General properties
Name, symbol, number dubnium, Db, 105
Pronunciation /ˈdbniəm/
Element category transition metal
Group, period, block 57, d
Standard atomic weight [268]
Electron configuration [Rn] 5f14 6d3 7s2
Electrons per shell 2, 8, 18, 32, 32, 11, 2
(predicted) (Image)
Physical properties
Phase Unknown
Atomic properties
Oxidation states 5
CAS registry number 53850-35-4
Most stable isotopes
Main article: Isotopes of dubnium
iso NA half-life DM DE (MeV) DP
262Db syn 34 s[1][2] 67% α 8.66,8.45 258Lr
33% SF
263Db syn 27 s[2] 56% SF
41% α 8.36 259Lr
3% ε 263mRf
266Db syn 22 m[2] SF
ε 266Rf
267Db syn 1.2 h[2] SF
268Db syn 29 h[2] SF
ε 268Rf
270Db syn 23.15 h[3] SF
only half times of over 5 seconds are included here
v ·  /ˈdbniəm/ doob-nee-əm),[4] is a chemical element with the symbol Db and atomic number 105, named after the town of Dubna in Russia, where it was first produced. It is a synthetic element (an element that can be created in a laboratory but is not found in nature) and radioactive; the most stable known isotope, dubnium-268, has a half-life of approximately 28 hours.[5]

In the periodic table of the elements, it is a d-block element and in the transactinide elements. It is a member of the period 7 and a group 5 element. Chemistry experiments have confirmed that dubnium behaves as the heavier homologue to tantalum in group 5. The chemical properties of dubnium are characterized only partly. They are similar with those of other group 5 elements.

In the 1960s, microscopic amounts of dubnium were produced in laboratories in the former Soviet Union and in California. The priority of the discovery and therefore the naming of the element was disputed between Soviet and American scientists, and it was not until 1997 that International Union of Pure and Applied Chemistry (IUPAC) established Soviet team priority and a compromise name of dubnium as the official name for the element.




Dubnium was first reported by Russian scientists in 1968 at the Joint Institute for Nuclear Research in Dubna, Soviet Union (now in Russia). Researchers there bombarded a americium-243 target with neon-22 ions. They reported a 9.40 MeV and a 9.70 MeV alpha-activity and assigned the decays to the isotopes 260Db or 261Db.

+ 22
+ x n

In 1970 Soviet team expanded their work by the application of thermal gradient chromatography and detection by spontaneous fission. They observed a 2.2 second spontaneous fission activity in a fraction portraying niobium-like characteristics and assigned the activity to dubnium-261 pentachloride, 261DbCl5.

In late April 1970 researchers led by Albert Ghiorso working at the University of California, Berkeley published a convincing synthesis of 260Db in the reaction between californium-249 target and nitrogen-15 ions:

+ 15
+ 4 n

The team claimed that 260Db decayed by 9.10 MeV alpha-emission with a half-life of 1.6 seconds to lawrencium-256, 256Lr. Decay data for lawrencium-256 agreed with the literature values and provided strong support to their claim. These results by the Berkeley scientists did not confirm the Soviet findings regarding the 9.40 MeV or 9.70 MeV alpha-decay of dubnium-260, leaving only dubnium-261 as possible produced isotope. In 1971, the Soviet team repeated their reaction using an improved set-up and were able to confirm the decay data for 260Db using the reaction:

+ 22
+ 5 n

In 1976, the Russian team continued their study of the reaction using thermal gradient chromatography and were able to identify the product dubnium-260 pentabromide, 260DbBr5.

In 1992 the IUPAC/IUPAP Transfermium Working Group assessed the claims of the two groups and concluded that confidence in the discovery grew from results from both laboratories and the claim of discovery should be shared.[6]

Naming controversy

A photo of Niels Bohr
A photo of Otto Hahn
The element 105 was originally proposed to be named after Niels Bohr (left side), a Danish nuclear physicist, with name nielsbohrium (Ns) by the Soviet/Russian team. The American team initially proposed the element to be named after Otto Hahn (right side), a German chemist, known as a pioneer in the fields of radioactivity and radiochemistry.

The Soviet (later, Russian) team proposed the name nielsbohrium (Ns) in honor of the Danish nuclear physicist Niels Bohr. The American team proposed that the new element should be named hahnium (Ha), in honor of the late German chemist Otto Hahn. Consequently hahnium was the name that most American and Western European scientists used and appears in many papers published at the time, and nielsbohrium was used in the Soviet Union and Eastern Bloc countries.

An element naming controversy erupted between the two groups. The International Union of Pure and Applied Chemistry (IUPAC) thus adopted unnilpentium (Unp) as a temporary, systematic element name. Attempting to resolve the issue, in 1994, the IUPAC proposed the name joliotium (Jl), after the French physicist Frédéric Joliot-Curie, which was originally proposed by Soviet team for element 102, later named nobelium. The two principal claimants still disagreed about the names of elements 104-106. However, in 1997 they resolved the dispute and adopted the current name, dubnium (Db), after the Russian town of Dubna, the location of the Joint Institute for Nuclear Research. It was argued by IUPAC that the Berkeley laboratory had already been recognized several times in the naming of elements (i.e., berkelium, californium, americium) and that the acceptance of the names rutherfordium and seaborgium for elements 104 and 106 should be offset by recognizing the Russian team's contributions to the discovery of elements 104, 105 and 106.[7][8]

Chemical properties

Extrapolated properties

Element 105 is projected to be the second member of the 6d series of transition metals and the heaviest member of group V in the Periodic Table, below vanadium, niobium and tantalum. Because it is positioned right below tantalum, it may also be called eka-tantalum. All the members of the group readily portray their oxidation state of +5 and the state becomes more stable as the group is descended. Thus dubnium is expected to form a stable +5 state. For this group, +4 and +3 states are also known for the heavier members and dubnium may also form these reducing oxidation states.

In an extrapolation of the chemistries from niobium and tantalum, dubnium should react with oxygen to form an inert pentoxide, Db2O5. In alkali, the formation of an orthodubnate complex, DbO43−, is expected. Reaction with the halogens should readily form the pentahalides, DbX5. The pentachlorides of niobium and tantalum exist as volatile solids or monomeric trigonal bipyramidal molecules in the vapour phase. Thus, DbCl5 is expected to be a volatile solid. Similarly, the pentafluoride, DbF5, should be even more volatile. Hydrolysis of the halides is known to readily form the oxyhalides, MOX3. Thus the halides DbX5 should react with water to form DbOX3. The reaction with fluoride ion is also well known for the lighter homologues and dubnium is expected to form a range of fluoro-complexes. In particular, reaction of the pentafluoride with HF should form a hexafluorodubnate ion, DbF6. Excess fluoride should lead to DbF72– and DbOF52–. If eka-tantalum properties are portrayed, higher concentrations of fluoride should ultimately form DbF83– since NbF83– is not known.

Experimental chemistry

The chemistry of dubnium has been studied for several years using gas thermochromatography. The experiments have studied the relative adsorption characteristics of isotopes of niobium, tantalum and dubnium radioisotopes. The results have indicated the formation of typical group 5 halides and oxyhalides, namely DbCl5, DbBr5, DbOCl3 and DbOBr3. Reports on these early experiments usually refer to dubnium as hahnium.

Formula Names(s)
DbCl5 dubnium pentachloride ; dubnium(V) chloride
DbBr5 dubnium pentabromide ; dubnium(V) bromide
DbOCl3 dubnium oxychloride ; dubnium(V) trichloride oxide ; dubnyl(V) chloride
DbOBr3 dubnium oxybromide ; dubnium(V) tribromide oxide ; dubnyl(V) bromide

Nucleosynthesis history

Cold fusion

This section deals with the synthesis of nuclei of dubnium by so-called "cold" fusion reactions. These are processes which create compound nuclei at low excitation energy (~10-20 MeV, hence "cold"), leading to a higher probability of survival from fission. The excited nucleus then decays to the ground state via the emission of one or two neutrons only.

209Bi(50Ti,xn)259-xDb (x=1,2,3)

The first attempts to synthesise dubnium using cold fusion reactions were performed in 1976 by the team at FLNR, Dubna using the above reaction. They were able to detect a 5 s spontaneous fission (SF) activity which they assigned to 257Db. This assignment was later corrected to 258Db. In 1981, the team at GSI studied this reaction using the improved technique of correlation of genetic parent-daughter decays. They were able to positively identify 258Db, the product from the 1n neutron evaporation channel.[9] In 1983, the team at Dubna revisited the reaction using the method of identification of a descendant using chemical separation. They succeeded in measuring alpha decays from known descendants of the decay chain beginning with 258Db. This was taken as providing some evidence for the formation of dubnium nuclei. The team at GSI revisited the reaction in 1985 and were able to detect 10 atoms of 257Db.[10] After a significant upgrade of their facilities in 1993, in 2000 the team measured 120 decays of 257Db, 16 decays of 256Db and decay of 258Db in the measurement of the 1n, 2n and 3n excitation functions. The data gathered for 257Db allowed a first spectroscopic study of this isotope and identified an isomer, 257mDb, and a first determination of a decay level structure for 257Db.[11] The reaction was used in spectroscopic studies of isotopes of mendelevium and einsteinium in 2003-2004.[12]

209Bi(49Ti,xn)258-xDb (x=2?)

This reaction was studied by Yuri Oganessian and the team at Dubna in 1983. They observed a 2.6 s SF activity tentatively assigned to 256Db. Later results suggest a possible reassignment to 256Rf, resulting from the ~30% EC branch in 256Db.

209Bi(48Ti,xn)257-xDb (x=1?)

This reaction was studied by Yuri Oganessian and the team at Dubna in 1983. They observed a 1.6 s activity with a ~80% alpha branch with a ~20% SF branch. The activity was tentatively assigned to 255Db. Later results suggest a reassignment to 256Db.

208Pb(51V,xn)259-xDb (x=1,2)

The team at Dubna also studied this reaction in 1976 and were again able to detect the 5 s SF activity, first tentatively assigned to 257Db and later to 258Db. In 2006, the team at LBNL reinvestigated this reaction as part of their odd-Z projectile program. They were able to detect 258Db and 257Db in their measurement of the 1n and 2n neutron evaporation channels.[13]


The team at Dubna also studied this reaction in 1976 but this time they were unable to detect the 5 s SF activity, first tentatively assigned to 257Db and later to 258Db. Instead, they were able to measure a 1.5 s SF activity, tentatively assigned to 255Db.

205Tl(54Cr,xn)259-xDb (x=1?)

The team at Dubna also studied this reaction in 1976 and were again able to detect the 5 s SF activity, first tentatively assigned to 257Db and later to 258Db.

Hot fusion

This section deals with the synthesis of nuclei of dubnium by so-called "hot" fusion reactions. These are processes which create compound nuclei at high excitation energy (~40-50 MeV, hence "hot"), leading to a reduced probability of survival from fission and quasi-fission. The excited nucleus then decays to the ground state via the emission of 3-5 neutrons.

232Th(31P,xn)263-xDb (x=5)

There are very limited reports that this rare reaction using a P-31 beam was studied in 1989 by Andreyev et al. at the FLNR. One source suggests that no atoms were detected whilst a better source from the Russians themselves indicates that 258Db was synthesised in the 5n channel with a yield of 120 pb.

238U(27Al,xn)265-xDb (x=4,5)

In 2006, as part of their study of the use of uranium targets in superheavy element synthesis, the LBNL team led by Ken Gregorich studied the excitation functions for the 4n and 5n channels in this new reaction.[14]

236U(27Al,xn)263-xDb (x=5,6)

This reaction was first studied by Andreyev et al. at the FLNR, Dubna in 1992. They were able to observe 258Db and 257Db in the 5n and 6n exit channels with yields of 450 pb and 75 pb, respectively.[15]

243Am(22Ne,xn)265-xDb (x=5)

The first attempts to synthesis dubnium were performed in 1968 by the team at the Flerov Laboratory of Nuclear Reactions (FLNR) in Dubna, Russia. They observed two alpha lines which they tentatively assigned to 261Db and 260Db. They repeated their experiment in 1970 looking for spontaneous fission. They found a 2.2 s SF activity which they assigned to 261Db. In 1970, the Dubna team began work on using gradient thermochromatography in order to detect dubnium in chemical experiments as a volatile chloride. In their first run they detected a volatile SF activity with similar adsorption properties to NbCl5 and unlike HfCl4. This was taken to indicate the formation of nuclei of dvi-niobium as DbCl5. In 1971, they repeated the chemistry experiment using higher sensitivity and observed alpha decays from an dvi-niobium component, taken to confirm the formation of 260105. The method was repeated in 1976 using the formation of bromides and obtained almost identical results, indicating the formation of a volatile, dvi-niobium-like [105]Br5.

241Am(22Ne,xn)263-xDb (x=4,5)

In 2000, Chinese scientists at the Institute of Modern Physics (IMP), Lanzhou, announced the discovery of the previously unknown isotope 259Db formed in the 4n neutron evaporation channel. They were also able to confirm the decay properties for 258Db.[16]

248Cm(19F,xn)267-xDb (x=4,5)

This reaction was first studied in 1999 at the Paul Scherrer Institute (PSI) in order to produce 262Db for chemical studies. Just 4 atoms were detected with a cross section of 260 pb.[17] Japanese scientists at JAERI studied the reaction further in 2002 and determined yields for the isotope 262Db during their efforts to study the aqueous chemistry of dubnium.[18]

249Bk(18O,xn)267-xDb (x=4,5)

Following from the discovery of 260Db by Albert Ghiorso in 1970 at the University of California (UC), the same team continued in 1971 with the discovery of the new isotope 262Db. They also observed an unassigned 25 s SF activity, probably associated with the now-known SF branch of 263Db.[19] In 1990, a team led by Kratz at LBNL definitively discovered the new isotope 263Db in the 4n neutron evaporation channel.[20] This reaction has been used by the same team on several occasions in order to attempt to confirm an electron capture (EC) branch in 263Db leading to long-lived 263Rf (see rutherfordium).[21]

249Bk(16O,xn)265-xDb (x=4)

Following from the discovery of 260Db by Albert Ghiorso in 1970 at the University of California (UC), the same team continued in 1971 with the discovery of the new isotope 261Db.[19]

250Cf(15N,xn)265-xDb (x=4)

Following from the discovery of 260Db by Ghiorso in 1970 at LBNL, the same team continued in 1971 with the discovery of the new isotope 261Db.[19]

249Cf(15N,xn)264-xDb (x=4)

In 1970, the team at the Lawrence Berkeley National Laboratory (LBNL) studied this reaction and identified the isotope 260Db in their discovery experiment. They used the modern technique of correlation of genetic parent-daughter decays to confirm their assignment.[22] In 1977, the team at Oak Ridge repeated the experiment and were able to confirm the discovery by the identification of K X-rays from the daughter lawrencium.[23]


In 1988, scientists as the Lawrence Livermore National Laboratory (LLNL) used the asymmetric hot fusion reaction with an einsteinium-254 target to search for the new nuclides 264Db and 263Db. Due to the low sensitivity of the experiment caused by the small Es-254 target,they were unable to detect any evaporation residues (ER).

Decay of heavier nuclides

Isotopes of dubnium have also been identified in the decay of heavier elements. Observations to date are summarised in the table below:

Evaporation Residue Observed dubnium isotope
294Uus 270Db
288Uup 268Db
287Uup 267Db
282Uut 266Db
267Bh 263Db
278Uut, 266Bh 262Db
265Bh 261Db
272Rg 260Db
266Mt, 262Bh 258Db
261Bh 257Db
260Bh 256Db


Chronology of isotope discovery
Isotope Year discovered discovery reaction
256Db 1983?, 2000 209Bi(50Ti,3n)
257Dbg 1985 209Bi(50Ti,2n)
257Dbm 2000 209Bi(50Ti,2n)
258Db 1976?, 1981 209Bi(50Ti,n)
259Db 2001 241Am(22Ne,4n)
260Db 1970 249Cf(15N,4n)
261Db 1971 249Bk(16O,4n)
262Db 1971 249Bk(18O,5n)
263Db 1971?, 1990 249Bk(18O,4n)
264Db unknown
265Db unknown
266Db 2006 237Np(48Ca,3n)
267Db 2003 243Am(48CaCa,4n)
268Db 2003 243Am(48Ca,3n)
269Db unknown
270Db 2009 249Bk(48Ca,3n)



Recent data on the decay of 272Rg has revealed that some decay chains continue through 260Db with extraordinary longer life-times than expected. These decays have been linked to an isomeric level decaying by alpha decay with a half-life of ~19 s. Further research is required to allow a definite assignment.


Evidence for an isomeric state in 258Db has been gathered from the study of the decay of 266Mt and 262Bh. It has been noted that those decays assigned to an electron capture (EC) branch has a significantly different half-life to those decaying by alpha emission. This has been taken to suggest the existence of an isomeric state decaying by EC with a half-life of ~20 s. Further experiments are required to confirm this assignment.


A study of the formation and decay of 257Db has proved the existence of an isomeric state. Initially, 257Db was taken to decay by alpha emission with energies 9.16,9.07 and 8.97 MeV. A measurement of the correlations of these decays with those of 253Lr have shown that the 9.16 MeV decay belongs to a separate isomer. Analysis of the data in conjunction with theory have assigned this activity to a meta stable state, 257mDb. The ground state decays by alpha emission with energies 9.07 and 8.97 MeV. Spontaneous fission of 257m,gDb was not confirmed in recent experiments.

Spectroscopic decay level schemes

This is the currently suggested decay level scheme for 257Dbg,m from the study performed in 2001 by Hessberger et al. at GSI

Retracted isotopes


In 1983, scientists at Dubna carried out a series of supportive experiments in their quest for the discovery of Bohrium. In two such experiments, they claimed they had detected a ~1.5 s spontaneous fission activity from the reactions 207Pb(51V,xn) and 209Bi(48Ti,xn). The activity was assigned to 255Db. Later research suggested that the assignment should be changed to 256Db. As such, the isotope 255Db is currently not recognised on the chart of radionuclides and further research is required to confirm this isotope.


  1. ^ Münzenberg, G.; Gupta, M. (2011). Production and Identification of Transactinide Elements. pp. 877. doi:10.1007/978-1-4419-0720-2_19. 
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  3. ^ Oganessian, Yu. Ts.; Abdullin, F. Sh.; Bailey, P. D.; Benker, D. E.; Bennett, M. E.; Dmitriev, S. N.; Ezold, J. G.; Hamilton, J. H. et al. (2010). "Synthesis of a New Element with Atomic Number Z=117". Physical Review Letters 104. doi:10.1103/PhysRevLett.104.142502. PMID 20481935. 
  4. ^ Merriam-Webster's Collegiate Dictionary-Eleventh Edition, Merriam-Webster, Inc, 2003
  5. ^ Physical experiments determined a half-life of ~16 h whilst chemical experiments provided a value of ~32 h. The half-life is often taken as ~28 h due to the higher number of atoms detected by chemical means
  6. ^ Barber, R. C.; Greenwood, N. N.; Hrynkiewicz, A. Z.; Jeannin, Y. P.; Lefort, M.; Sakai, M.; Ulehla, I.; Wapstra, A. P. et al. (1993). "Discovery of the transfermium elements. Part II: Introduction to discovery profiles. Part III: Discovery profiles of the transfermium elements (Note: for Part I see Pure Appl. Chem., Vol. 63, No. 6, pp. 879–886, 1991)". Pure and Applied Chemistry 65 (8): 1757. doi:10.1351/pac199365081757. 
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  11. ^ F. P. Hessberger; Hofmann, S.; Ackermann, D.; Ninov, V.; Leino, M.; Münzenberg, G.; Saro, S.; Lavrentev, A. et al. (2001). "Decay properties of neutron-deficient isotopes 256,257Db, 255Rf, 252,253Lr". Eur. Phys. J. A 12: 57–67. Bibcode 2001EPJA...12...57H. doi:10.1007/s100500170039. http://www.edpsciences.org/articles/epja/abs/2001/09/epja1103/epja1103.html. 
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  13. ^ Gates (2005). "Measurement of the 208Pb(51V, xn)259-xDb Excitation Function". LBNL Annual Report. http://rnc.lbl.gov/nsd/annualreport2005/contributions/Gates1_LE.pdf. 
  14. ^ "238U studies". http://rnc.lbl.gov/nsd/annualreport2005/contributions/Gregorich_LE.pdf. Retrieved 2009-05-05. 
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  • Dubnium — Rutherfordium ← Dubnium → Seaborgium Ta …   Wikipédia en Français

  • dubnium — [doob′nē əm] n. 〚ModL, after Dubna, Russia, where important work in nuclear physics took place + IUM〛 a radioactive chemical element with a very short half life: a transactinide produced by bombarding californium or berkelium with high energy… …   Universalium

  • dubnium — (Db) Elemento transuránido. Su número atómico es 104; su peso atómico (masa) es 260. Se produce mediante una reacción nuclear inducida. También llamado elemento 105. Diccionario Mosby Medicina, Enfermería y Ciencias de la Salud, Ediciones… …   Diccionario médico

  • dubnium — ● dubnium nom masculin (de Dubna ou Doubna, nom propre) Élément chimique artificiel (Db) de numéro atomique 105, de masse atomique 262,1144 …   Encyclopédie Universelle

  • dubnium — Symbol: Db Competing name for unnilquadium, the 104th element, proposed by the IUPAC …   Elements of periodic system

  • dubnium — [doob′nē əm] n. [ModL, after Dubna, Russia, where important work in nuclear physics took place + IUM] a radioactive chemical element with a very short half life: a transactinide produced by bombarding californium or berkelium with high energy… …   English World dictionary

  • Dubnium — Eigenschaften …   Deutsch Wikipedia

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  • dubnium — dubnis statusas T sritis fizika atitikmenys: angl. dubnium vok. Dubnium, n rus. дубний, m pranc. dubnium, m …   Fizikos terminų žodynas

  • dubnium — dubnis statusas T sritis chemija apibrėžtis Cheminis elementas. simbolis( iai) Db atitikmenys: lot. dubnium angl. dubnium rus. дубний …   Chemijos terminų aiškinamasis žodynas

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