Paper

For other uses, see Paper (disambiguation).

A stack of copy paper

Paper is a thin material mainly used for writing upon, printing upon, drawing or for packaging. It is produced by pressing together moist fibers, typically cellulose pulp derived from wood, rags or grasses, and drying them into flexible sheets.

Paper is a versatile material with many uses. Whilst the most common is for writing and printing upon, it is also widely used as a packaging material, in many cleaning products, in a number of industrial and construction processes, and even as a food ingredient – particularly in Asian cultures.

Paper, and the pulp papermaking process, was said to be developed in China during the early 2nd century AD by the Han court eunuch Cai Lun, although the earliest archaeological fragments of paper derive from the 2nd century BC in China.^[1]

History

Main article: History of paper

Further information: Science and technology of the Han Dynasty and List of Chinese inventions

Hemp wrapping paper, China, circa 100 BCE.

The oldest known archaeological fragments of the immediate precursor to modern paper date to 2nd century BC China. Papermaking is considered one of the Four Great Inventions of China, and the pulp papermaking process is ascribed to Cai Lun, a 2nd century AD Han court eunuch.^[1] With paper an effective substitute for silk in many applications, China could export silk in greater quantity, contributing to a Golden Age.

Paper spread from China through the Islamic world to medieval Europe in the 13th century, where the first water-powered paper mills were built.^[2] In the 19th century, industrial manufacture greatly lowered its cost, enabling mass exchange of information and contributing to significant cultural shifts. In 1844, Canadian inventor Charles Fenerty and German F.G. Keller independently developed processes for pulping wood fibers.^[3]

Etymology

Further information: Papyrus

The word "paper" is etymologically derived from Latin papyrus, which comes from the Greek πάπυρος (papuros), the word for the Cyperus papyrus plant.^[4][5] Papyrus is a thick, paper-like material produced from the pith of the Cyperus papyrus plant which was used in ancient Egypt and other Mediterranean cultures for writing before the introduction of paper into the Middle East and Europe.^[6] Although paper is etymologically derived from papyrus, the two are produced very differently and the development of modern paper is separate from the development of papyrus. Papyrus is a "lamination of natural plants, while paper is manufactured from fibres whose properties have been changed by maceration or disintegration.^[1]

Papermaking

Main article: Papermaking

Chemical pulping

Main articles: kraft process, sulfite process, and soda pulping

The purpose of a chemical pulping process is to break down the chemical structure of lignin and render it soluble in the cooking liquor, so that it may be washed from the cellulose fibers. Because lignin holds the plant cells together, chemical pulping frees the fibres and makes pulp. The pulp can also be bleached to produce white paper for printing, painting and writing. Chemical pulps tend to cost more than mechanical pulps, largely due to the low yield, 40–50% of the original wood. Since the process preserves fibre length, however, chemical pulps tend to make stronger paper. Another advantage of chemical pulping is that the majority of the heat and electricity needed to run the process is produced by burning the lignin removed during pulping.

The microscopic structure of paper: Micrograph of paper autofluorescing under ultraviolet illumination. The individual fibres in this sample are around 10 µm in diameter.

Paper made from chemical pulps are also known as wood-free papers. Not to be confused with tree-free paper.

The kraft process is the most commonly practiced strategy for pulp manufacturing and produces especially strong, unbleached papers that can be used directly for bags and boxes but are often processed further, e.g. to make corrugated cardboard.

Mechanical pulping

There are two major mechanical pulps, thermo mechanical pulp (TMP) and groundwood pulp (GW). In the TMP process, wood is chipped and then fed into large steam-heated refiners where the chips are squeezed and made into fibres between two steel discs. In the groundwood process, debarked logs are fed into grinders where they are pressed against rotating stones and made into fibres. Mechanical pulping does not remove the lignin, so the yield is very high, >95%, but also causes paper made from this pulp to yellow and become brittle over time. Mechanical pulps have rather short fibre lengths and produce weak paper. Although large amounts of electrical energy are required to produce mechanical pulp, it costs less than chemical pulp.

Deinked pulp

Main article: deinking

Paper recycling processes can use either chemical or mechanical pulp. By mixing with water and applying mechanical action the hydrogen bonds in the paper can be broken and fibres separated again. Most recycled paper contains a proportion of virgin fibre in the interests of quality. Generally deinked pulp is of the same quality or lower than the collected paper it was made from.

There are three main classifications of recycled fibre:.

• Mill broke or internal mill waste – this incorporates any substandard or grade-change paper made within the paper mill which then goes back into the manufacturing system to be re-pulped back into paper. Such out-of-specification paper is not sold and is therefore often not classified as genuine reclaimed recycled fibre. However, most paper mills have been recycling their own waste fibre for many years, long before recycling become popular.
• Preconsumer waste – this is offcuts and processing waste, such as guillotine trims and envelope blank waste. This waste is generated outside the paper mill and could potentially go to landfill, and is a genuine recycled fibre source. Also includes de-inked preconsumer (recycled material that has been printed but did not reach its intended end use, such as waste from printers and unsold publications).^[7]
• Postconsumer waste – this is fibre from paper which has been used for its intended end use and would include office waste, magazine papers and newsprint. As the vast majority of this paper has been printed (either digitally or by more conventional means such as lithography or rotogravure), it will either be recycled as printed paper or go through a deinking process first.

Recycled papers can be made from 100% recycled materials or blended with virgin pulp. They are (generally) not as strong nor as bright as papers made from virgin pulp.

Additives

Besides the fibres, pulps may contain fillers such as chalk or china clay, which improve the characteristics of the paper for printing or writing. Additives for sizing purposes may be mixed into the pulp and/or applied to the paper web later in the manufacturing process. The purpose of sizing is to establish the correct level of surface absorbency to suit the ink or paint.

Producing paper

Main articles: Papermachine and handmade paper

See also: Air-laid paper

The pulp is feed to a paper machine where it is formed as a paper web and the water is removed from it by pressing and drying.

Pressing the sheet removes the water by force. Once the water is forced from the sheet, felt (not to be confused with the traditional felt) is used to collect the water. When making paper by hand, a blotter sheet is used.

Drying involves using air and or heat to remove water from the paper sheet. In the earliest days of papermaking this was done by hanging the paper sheets like laundry. In more modern times, various forms of heated drying mechanisms are used. On the paper machine, the most common is the steam-heated can dryer. These dryers can heat to temperatures above 200 °F (93 °C) and are used in long sequences of more than 40 cans. The heat produced by these can easily dry the paper to less than 6% moisture.

Finishing

The paper may then undergo sizing to alter its physical properties for use in various applications.

Paper at this point is uncoated. Coated paper has a thin layer of material such as calcium carbonate or china clay applied to one or both sides in order to create a surface more suitable for high-resolution halftone screens. (Uncoated papers are rarely suitable for screens above 150 lpi.) Coated or uncoated papers may have their surfaces polished by calendering. Coated papers are divided into matte, semi-matte or silk, and gloss. Gloss papers give the highest optical density in the printed image.

The paper is then fed onto reels if it is to be used on web printing presses, or cut into sheets for other printing processes or other purposes. The fibres in the paper basically run in the machine direction. Sheets are usually cut "long-grain", i.e. with the grain parallel to the longer dimension of the sheet.

All paper produced by paper machines as the Fourdrinier Machine are wove paper, i.e. the wire mesh that transports the web leaves a pattern that has the same density along the paper grain and across the grain. Textured finishes, watermarks and wire patterns imitating hand-made laid paper can be created by the use of appropriate rollers in the later stages of the machine.

Wove paper does not exhibit "laidlines", which are small regular lines left behind on paper when it was handmade in a mould made from rows of metal wires or bamboo. Laidlines are very close together. They run perpendicular to the "chainlines", which are further apart. Handmade paper similarly exhibits "deckle edges", or rough and feathery borders.^[8]

Applications

Paper can be produced with a wide variety of properties, depending on its intended use.^[9]

• For representing value: paper money, bank note, cheque, security (see security paper), voucher and ticket
• For storing information: book, notebook, magazine, newspaper, art, zine, letter
• For personal use: diary, note to remind oneself, etc.; for temporary personal use: scratch paper
• For communication: between individuals and/or groups of people.
• For packaging: corrugated box, paper bag, envelope, wrapping tissue, Charta emporetica and wallpaper
• For cleaning: toilet paper, handkerchiefs, paper towels, facial tissue and cat litter
• For construction: papier-mâché, origami, paper planes, quilling, paper honeycomb, used as a core material in composite materials, paper engineering, construction paper and paper clothing
• For other uses: emery paper, sandpaper, blotting paper, litmus paper, universal indicator paper, paper chromatography, electrical insulation paper (see also dielectric and permittivity) and filter paper

Types, thickness and weight

Card and paper stock for craft use comes in a wide variety of textures and colors.

Main articles: Paper size and Paper density

The thickness of paper is often measured by caliper, which is typically given in thousandths of an inch.^[10] Paper may be between 0.07 millimetres (0.0028 in) and 0.18 millimetres (0.0071 in) thick.^[11]

Paper is often characterized by weight. In the United States, the weight assigned to a paper is the weight of a ream, 500 sheets, of varying "basic sizes", before the paper is cut into the size it is sold to end customers. For example, a ream of 20 lb, 8.5 × 11 in (216 × 279 mm) paper weighs 5 pounds, because it has been cut from a larger sheet into four pieces.^[12] In the United States, printing paper is generally 20 lb, 24 lb, or 32 lb at most. Cover stock is generally 68 lb, and 110 lb or more is considered card stock.

In Europe, and other regions using the ISO 216 paper sizing system, the weight is expressed in grammes per square metre (g/m² or usually just g) of the paper. Printing paper is generally between 60 g and 120 g. Anything heavier than 160 g is considered card. The weight of a ream therefore depends on the dimensions of the paper and its thickness.

Most commercial paper sold in North America is cut to standard paper sizes based on customary units and is defined by the length and width of a sheet of paper.

The ISO 216 system used in most other countries is based on the surface area of a sheet of paper, not on a sheet's width and length. It was first adopted in Germany in 1922 and generally spread as nations adopted the metric system. The largest standard size paper is A0 (A zero), measuring one square meter (approx. 1189x841 mm). Two sheets of A1, placed upright side by side fit exactly into one sheet of A0 laid on its side. Similarly, two sheets of A2 fit into one sheet of A1 and so forth. Common sizes used in the office and the home are A4 and A3 (A3 is the size of two A4 sheets).

The density of paper ranges from 250 kg/m³ (16 lb/cu ft) for tissue paper to 1,500 kg/m³ (94 lb/cu ft) for some speciality paper. Printing paper is about 800 kg/m³ (50 lb/cu ft).^[13]

Paper may be classified into seven categories^[14] :

• Printing papers of wide variety.
• Wrapping papers for the protection of goods and merchandise. This includes wax and kraft papers.
• Writing paper suitable for stationary requirements. This includes ledger, bank, and bond paper.
• Blotting papers containing little or no size.
• Drawing papers usually with rough surfaces used by artists and designers, including cartridge paper.
• Handmade papers including most decorative papers, Ingres papers, Japanese paper and tissues, all characterized by lack of grain direction.
• Specialty papers including cigarette paper, toilet tissue, and other industrial papers.

Some paper types include:

Bank paper Banana paper Bond paper Book paper Coated paper: glossy and matte surface Construction paper/sugar paper Cotton paper Electronic paper

Fish paper (vulcanized fibres for electrical insulation) Inkjet paper Kraft paper Laid paper Leather paper Mummy paper Sandpaper

Tyvek paper Wallpaper Washi Waterproof paper Wax paper Wove paper Xuan paper

Paper stability

Much of the early paper made from wood pulp contained significant amounts of alum, a variety of aluminium sulfate salts that are significantly acidic. Alum was added to paper to assist in sizing the paper,^[15] making it somewhat water resistant so that inks did not "run" or spread uncontrollably. The early papermakers did not realize that the alum they added liberally to cure almost every problem encountered in making their product would eventually be detrimental.^[16] The cellulose fibres which make up paper are hydrolyzed by acid, and the presence of alum would eventually degrade the fibres until the paper disintegrated in a process which has come to be known as "slow fire". Documents written on rag paper were significantly more stable. The use of non-acidic additives to make paper is becoming more prevalent and the stability of these papers is less of an issue.

Paper made from mechanical pulp contains significant amounts of lignin, a major component in wood. In the presence of light and oxygen lignin reacts to give yellow materials, which is why newsprint and other mechanical paper yellows with age. Paper made from bleached kraft or sulfite pulps does not contain significant amounts of lignin and is therefore better suited for books, documents and other applications where whiteness of the paper is essential.

It is important to note that just because a paper is made of wood pulp, does not necessarily mean it is any less durable than a rag paper. The factor that determines the ageing behavior of a paper is how it was manufactured, not the original source of the fibres.^[17] Furthermore, tests sponsored by the Library of Congress prove that all paper is at risk of acid decay, because cellulose itself produces formic, acetic, lactic and oxalic acids.^[18]

Mechanical pulping yields almost a tonne of pulp per tonne of dry wood used (which is why mechanical pulps are sometimes referred to as "high yield" pulps), which is about twice as much as chemical pulping. Consequently, paper made with mechanical pulps is often cheaper than that made with bleached chemical pulps. Mass-market paperback books and newspapers use these mechanical papers. Book publishers tend to use acid-free paper, made from fully bleached chemical pulps for hardback and trade paperback books.

The future of paper

Some manufacturers have started using a new, significantly more environmentally friendly alternative to expanded plastic packaging made out of paper, known commercially as paperfoam. The packaging has very similar mechanical properties to some expanded plastic packaging, but is biodegradable and can also be recycled with ordinary paper.^[19]

With increasing environmental concerns about synthetic coatings (such as PFOA) and the higher prices of hydrocarbon based petrochemicals, there is a focus on zein (corn protein) as a coating for paper in high grease applications such as popcorn bags.^[20]

Also, synthetics such as Tyvek and Teslin have been introduced as printing media as a more durable material than paper.

See also

Arches paper Buckypaper Deinked pulp Fiber crop Graphene oxide paper Origami Paper and ink testing

Paper engineering Paper recycling Paper size, sizing Paper chemicals Paper towels Papier-mâché

Papier "paper" in French or German Papyrus Roll hardness tester Security paper Seed paper Toilet paper Wood Pulp

References and notes

1. ^ ^{a b c} Tsien 1985, p. 38
2. ^ Burns 1996, pp. 417f.
3. ^ Burger, Peter. Charles Fenerty and his Paper Invention. Toronto: Peter Burger, 2007. ISBN 978-0-9783318-1-8 pp.25-30
4. ^ πάπυρος, Henry George Liddell, Robert Scott, A Greek-English Lexicon, on Perseus
5. ^ papyrus, on Oxford Dictionaries
6. ^ "Papyrus definition". Dictionary.com. http://dictionary.reference.com/browse/Papyrus. Retrieved 2008-11-20. 
7. ^ Natural Resource Defense Council
8. ^ "Document Doubles" in Detecting the Truth: Fakes, Forgeries and Trickery, a virtual museum exhibition at Library and Archives Canada
9. ^ "Grades and uses of paper". http://www.paperonweb.com/grade11.htm. Retrieved 2007-10-12. 
10. ^ "Paper Thickness Chart", Case Paper Company Inc.
11. ^ "Thickness of a Piece of Paper", HyperTextbook.com
12. ^ McKenzie, Bruce G., The Hammermill Guide to Desktop Publishing in Business, p. 144, Hammermill Papers, 1989.
13. ^ "Density of paper and paperboard". PaperOnWeb. http://www.paperonweb.com/density.htm. Retrieved 2007-10-31. 
14. ^ Johnson, Arthur (1978). The Thames and Hudson Manual of Bookbinding. London: Thames and Hudson. 
15. ^ Biermann, Christopher J. (1993). Handbook of Pulping and Papermaking. San Diego: Academic Press. ISBN 0-12-097360-X. 
16. ^ Clark, James d'A. (1985). Pulp Technology and Treatment for Paper, 2nd ed.. San Francisco: Miller Freeman Publications. ISBN 0-87930-164-3. 
17. ^ Erhardt, D. & C. Tumosa (2005). Chemical Degradation of Cellulose in Paper over 500 years. Restaurator: International Journal for the Preservation of Library and Archival Material. 26: 155.
18. ^ Library of Congress. (2006). The Deterioration and Preservation of Paper: Some Essential Facts, Retrieved November 4, 2007, from http://www.loc.gov/preserv/deterioratebrochure.html.
19. ^ PaperFoam Carbon Friendly Packaging
20. ^ Barrier compositions and articles produced with the compositions cross-reference to related application

• Burns, Robert I. (1996). "Paper comes to the West, 800−1400". In Lindgren, Uta. Europäische Technik im Mittelalter. 800 bis 1400. Tradition und Innovation (4th ed.). Berlin: Gebr. Mann Verlag. pp. 413–422. ISBN 3-7861-1748-9 
• Tsien, Tsuen-Hsuin (1985). Paper and Printing. Joseph Needham, Science and Civilisation in China, Chemistry and Chemical Technology. Vol. 5 part 1. Cambridge University Press 
• "Document Doubles" in Detecting the Truth: Fakes, Forgeries and Trickery, a virtual museum exhibition at Library and Archives Canada

External links

• TAPPI Technical Association of the Pulp and Paper Industry
• How is paper made? at The Straight Dope, 22 November 2005
• Papar Toys
• United States Government Printing Office: Government Paper Specification Standards
• How Organic Paper is Made