countermeasures (SPCC) program by the United States Environmental Protection Agency.
- Double-hulling - build double hulls into vessels, which reduces the risk and severity of a spill in case of a collision or grounding. Existing single-hull vessels can also be rebuilt to have a double hull.
Environmental Sensitivity Index (ESI) mapping
Environmental Sensitivity Index (ESI) maps are used to identify sensitive shoreline resources prior to an oil spill event in order to set priorities for protection and plan cleanup strategies. By planning spill response ahead of time, the impact on the environment can be minimized or prevented. Environmental sensitivity index maps are basically made up of information within the following three categories: shoreline type, and biological and human-use resources.
Shoreline type is classified by rank depending on how easy the garet would be to clean up, how long the oil would persist, and how sensitive the shoreline is. The floating oil slicks put the shoreline at particular risk when they eventually come ashore, covering the substrate with oil. The differing substrates between shoreline types vary in their response to oiling, and influence the type of cleanup that will be required to effectively decontaminate the shoreline. In 1995, the US National Oceanic and Atmospheric Administration extended ESI maps to lakes, rivers, and estuary shoreline types. The exposure the shoreline has to wave energy and tides, substrate type, and slope of the shoreline are also taken into account – in addition to biological productivity and sensitivity. The productivity of the shoreline habitat is also taken into account when determining ESI ranking. Mangroves and marshes tend to have higher ESI rankings due to the potentially long-lasting and damaging effects of both the oil contamination and cleanup actions. Impermeable and exposed surfaces with high wave action are ranked lower due to the reflecting waves keeping oil from coming onshore, and the speed at which natural processes will remove the oil.
Habitats of plants and animals that may be at risk from oil spills are referred to as “elements” and are divided by functional group. Further classification divides each element into species groups with similar life histories and behaviors relative to their vulnerability to oil spills. There are eight element groups: Birds, Reptiles Amphibians, Fish, Invertebrates, Habitats and Plants, Wetlands, and Marine Mammals and Terrestrial Mammals. Element groups are further divided into sub-groups, for example, the ‘marine mammals’ element group is divided into dolphins, manatees, pinnipeds (seals, sea lions & walruses), polar bears, sea otters and whales. Problems taken into consideration when ranking biological resources include the observance of a large number of individuals in a small area, whether special life stages occur ashore (nesting or molting), and whether there are species present that are threatened, endangered or rare.
Human use resources are divided into four major classifications; archaeological importance or cultural resource site, high-use recreational areas or shoreline access points, important protected management areas, or resource origins. Some examples include airports, diving sites, popular beach sites, marinas, natural reserves or marine sanctuaries.
Estimating the volume of a spill
By observing the thickness of the film of oil and its appearance on the surface of the water, it is possible to estimate the quantity of oil spilled. If the surface area of the spill is also known, the total volume of the oil can be calculated.
Film thickness Quantity spread Appearance in mm nm gal/sq mi L/ha Barely visible 0.0000015 0.0000380 38 25 0.370 Silvery sheen 0.0000030 0.0000760 76 50 0.730 First trace of color 0.0000060 0.0001500 150 100 1.500 Bright bands of color 0.0000120 0.0003000 300 200 2.900 Colors begin to dull 0.00004 0.0010000 1000 666 9.700 Colors are much darker 0.0000800 0.0020000 2000 1332 19.500
Oil spill model systems are used by industry and government to assist in planning and emergency decision making. Of critical importance for the skill of the oil spill model prediction is the adequate description of the wind and current fields. There is a worldwide oil spill modelling (WOSM) program. Tracking the scope of an oil spill may also involve verifying that hydrocarbons collected during an ongoing spill are derived from the active spill or some other source. This can involve sophisticated analytical chemistry focused on finger printing an oil source based on the complex mixture of substances present. Largely, these will be various hydrocarbons, among the most useful being polyaromatic hydrocarbons. In addition, both oxygen and nitrogen heterocyclic hydrocarbons, such as parent and alkyl homologues of carbazole, quinoline, and pyridine, are present in many crude oils. As a result, these compounds have great potential to supplement the existing suite of hydrocarbons targets to fine tune source tracking of petroleum spills. Such analysis can also be used to follow weathering and degradation of crude spills.
Largest oil spills
Oil spills of over 100,000 tons or 30 million US gallons, ordered by tons[a] Spill / Tanker Location Date *Tons of crude oil
References Kuwaiti oil fires [b] Kuwait January, 1991 - November, 1991 136,000-205,000 1,000,000-1,500,000 42,000,000-63,000,000  Kuwaiti oil lakes [c] Kuwait January, 1991 - November, 1991 3,409-6,818 25,000-50,000 1,050,000-2,100,000  Lakeview Gusher United States, Kern County, California May 14, 1910 – September, 1911 1,200 9,000 378,000  Gulf War oil spill [d] Iraq, Persian Gulf and Kuwait January 19, 1991 - January 28, 1991 818–1,091 6,000–8,000 252,000–336,000  Deepwater Horizon United States, Gulf of Mexico April 20, 2010 – July 15, 2010 560-585 4,100-4,900 172,000-180,000  Ixtoc I Mexico, Gulf of Mexico June 3, 1979 – March 23, 1980 454–480 3,329–3,520 139,818–147,840  Atlantic Empress / Aegean Captain Trinidad and Tobago July 19, 1979 287 2,105 88,396  Fergana Valley Uzbekistan March 2, 1992 285 2,090 87,780  Nowruz Field Platform Iran, Persian Gulf February 4, 1983 260 1,907 80,080  ABT Summer Angola, 700 nmi (1,300 km; 810 mi) offshore May 28, 1991 260 1,907 80,080  Castillo de Bellver South Africa, Saldanha Bay August 6, 1983 252 1,848 77,616  Amoco Cadiz France, Brittany March 16, 1978 223 1,635 68,684  MT Haven Italy, Mediterranean Sea near Genoa April 11, 1991 144 1,056 44,352  Odyssey Canada, 700 nmi (1,300 km; 810 mi) off Nova Scotia November 10, 1988 132 968 40,656  Sea Star Iran, Gulf of Oman December 19, 1972 115 843 35,420  Irenes Serenade Greece, Pylos February 23, 1980 100 733 30,800  Urquiola Spain, A Coruña May 12, 1976 100 733 30,800  Torrey Canyon United Kingdom, Isles of Scilly March 18, 1967 80–119 587–873 24,654–36,666  Greenpoint oil spill United States, Brooklyn, New York City 1940 – 1950s 55– 97 400–710 17,000–30,000 
a One ton of crude oil is roughly equal to 308 US gallons or 7.33 barrels approx.; 1 oil barrel is equal to 35 imperial or 42 US gallons.
b Estimates for the amount of oil burned in the Kuwaiti oil fires range from 500,000,000 barrels (79,000,000 m3) to nearly 2,000,000,000 barrels (320,000,000 m3). 732 wells were set ablaze, while many others were severely damaged and gushed uncontrolled for several months. The fires alone were estimated to consume approximately 6,000,000 barrels (950,000 m3) of oil per day at their peak. However, it is difficult to find reliable sources for the total amount of oil burned. The range of 1,000,000,000 barrels (160,000,000 m3) to 1,500,000,000 barrels (240,000,000 m3) given here represents frequently-cited figures, but better sources are needed.
c Oil spilled from sabotaged fields in Kuwait during the 1991 Persian Gulf War pooled in approximately 300 oil lakes, estimated by the Kuwaiti Oil Minister to contain approximately 25,000,000 to 50,000,000 barrels (7,900,000 m3) of oil. According to the U.S. Geological Survey, this figure does not include the amount of oil absorbed by the ground, forming a layer of "tarcrete" over approximately five percent of the surface of Kuwait, fifty times the area occupied by the oil lakes.
d Estimates for the Gulf War oil spill range from 4,000,000 to 11,000,000 barrels (1,700,000 m3). The figure of 6,000,000 to 8,000,000 barrels (1,300,000 m3) is the range adopted by the U.S. Environmental Protection Agency and the United Nations in the immediate aftermath of the war, 1991–1993, and is still current, as cited by NOAA and The New York Times in 2010. This amount only includes oil discharged directly into the Persian Gulf by the retreating Iraqi forces from January 19 to 28, 1991. However, according to the U.N. report, oil from other sources not included in the official estimates continued to pour into the Persian Gulf through June, 1991. The amount of this oil was estimated to be at least several hundred thousand barrels, and may have factored into the estimates above 8,000,000 barrels (1,300,000 m3).
- National Oil and Hazardous Substances Pollution Contingency Plan
- Ohmsett (Oil and Hazardous Materials Simulated Environmental Test Tank)
- Oil Pollution Act of 1990 (in the US)
- Oil well
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