Heptane

n-Heptane
Identifiers
CAS number	142-82-5 Y
PubChem	8900
ChemSpider	8560 Y
UNII	456148SDMJ Y
ChEBI	CHEBI:43098 Y
ChEMBL	CHEMBL134658 Y
RTECS number	MI7700000
Jmol-3D images	Image 1
SMILES CCCCCCC
InChI InChI=1S/C7H16/c1-3-5-7-6-4-2/h3-7H2,1-2H3 Y Key: IMNFDUFMRHMDMM-UHFFFAOYSA-N Y InChI=1/C7H16/c1-3-5-7-6-4-2/h3-7H2,1-2H3 Key: IMNFDUFMRHMDMM-UHFFFAOYAU
Properties
Molecular formula	C7H16
Molar mass	100.21 g/mol
Appearance	colourless liquid
Density	0.684 g/ml, liquid
Melting point	−90.61 °C (182.55 K)
Boiling point	98.42 °C (371.58 K)
Solubility in water	Immiscible
Viscosity	0.386 cP at 25 °C
Hazards
EU classification	Flammable (F) Harmful (Xn) Dangerous for the environment (N)
R-phrases	R11, R38, R50/53, R65, R67
S-phrases	(S2), S9, S16, S29, S33, S60, S61, S62
NFPA 704	3 1 0
Flash point	−4 °C
Autoignition temperature	220 °C
Related compounds
Related alkanes	Hexane Octane
Related compounds	Methylcyclohexane Cycloheptane
Y (verify) (what is: Y/N?) Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Infobox references

n-Heptane is the straight-chain alkane with the chemical formula H₃C(CH₂)₅CH₃ or C₇H₁₆. When used as a test fuel component in anti-knock test engines, a 100% heptane fuel is the zero point of the octane rating scale (the 100 point is a 100% iso-octane). Octane number equates to the anti-knock qualities of a comparison mixture of heptane and isooctane which is expressed as the percentage of isooctane in heptane and is listed on pumps for gasoline dispensed in the United States and internationally.

Uses

Heptane (and its many isomers) is widely applied in laboratories as a totally non-polar solvent. As a liquid, it is ideal for transport and storage. In the grease spot test, heptane is used to dissolve the oil spot to show the previous presence of organic compounds on a stained paper. This is done by shaking the stained paper in a heptane solution for about half a minute.^{[citation needed]}

Aqueous bromine may be distinguished from aqueous iodine by its appearance after extraction into heptane. In water, both bromine and iodine appear brown. However, iodine turns purple when dissolved in heptane, whereas the bromine solution remains brown.

Heptane is commercially available as mixed isomers for use in paints and coatings, as the rubber cement solvent "Bestine", the outdoor stove fuel "Powerfuel" by Primus, as pure n-Heptane for research and development and pharmaceutical manufacturing and as a minor component of gasoline.

Octane rating scale

n-Heptane is the zero point of the octane rating scale. It is undesirable in petrol, because it burns explosively, causing engine knocking, as opposed to branched-chain octane isomers, which burn more slowly and give better performance. It was chosen as the zero point of the scale because of the availability of very high purity n-heptane, unmixed with other isomers of heptane or other alkanes, distilled from the resin of Jeffrey Pine and from the fruit of Pittosporum resiniferum. Other sources of heptane and octane, produced from crude oil, contain a mixture of different isomers with greatly differing ratings and do not give as precise a zero point. ChevronPhillips Specialty Chemical produces a specialized grade of high purity n-Heptane (>99.0%) from crude oil through precision refining and distillation that is used in the measurement of octane rating for fuels.

Isomers and enantiomers

Heptane has nine isomers, or eleven if enantiomers are counted:

• Heptane (n-heptane), H₃C–CH₂–CH₂–CH₂–CH₂–CH₂–CH₃,
• 2-Methylhexane (isoheptane), H₃C–CH(CH₃)–CH₂–CH₂–CH₂–CH₃,
• 3-Methylhexane, H₃C–CH₂–C^*H(CH₃)–CH₂–CH₂–CH₃ (chiral),
• 2,2-Dimethylpentane (neoheptane), (H₃C)₃–C–CH₂–CH₂–CH₃,
• 2,3-Dimethylpentane, (H₃C)₂–CH–C^*H(CH₃)–CH₂–CH₃ (chiral),
• 2,4-Dimethylpentane, (H₃C)₂–CH–CH₂–CH–(CH₃)₂,
• 3,3-Dimethylpentane, H₃C–CH₂–C(CH₃)₂–CH₂–CH₃,
• 3-Ethylpentane, H₃C–CH₂–CH(CH₂CH₃)–CH₂–CH₃,
• 2,2,3-Trimethylbutane, CH₃–C(CH₃)₂–CH(CH₃)–CH₃, this isomer is also known as pentamethylethane and triptane.^[1]

References

1. ^ [1]

External links

• International Chemical Safety Card 0657 (n-heptane)
• International Chemical Safety Card 0658 (2-methylhexane)
• NIOSH Pocket Guide to Chemical Hazards
• Material Safety Data Sheet for Heptane
• Phytochemical database entry