- Organoxenon compound
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Organoxenon compounds in organic chemistry contain carbon to xenon chemical bonds. Early synthesized organoxenon compound are all based on xenon difluoride, such as (C6F5)2Xe. The first tetravalent organoxenon compound [C6F5XeF2][BF4] was synthesized in 2004.[1] So far, more than one hundred organoxenon compounds have been researched.
Most of the organoxenon compounds are more unstable than xenon fluorides due to the high polarity. The molecular dipoles of xenon difluoride and xenon tetrafluoride are both 0 D. The early synthesized ones only contain perfluoro groups, but later some other groups were found, e.g. 2,4,6-trifluorophenyl.[2]
Contents
Xe(II)
The most common bivalent organoxenon compound is C6F5XeF, which is always used as a precursor to other organoxenon compounds. Due to the unstability of xenon fluoride, it is impossible to synthesize organoxenon compound by using general organic reagents. Most frequently used fluorinating agents include Cd(ArF)2(subscript "F" means fluorine-including aryl), C6F5SiF3, and C6F5SiMe3 (should be used along with fluoride).
With the use of stronger lewis acids, such as C6F5BF2, ionic compounds like [RXe][ArFBF3] can be produced. Alkenyl and alkyl organoxenon compounds are prepared in this way as well, for example, C6F5XeCF=CF2 and C6F5CF3[2].
Some typical reactions are listed below:
The third reaction also produces (C6F5)2Xe, Xe(2,4,6-C6H2F3)2 and so on.
The precursor C6F5XeF can be prepared by the reaction of trimethyl(pentaflurophenyl)silane(C6F5SiMe3) and xenon difluoride. Adding fluoride to the adduct of C6F5XeF and arsenic pentafluoride is another method[2].
Xe(IV)
See also
- Compounds of carbon with other elements in the periodic table:
CH He CLi CBe CB CC CN CO CF Ne CNa CMg CAl CSi CP CS CCl CAr CK CCa CSc CTi CV CCr CMn CFe CCo CNi CCu CZn CGa CGe CAs CSe CBr CKr CRb CSr CY CZr CNb CMo CTc CRu CRh CPd CAg CCd CIn CSn CSb CTe CI CXe CCs CBa CHf CTa CW CRe COs CIr CPt CAu CHg CTl CPb CBi CPo CAt Rn Fr Ra Rf Db Sg Bh Hs Mt Ds Rg Cn Uut Uuq Uup Uuh Uus Uuo ↓ CLa CCe CPr CNd CPm CSm CEu CGd CTb CDy CHo CEr CTm CYb CLu Ac Th Pa CU Np Pu Am Cm Bk Cf Es Fm Md No Lr Chemical bonds to carbon Core organic chemistry Many uses in chemistry Academic research, but no widespread use Bond unknown / not assessed References
- ^ "The First Organoxenon(IV) Compound: Pentafluorophenyldifluoroxenonium(IV) Tetrafluoroborate". Angewandte Chemie International Edition 39 (2): 391–393. 2000-01-16. doi:10.1002/(SICI)1521-3773(20000117)39:2<391::AID-ANIE391>3.0.CO;2-U.
- ^ a b c FROHN, H (2004-05-31). "C6F5XeF, a versatile starting material in xenon-carbon chemistry". Journal of Fluorine Chemistry 125 (6): 981–988. doi:10.1016/j.jfluchem.2004.01.019.
Categories:- Xenon compounds
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