Mica

For other uses, see Mica (disambiguation).

Rock with mica

Mica sheet

Mica flakes

The mica group of sheet silicate (phyllosilicate) minerals includes several closely related materials having highly perfect basal cleavage. All are monoclinic, with a tendency towards pseudohexagonal crystals, and are similar in chemical composition. The highly perfect cleavage, which is the most prominent characteristic of mica, is explained by the hexagonal sheet-like arrangement of its atoms.

The word "mica" is derived from the Latin word mica, meaning "a crumb", and probably influenced by micare, "to glitter".^[1]

Mica classification

Chemically, micas can be given the general formula^[2]

X₂Y_4–6Z₈O₂₀(OH,F)₄

in which X is K, Na, or Ca or less commonly Ba, Rb, or Cs;

Y is Al, Mg, or Fe or less commonly Mn, Cr, Ti, Li, etc.;

Z is chiefly Si or Al, but also may include Fe³⁺ or Ti.

Structurally, micas can be classed as dioctahedral (Y = 4) and trioctahedral (Y = 6). If the X ion is K or Na, the mica is a "common" mica, whereas if the X ion is Ca, the mica is classed as a "brittle" mica.

Trioctahedral micas

Common micas:

• Biotite
• Lepidolite
• Muscovite
• Phlogopite
• Zinnwaldite

Brittle micas:

• Clintonite

Interlayer deficient micas

Very fine-grained micas, which typically show more variation in ion and water content, are informally termed "clay micas". They include

• Hydro-muscovite with H₃O⁺ along with K in the X site;
• Illite with a K deficiency in the X site and correspondingly more Si in the Z site;
• Phengite with Mg or Fe²⁺ substituting for Al in the Y site and a corresponding increase in Si in the Z site.

Occurrence and production

Mica output in 2005

Mica is widely distributed and occurs in igneous, metamorphic and sedimentary regimes. Large crystals of mica used for various applications are typically mined from granitic pegmatites.

Until the 19th century, large crystals of mica were quite rare and expensive as a result of the limited supply in Europe. However, their price dramatically dropped when large reserves were found and mined in Africa and South America during the early 19th century. The largest documented single crystal of mica (phlogopite) was found in Lacey mine, Ontario, Canada; it measured 10×4.3×4.3 m and weighed about 330 tonnes.^[3] Similar-sized crystals were also found in Karelia, Russia.^[4]

The British Geological Survey reported that as of 2005, Kodarma district in Jharkhand state in India had the largest deposits of mica in the world. China was the top producer of mica with almost a third of the global share, closely followed by the USA, South Korea and Canada. Large deposits of sheet mica were mined in New England from the 19th century to the 1960s. Large mines existed in Connecticut, New Hampshire, and Maine.

Scrap and flake mica is produced all over the world. In 2010, the major producers were Russia (100,000 tonnes), Finland (68,000 t), United States (53,000 t), South Korea (50,000 t), France (20,000 t) and Canada (15,000 t). The total production was 350,000 t, although no reliable data were available for China. Most sheet mica was produced in India (3,500 t) and Russia (1,500 t).^[5] Flake mica comes from several sources: the metamorphic rock called schist as a byproduct of processing feldspar and kaolin resources, from placer deposits, and from pegmatites. Sheet mica is considerably less abundant than flake and scrap mica, and is occasionally recovered from mining scrap and flake mica. The most important sources of sheet mica are pegmatite deposits. Sheet mica prices vary with grade and can range from less than $1 per kilogram for low-quality mica to more than $2,000 per kilogram for the highest quality.^[6]

Properties and uses

The mica group represents 37 phyllosilicate minerals that have a layered or platy texture. The commercially important micas are muscovite and phlogopite, which are used in a variety of applications. Mica’s value is based on several of its unique physical properties. The crystalline structure of mica forms layers that can be split or delaminated into thin sheets. These sheets are chemically inert, dielectric, elastic, flexible, hydrophilic, insulating, lightweight, platy, reflective, refractive, resilient, and range in opacity from transparent to opaque. Mica is stable when exposed to electricity, light, moisture, and extreme temperatures. It has superior electrical properties as an insulator and as a dielectric, and can support an electrostatic field while dissipating minimal energy in the form of heat; it can be split very thin (0.025 to 0.125 millimeters or thinner) while maintaining its electrical properties, has a high dielectric breakdown, is thermally stable to 500°C, and is resistant to corona discharge. Muscovite, the principal mica used by the electrical industry, is used in capacitors that are ideal for high frequency and radio frequency. Phlogopite mica remains stable at higher temperatures (to 900°C) and is used in applications in which a combination of high-heat stability and electrical properties is required. Muscovite and phlogopite are used in sheet and ground forms.^[7]

Ground mica

The leading use of dry-ground mica in the US was in joint compound for filling and finishing seams and blemishes in gypsum wallboard (drywall). The mica acts as a filler and extender, provides a smooth consistency, improves the workability of the compound, and provides resistance to cracking. In 2008, joint compound accounted for 54% of dry-ground mica consumption. In the paint industry, ground mica is used as a pigment extender that also facilitates suspension, reduces chalking, prevents shrinking and shearing of the paint film, increases resistance of the paint film to water penetration and weathering, and brightens the tone of colored pigments. Mica also promotes paint adhesion in aqueous and oleoresinous formulations. Consumption of dry-ground mica in paint, the second ranked use, accounted for 22% of the dry-ground mica used in 2008.^[6]

Ground mica is used in the well-drilling industry as an additive to drilling fluids. The coarsely ground mica flakes help prevent the loss of circulation by sealing porous sections of the drill hole. Well drilling muds accounted for 15% of dry-ground mica use in 2008. The plastics industry used dry-ground mica as an extender and filler, especially in parts for automobiles as lightweight insulation to suppress sound and vibration. Mica is used in plastic automobile fascia and fenders as a reinforcing material, providing improved mechanical properties and increased dimensional stability, stiffness, and strength. Mica-reinforced plastics also have high-heat dimensional stability, reduced warpage, and the best surface properties of any filled plastic composite. In 2008, consumption of dry-ground mica in plastic applications accounted for 2% of the market. The rubber industry used ground mica as an inert filler and mold release compound in the manufacture of molded rubber products, such as tires and roofing. The platy texture acts as an antiblocking, antisticking agent. Rubber mold lubricant accounted for 1.5% of the dry-ground mica used in 2008. As a rubber additive, mica reduces gas permeation and improves resiliency.^[6]

Dry-ground mica is used in the production of rolled roofing and asphalt shingles, where it serves as a surface coating to prevent sticking of adjacent surfaces. The coating is not absorbed by freshly manufactured roofing because mica’s platy structure is unaffected by the acid in asphalt or by weather conditions. Mica is used in decorative coatings on wallpaper, concrete, stucco, and tile surfaces. It also is used as an ingredient in flux coatings on welding rods, in some special greases, and as coatings for core and mold release compounds, facing agents, and mold washes in foundry applications. Dry-ground phlogopite mica is used in automotive brake linings and clutch plates to reduce noise and vibration (asbestos substitute); as sound-absorbing insulation for coatings and polymer systems; in reinforcing additives for polymers to increase strength and stiffness and to improve stability to heat, chemicals, and ultraviolet (UV) radiation; in heat shields and temperature insulation; in industrial coating additive to decrease the permeability of moisture and hydrocarbons; and in polar polymer formulations to increase the strength of epoxies, nylons, and polyesters.^[6]

Mica flakes embedded in a fresque for glitter

Wet-ground mica, which retains the brilliancy of its cleavage faces, is used primarily in pearlescent paints by the automotive industry. Many metallic-looking pigments are composed of a substrate of mica coated with another mineral, usually titanium dioxide (TiO₂). The resultant pigment produces a reflective color depending on the thickness of the coating. These products are used to produce automobile paint, shimmery plastic containers, high quality inks used in advertising and security applications. In the cosmetics industry, its reflective and refractive properties make mica an important ingredient in blushes, eye liner, eye shadow, foundation, hair and body glitter, lipstick, lip gloss, mascara, moisturizing lotions, and nail polish. Some brands of toothpaste include powdered white mica. This acts as a mild abrasive to aid polishing of the tooth surface, and also adds a cosmetically pleasing, glittery shimmer to the paste. Mica is added to latex balloons to provide a colored shiny surface.^[6]

Mica is also used as an insulator in concrete block, home attics, and can be poured into walls (usually in retrofitting uninsulated open top walls). Mica may also be used as a soil conditioner, especially in potting soil mixes and in gardening plots. Greases used for axles are composed of a compound of fatty oils to which mica, tar or graphite is added to increase the durability of the grease and give it a better surface.

Built-up mica

Muscovite and phlogopite splittings can be fabricated into various built-up mica products. Produced by mechanized or hand setting of overlapping splittings and alternate layers of binders and splittings, built-up mica is used primarily as an electrical insulation material. Mica insulation is used in high-temperature and fire-resistant power cables in aluminium plants, blast furnaces, critical wiring circuits (for example, defense systems, fire and security alarm systems, and surveillance systems), heaters and boilers, lumber kilns, metal smelters, and tanks and furnace wiring. Specific high-temperature mica-insulated wire and cable is rated to work for up to 15 minutes in molten aluminium, glass, and steel. Major products are bonding materials; flexible, heater, molding, and segment plates; mica paper; and tape.^[6]

Flexible plate is used in electric motor and generator armatures, field coil insulation, and magnet and commutator commutator core insulation. Mica consumption in flexible plate was about 21 tonnes in 2008 in the US. Heater plate is used where high-temperature insulation is required. Molding plate is sheet mica from which V-rings are cut and stamped for use in insulating the copper segments from the steel shaft ends of a commutator. Molding plate is also fabricated into tubes and rings for insulation in armatures, motor starters, and transformers. Segment plate acts as insulation between the copper commutator segments of direct-current universal motors and generators. Phlogopite built-up mica is preferred because it wears at the same rate as the copper segments. Although muscovite has a greater resistance to wear, it causes uneven ridges that may interfere with the operation of a motor or generator. Consumption of segment plate was about 149 t in 2008 in the US. Some types of built-up mica have the bonded splittings reinforced with cloth, glass, linen, muslin, plastic, silk, or special paper. These products are very flexible and are produced in wide, continuous sheets that are either shipped, rolled, or cut into ribbons or tapes, or trimmed to specified dimensions. Built-up mica products may also be corrugated or reinforced by multiple layering. In 2008, about 351 t of built-up mica was consumed in the US, mostly for molding plates (19%) and segment plates (42%).^[6]

Sheet mica

Mica insulator items

Silver mica capacitors

Muscovite windows

Sheet mica is used in electrical components, electronics, isinglass, and atomic force microscopy. Other uses include diaphragms for oxygen-breathing equipment, marker dials for navigation compasses, optical filters, pyrometers, thermal regulators, stove and kerosene heater windows, and micathermic heater elements. Mica is birefringent and is therefore commonly used to make quarter and half wave plates. Specialized applications for sheet mica are found in aerospace components in air-, ground-, and sea-launched missile systems, laser devices, medical electronics and radar systems. Mica is mechanically stable in micrometer-thin sheets which are relatively transparent to radiation (such as alpha particles) while being impervious to most gases. It is therefore used as a window on radiation detectors such as Geiger-Müller tubes.

In 2008, mica splittings represented the largest part of the sheet mica industry in the United States. Consumption of muscovite and phlogopite splittings was about 308 t in 2008. Muscovite splittings from India accounted for essentially all domestic consumption. The remainder was primarily imported from Madagascar.^[6]

Electrical and electronic

Sheet mica is used principally in the electronic and electrical industries. Its usefulness in these applications is derived from its unique electrical and thermal insulating properties and its mechanical properties, which allow it to be cut, punched, stamped, and machined to close tolerances. The leading use of block mica is as an electrical insulator in electronic equipment. High-quality block mica is processed to line the gauge glasses of high-pressure steam boilers because of its flexibility, transparency, and resistance to heat and chemical attack. Only high-quality muscovite film mica, which is variously called India ruby mica or ruby muscovite mica, is used as a dielectric in capacitors. The highest quality mica film is used to manufacture capacitors for calibration standards. The next lower grade is used in transmitting capacitors. Receiving capacitors use a slightly lower grade of high-quality muscovite.^[6]

Mica sheets are used to provide structure for heating wire (such as in Kanthal or Nichrome) in heating elements and can withstand up to 900 °C (1,650 °F).

Isinglass

Thin transparent sheets of mica called "isinglass" were used for peepholes in boilers, lanterns, stoves, and kerosene heaters because they were less likely to shatter compared to glass when exposed to extreme temperature gradients. Such peepholes were also used in "isinglass curtains" in horse-drawn carriages^[8] and early 20th century cars. A book about a journey in a Model T Ford car describes isinglass curtains as follows: "Oiled canvas side curtains were put up over the windows for wind, rain, and cold (there were no heaters) and were held in place with rods that fit into the doors and twisting button snaps around the perimeter... 'Isinglass' peepholes in the curtains allowed limited visibility. Isinglass was made of thin sheets of cracked mica."^[9]

Atomic force microscopy

Another use of mica is in the production of ultraflat, thin-film surfaces (e.g. gold surfaces) using mica as substrate. Although the deposited film surface is still rough due to deposition kinetics, the back side of the film at mica-film interface provides ultraflatness, when the film is removed from the substrate. Such ultraflat substrates are common substrates for sample preparation for the atomic force microscopy.^[10] Freshly cleaved mica surfaces have been used as clean imaging substrates in atomic force microscopy, enabling for example the imaging of bismuth films,^[11] plasma glycoproteins,^[12] membrane bilayers,^[13] and DNA molecules.^[14]

Substitutes

Some lightweight aggregates, such as diatomite, perlite, and vermiculite, may be substituted for ground mica when used as filler. Ground synthetic fluorophlogopite, a fluorine-rich mica, may replace natural ground mica for uses that require thermal and electrical properties of mica. Many materials can be substituted for mica in numerous electrical, electronic, and insulation uses. Substitutes include acrylate polymers, cellulose acetate, fiberglass, fishpaper, nylon, phenolics, polycarbonate, polyester, styrene, vinyl-PVC, and vulcanized fiber. Mica paper made from scrap mica can be substituted for sheet mica in electrical and insulation applications.^[5]

Hand carved from mica from the Hopewell tradition

Mica in ancient times

Human use of mica dates back to prehistoric times. Mica was known to ancient Indian, Egyptian, Greek and Roman and Chinese civilizations, as well as the Aztec civilization of the New World.

The earliest use of mica has been found in cave paintings created during the Upper Paleolithic period (40,000 BC to 10,000 BC). The first hues were red (iron oxide, hematite, or red ochre) and black (manganese dioxide, pyrolusite), though black from juniper or pine carbons has also been discovered. White from kaolin or mica was used occasionally.

A few kilometers northeast of Mexico City stands the ancient site of Teotihuacan. The most striking visual and striking structure of Teotihuacan is the towering Pyramid of the Sun. The pyramid contained considerable amounts of mica in layers up to 30 cm (12 in) thick.^[15]

Natural mica was and is still used by the Taos and Picuris Pueblos Indians in north-central New Mexico to make pottery. The pottery is made from weathered Precambrian mica schist, and has flecks of mica throughout the vessels. Tewa Pueblo pottery is made by coating the clay with mica to provide a dense-glittery micaceous finish over the entire object.^[6]

Throughout the ages, fine powders of mica have been used for various purposes, including decorations. The colored Gulal and Abeer used by Hindus of north India during holi festival contain fine, small crystals of mica. The majestic Padmanabhapuram palace, 65 km (40 mi) from Trivandrum in India, has colored mica windows.

References

 This article incorporates public domain material from the United States Geological Survey document "Mica".

1. ^ E. M. Kirkpatrick, ed (1983). Chambers 20th Century Dictionary. Schwarz, Davidson, Seaton, Simpson, Sherrard (New ed.). Edinburgh: W & R Chambers Ltd. p. 793. ISBN 0550102345. 
2. ^ Deer, W. A., R. A. Howie and J. Zussman (1966) An Introduction to the Rock Forming Minerals, Longman, ISBN 0-582-44210-9
3. ^ P. C. Rickwood (1981). "The largest crystals". American Mineralogist 66: 885–907. http://www.minsocam.org/ammin/AM66/AM66_885.pdf. 
4. ^ "The giant crystal project site". http://giantcrystals.strahlen.org/europe/kovdor.htm. Retrieved 2009-06-06. 
5. ^ ^{a b} Mica, USGS Mineral Commodity Summaries 2011
6. ^ ^{a b c d e f g h i j} Thomas P. Dolley Mica, USGS 2008 Minerals Yearbook
7. ^ Thomas P. Dolley [Mica], USGS 2008 Minerals Yearbook (July 2010)
8. ^ Isinglass curtains are referred to in the 1955 musical Oklahoma's song The Surrey with the Fringe on Top.
9. ^ Wilke, Joanne (2007). Eight Women, Two Model Ts and the American West. University of Nebraska Press. ISBN 0803260199. 
10. ^ Substrates for AFM, in Atomic Force Microscopy, Eaton and West, OUP (2010), pp. 87–89, ISBN 978-0-19-957045-4.
11. ^ Weisenhorn, A. L.; et al. (1991). "Atomically resolved images of bismuth films on mica with an atomic force microscope". Journal of Vacuum Science & Technology, B: Microelectronics and Nanometer Structures 9 (2): 1333–1335. doi:10.1116/1.585190. 
12. ^ Marchant, Roger E.; Lea, A. Scott; Andrade, Joseph D.; Bockenstedt, Paula (1992). "Interactions of von Willebrand factor on mica studied by atomic force microscopy". Journal of Colloid and Interface Science 148 (1): 261–272. doi:10.1016/0021-9797(92)90135-9. 
13. ^ Singh, Seema; Keller, David J. (1991). "Atomic force microscopy of supported planar membrane bilayers". Biophysical Journal 60 (6): 1401–1410. doi:10.1016/S0006-3495(91)82177-4. PMC 1260200. PMID 1777565. http://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=1260200. 
14. ^ Thundat, T.; Allison, D. P.; Warmack, R. J.; Brown, G. M.; Jacobson, K. B.; Schrick, J. J.; Ferrell, T. L. (1992). "Atomic force microscopy of DNA on mica and chemically modified mica". Scanning Microscopy 6 (4): 911. PMID 1295085. 
15. ^ Fagan, Garrett G. (2006). Archaeological Fantasies: How Pseudoarchaeology Misrepresents the Past and Misleads the Public. New York: Routledge. p. 102. ISBN 0415305934. http://books.google.com/?id=sIYpx9mzd4gC&pg=PA102. 

External links

• Mineral Galleries data
• Mindat