- Illite
Illite is a non-expanding,
clay -sized, micaceous mineral. Illite is a phyllosilicate or layered alumino-silicate. Its structure is constituted by the repetition of Tetrahedron – Octahedron – Tetrahedron (TOT) layer. The interlayer space is mainly occupied by poorly hydrated potassium cations responsible for the absence of swelling. Structurally illite is quite similar tomuscovite orsericite with slightly moresilicon ,magnesium ,iron , and water and slightly less tetrahedralaluminium and interlayerpotassium . The chemical formula is given as (K,H3O)(Al,Mg,Fe)2(Si,Al)4O10 [(OH)2,(H2O)] [ [http://webmineral.com/data/Illite.shtml Illite Mineral Data ] ] , but there is considerable ion substitution. It occurs as aggregates of smallmonoclinic grey to white crystals. Due to the small size, positive identification usually requiresx-ray diffraction analysis. Illite occurs as an alteration product of muscovite andfeldspar inweathering andhydrothermal environments. It is common in sediments, soils, and argillaceoussedimentary rocks as well as in some low grademetamorphic rocks .Glauconite in sediments can be differentiated by x-ray analysis.The cation exchange capacity (CEC) of illite is smaller than that of
smectite but higher than that ofkaolinite , typically around 20 – 30 meq/100 g.Illite was first described for occurrences in the Maquoketa
shale inCalhoun County, Illinois , USA, in 1937. The name was derived from its type location in Illinois. Illite is also called hydromica or hydromuscovite.Brammallite is a sodium rich analogue.Illite is also used in food supplements, with claimed benefits that range from bowel function to reduction of
heavy metals in the blood. Apparently, a French company, Argiletz, provides a wide range of products which are offered for sale in theUK and elsewhere. "Green clay", a term used in several languages, often contains illite. InScotland , internal uses of illite probably date back to Celtic times.References
* [http://www.amazon.com/dp/0471463027/ Mitchell J.K. (1993)] Fundamentals of soil behavior. Second edition. John Wiley and Sons, Inc., New York. 437 pp, see Chapter 3, Soil Mineralogy, p. 32.
External links
* [http://webmineral.com/data/Illite.shtml Webmineral]
* [http://pubs.usgs.gov/of/of01-041/htmldocs/clays/illite.htm USGS]
* [http://www.mindat.org/min-2011.html Mindat]
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