Colored gold

Ternary plot of different colors of Ag-Au-Cu alloys

While pure gold is yellow in color, colored gold can be developed into various colors. These colors are generally obtained by alloying gold with other elements in various proportions.

For example, alloys which are mixed 14 parts gold to 10 parts alloy create 14-karat gold, 18 parts gold to 6 parts alloy creates 18 karat, and so on. This is often expressed as the result of the ratio, i.e.: 14/24 equals 0.585 and 18/24 is 0.750. There are hundreds of possible alloys and mixtures, but in general the addition of silver will color gold white, and the addition of copper will color it red. A mix of around 50/50 copper and silver gives the range of yellow gold alloys the public is accustomed to seeing in the marketplace. A small amount (0.2%) of zinc can be added to harden the alloy.

The most common grades of gold, in addition to pure 24K, are 22K (92%), 18K (75%), 14K (58%) and 9K (38%).^[1]

Colored golds can be classified to three groups:^[2]

• the Au-Ag-Cu system, producing white, yellow, green and red golds; typically malleable alloys
• the intermetallic compounds, producing blue and purple golds, as well as other colors. These are typically brittle but can be used as gems and inlays
• the surface oxide layers, such as black gold; mechanical properties depend on the bulk alloy, and the colored surface is prone to wear

White gold

Rhodium-plated white gold wedding ring

For other uses, see White Gold (disambiguation).

White gold is an alloy of gold and at least one white metal, usually nickel, manganese or palladium. Like yellow gold, the purity of white gold is given in karats.

White gold's properties vary depending on the metals and proportions used. As a result, white gold alloys can be used for many different purposes; while a nickel alloy is hard and strong and therefore good for rings and pins, gold-palladium alloys are soft, pliable and good for white gold gemstone settings, sometimes with other metals like copper, silver, and platinum for weight and durability, although this often requires specialized goldsmiths. The term white gold is used very loosely in the industry to describe karat gold alloys with a whitish hue. Many believe that the color of the rhodium plating, which is seen on many commercial pieces, is actually the color of white gold. The term "white" covers a large spectrum of colors that borders or overlaps pale yellow, tinted brown, and even very pale rose. The jewelry industry often hides these off-white colors by rhodium plating.

A common white gold formulation consists of 90 wt.% gold and 10 wt.% nickel.^[1] Copper can be added to increase malleability.^[2]

The strength of gold-nickel-copper alloys is caused by formation of two phases, a gold-rich Au-Cu, and a nickel-rich Ni-Cu, and the resulting hardening of the material.^[2]

The alloys used in jewelry industry are gold-palladium-silver and gold-nickel-copper-zinc. Palladium and nickel act as primary bleaching agents for gold; zinc acts as a secondary bleaching agent to attenuate the color of copper.

Contact allergy

About one out of eight people have an allergic reaction to the nickel in some white gold alloys when worn over long periods. A typical reaction is a minor skin rash.^[3] Because of this, many European countries do not use nickel white gold. White gold alloys made without nickel are less likely to be allergenic.

Rose, red, and pink gold

"Red gold" redirects here. For the deciduous Australian Red Cedar tree, see Toona ciliata. For other uses, see Red gold (disambiguation).

Rose gold is a gold and copper alloy widely used for specialized jewelry. It is also known as pink gold and red gold. As it was popular in Russia at the beginning of the nineteenth century, it is also known as Russian gold, however, this term is now obsolete.

Although the names are often used interchangeably, the difference between red, rose, and pink gold is the copper content – the higher the copper content, the stronger the red coloration. A common alloy for rose gold is 75% gold and 25% copper by mass (18 karat). Since rose gold is an alloy, there is no such thing as "pure rose gold".

A common formulation for red gold is 50% gold and 50% copper.^[1]

Up to 15% zinc can be added to copper-rich alloys to change their color to reddish yellow or dark yellow.^[2]

During ancient times, due to impurities in the smelting process, gold frequently turned a reddish color. This is why many Greco-Roman texts, and even many texts from the Middle Ages, describe gold as "red".^{[citation needed]}

Rose gold alloys

See also: Crown gold

The highest karat version of rose gold is also known as crown gold, which is 22 karat. Eighteen karat red gold may be made of 25% copper and 75% gold. For 18 karat rose gold, typically about 4% silver is added to 75% gold and 21% copper to give a rose color. 14 karat red gold is often found in the Middle East and contains 41.67% copper.

Rose gold in musical instruments

High-end flutes are very commonly made of solid rose gold, the most common alloy being 14K, but 9K, 10K, 18K and 19.5K are also available from the major flute makers.

Spangold

Some gold copper-aluminum alloys form a fine surface texture at heat treatment, yielding an interesting spangling effect. At cooling, they undergo a quasi-martensitic transformation from body centered cubic to body-centered tetragonal phase; the transformation does not depend on the cooling rate. A polished object is heated in hot oil to 150 200 °C for 10 minutes then cooled below 20 °C, forming a sparkly surface covered with tiny facets.

The alloy of 76% gold, 19% copper, and 5% aluminum yields yellow color, the alloy of 76% gold, 18% copper and 6% aluminum is pink.^[2]

Green gold

"Green gold" redirects here. For the color, see green-gold. For the Israeli figure, see Greengold.

Green gold alloys are made by leaving the copper out of the alloy mixture and just using gold and silver. It actually appears as a greenish yellow rather than green. Eighteen karat green gold would therefore contain a mix of gold 75% and silver 25% (or 73% gold and 27% silver). Fired enamels adhere better to these alloys.

Green gold was known to Lydians as long ago as 860 BC under the name electrum, a naturally occurring alloy of silver and gold.^[1]

Cadmium can be added to gold alloys in amount of up to 4% to achieve green color. The alloy of 75% gold, 23% copper, and 2% cadmium yields light green 18ct gold. The alloy of 75% gold, 15% silver, 6% copper, and 4% cadmium yields a dark green alloy. Cadmium is, however, toxic.

Grey gold

Grey gold alloys are made by adding silver, manganese and copper in specific ratios to the gold.^[4]

Black gold

For the colloquial term "black gold", see crude oil.

Black gold is a type of gold used in jewelry.^[5][6] Black colored gold can be produced by various methods:

• Electroplating, using black rhodium or ruthenium. Solutions that contain ruthenium give a slightly harder black coating than those that contain rhodium.^[7]
• Patination by applying sulfur and oxygen containing compounds.
• Plasma assisted chemical vapor deposition process involving amorphous carbon
• Controlled oxidation of gold containing chromium or cobalt (e.g. 75% gold, 25% cobalt^[1]).

A range of colors from brown to black can be achieved on copper-rich alloys by treatment with potassium sulfide.^[2]

Cobalt-containing alloys, e.g. 75% gold with 25% cobalt, form a black oxide layer with heat treatment at 700-950 °C. Copper, iron and titanium can be also used for such effect. Gold-cobalt-chromium alloy (75% gold, 15% cobalt, 10% chromium) yields surface oxide that's olive-tinted because of the chromium(III) oxide content, is about 5 times thinner than Au-Co and has significantly better wear resistance. The gold-cobalt alloy consists of a gold-rich (about 94% Au) and cobalt-rich (about 90% Co) phases; the cobalt-rich phase grains are capable of oxide layer formation on their surface.^[2]

More recently a laser technique has been developed that renders the surface of metals deep black. A femtosecond laser pulse deforms the surface of the metal forming nanostructures. The immensely increased surface area can absorb virtually all the light that falls on it thus rendering it deep black.^[8]

Purple and blue golds

Gold-aluminium phase diagram

Purple gold (also called amethyst gold and violet gold) is an alloy of gold and aluminum rich in gold-aluminium intermetallic (AuAl₂). Gold content in AuAl₂ is around 79% and can therefore be referred to as 18 karat gold. Purple gold is more brittle than other gold alloys, as it is an intermetallic compound instead of a malleable alloy, and a sharp blow may cause it to shatter.^[7] It is therefore usually machined and faceted to be used as a "gem" in conventional jewelry rather than by itself. At lower content of gold, the material is composed of the intermetallic and an aluminium-rich solid solution phase. At higher content of gold, the gold-richer intermetallic AuAl forms; the purple color is preserved to about 15% of aluminium. At 88% of gold the material is composed of AuAl and changes color. (The actual composition of AuAl₂ is closer to Al₁₁Au₆ as the sublattice is incompletely occupied.)^[2]

Blue gold is an alloy of gold and indium.^[7] It contains 46% gold (about 12 ct) and 54% indium,^[1] forming an intermetallic compound AuIn₂, with a clear blue color. With gallium, gold forms an intermetallic AuGa₂ (58.5% Au, 14ct) which has slight bluish hue. The melting point of AuIn₂ is 541 °C, for AuGa₂ it is 492 °C. AuIn₂ is less brittle than AuGa₂, which itself is less brittle than AuAl₂.^[9]

All the AuX₂ intermetallics have crystal structure of CaF₂ and therefore are brittle.^[2] Deviation from the stoichiometry results in loss of color. Slightly nonstoichiometric compositions are however used, to achieve a fine-grained two- or three-phase microstructure with reduced brittleness. A small amount of palladium, copper or silver can be added to achieve a less brittle microstructure.^[9]

The intermetallic compounds tend to have poor corrosion resistance. The less noble elements are leached to the environment, and a gold-rich surface layer is formed. Direct contact of blue and purple gold elements with skin should be avoided as exposition to sweat may result in metal leaching and discoloration of the metal surface.^[9]

A surface plating of blue gold on karat gold or sterling silver can be achieved by a gold plating of the surface, followed by indium plating, with layer thickness matching the 1:2 atomic ratio. A heat treatment then causes interdiffusion of the metals and formation of the required intermetallic compound.

Oxide layer blue gold

Blue gold can be achieved by formation of an oxide layer on an alloy of 75% gold, 24.4% iron, and 0.6% nickel; the layer forms on heat treatment in air between 450–600 °C.^[2]

Gold of purity 20–23 carat, when alloyed with ruthenium, rhodium and three other elements and heat-treated at 1800 °C, forms a 3–6 micrometers thick surface layer with a rich sapphire blue color.^[2]

See also

• Tumbaga
• Electrum
• Crown gold
• List of alloys

References

1. ^ ^{a b c d e f} John Emsley Nature's building blocks: an A-Z guide to the elements p. 168, Oxford University Press (2003) ISBN 0198503407
2. ^ ^{a b c d e f g h i j k} Cristian Cretu and Elma van der Lingen Coloured Gold Alloys, Gold Bulletin (1999) 32, 4, 115
3. ^ White Gold - Site provided by the World Gold Council
4. ^ 18 karat grey gold alloy, without nickel and without palladium, for jewellery - Patent 6576187
5. ^ "Jewelery Technology". http://www.gold.org/jewellery/technology/colours/special.html. Retrieved 2007-11-21. 
6. ^ W.S. Rapson (1978), Gold Usage, Academic Press, ISBN 0125812507 
7. ^ ^{a b c} "Gold In Purple Color, Blue Color And Even Black Gold". http://www.newsletter.kaijewels.com/gold-colors.htm. Retrieved 2007-11-21. 
8. ^ "Ultra-Intense Laser Blast Creates True 'Black Metal'". http://www.rochester.edu/news/show.php?id=2701. Retrieved 2007-11-21. 
9. ^ ^{a b c} Ulrich E. Klotz Metallurgy and processing of coloured gold intermetallics – Part I: Properties and surface processing Gold Bulletin (2010) 43, 1, 4