Stilbite

Stilbite
Stilbite from Kiui Island, Alaska, USA
General
Category	Zeolite
Chemical formula	Stilbite-Ca: NaCa4(Si27Al9)O72·28(H2O) Stilbite-Na: Na9(Si27Al9)O72·28(H2O)
Strunz classification	8/J.23-30 or 9.GE.10
Dana classification	77.1.4.3
Identification
Molar mass	Stilbite-Ca: 2,840 gm Stilbite-Na: 2,864 gm
Color	Usually colorless, white or pink
Crystal habit	Thin tabular, aggregates sheaf-like or in bow-ties, also fibrous and globular.
Crystal system	Monoclinic 2/m, also triclinic and orthorhombic
Twinning	Very common on {001}
Cleavage	Perfect on {010}
Fracture	Conchoidal or uneven
Tenacity	Brittle
Mohs scale hardness	3½ to 4
Luster	Vitreous, pearly on {010}
Streak	White
Diaphaneity	Transparent to translucent
Specific gravity	2.12 to 2.22
Optical properties	Biaxial (-)
Refractive index	Nx = 1.479 to 1.492, Ny = 1.485 to 1.500, Nz = 1.489 to 1.505[1][2] Nx = 1.484 to 1.500, Ny = 1.492 to 1.507, Nz = 1.494 to 1.513[3][4]
Fusibility	Easily fused by blowpipe (~1050 °C) to produce a white "enamel"[5]
Solubility	Decomposes in HCl[5]
References	[2] [3] [4] [6] [7] [8]

Stilbite is the name of a series of tectosilicate minerals of the zeolite group. Prior to 1997, stilbite was recognized as a mineral species, but a reclassification in 1997 by the International Mineralogical Association changed it to a series name, with the mineral species being named:

• stilbite-Ca
• stilbite-Na

Stilbite-Ca, by far the more common of the two, is a hydrous calcium sodium and aluminium silicate, NaCa₄(Si₂₇Al₉)O₇₂·28(H₂O). In the case of stilbite-Na, sodium dominates over calcium. The species are visually indistinguishable, and the series name stilbite is still used whenever testing has not been performed.

History

At one time heulandite and stilbite were considered to be identical minerals. After they were found to be two separate species, in 1818, the name desmine ("a bundle") was proposed for stilbite, and this name is still employed in Germany. The English name "stilbite" is from the Greek stilbein = to shine, because of the pearly luster of the {010} faces.

Chemistry and related species

Stilbite shows a wide variation in exchangeable cations (positively charged ions). Silicon, Si, ions and aluminium, Al, ions occupy equivalent sites, and can substitute for each other, but they have a different charge (Si⁴⁺ and Al³⁺) so the ions occupying the Na/Ca site have to adjust to maintain charge balance. There is a continuous series between stellerite, whose formula can be written as Ca₄(Si₂₈Al₈)O₇₂·28(H₂O), and stilbite, and another a continuous series between stilbite and barrerite, Na₈(Si₂₈Al₈)O₇₂·26(H₂O).

Epistilbite is a distinct zeolite species unrelated to stilbite.

Crystal class

Stilbite is usually monoclinic 2/m, meaning that it has one twofold axis of rotational symmetry perpendicular to a mirror plane. The twofold axis is the crystal axis b, and the a and c crystal axes lie in the mirror plane. For a monoclinic crystal a and c are inclined to each other at an angle β which is not a right angle. For stilbite β is nearly 130°. Stilbite crystals, however, appear to be almost orthorhombic, and a larger unit cell can be chosen, containing two formula units (Z = 2) such that it looks like an orthorhombic cell, with all three crystal axes very nearly mutually perpendicular. The mineral is said to be pseudo-orthorhombic.

Non-endmember forms of stilbite may be triclinic or even truly orthorhombic, indeed the framework can have symmetry ranging from orthorhombic to triclinic in a single crystal.^[1]

Habit

Crystals are typically thin tabular, flattened parallel to the dominant cleavage and elongated along the a axis. Aggregates may be sheaf-like or in bow-ties, also fibrous and globular.^[1] Twinning, cruciform and penetration, is extremely common on {001}.^[6]

Physical and optical properties

The color is usually colorless or white, also yellow, brown, pink, salmon, orange, red, green, blue or black. The luster is generally vitreous, and on the perfect cleavage parallel to the plane of symmetry it is markedly pearly. The streak is white and crystals are transparent to translucent. The hardness is 3½ to 4 and the specific gravity 2.12 to 2.22. Cleavage is perfect on {010}, poor on {001}.^[1] The mineral is brittle, with a conchoidal or uneven fracture. It is not radioactive.

Stilbite is biaxial (-) with refractive indices:

• Nx = 1.479 to 1.492, Ny = 1.485 to 1.500, Nz = 1.489 to 1.505^[1][2]
• Nx = 1.484 to 1.500, Ny = 1.492 to 1.507, Nz = 1.494 to 1.513^[3][4]

Unit cell and structure

Where sources give cell parameters for stilbite-Na, they are the same as those for stilbite-Ca.

The unit cell can be considered as a monoclinic cell with β close to 130° and one formula unit per unit cell (Z = 1), or as a larger pseudo-orthorhombic cell with β close to 90° and Z = 2.
Cell Parameters for the monoclinic cell:

• a = 13.595 to 13.69 Å, b = 18.197 to 18.31 Å, c = 11.265 to 11.30 Å, β = 127.94 to 128.1°^[6]
• a = 13.63 Å, b = 18.17 Å, c = 11.31 Å, β = 129.166°^[2][3][7][8]
• a = 13.60 to 13.69 Å, b = 18.20 to 18.31 Å, c = 11.27 Å, β = 128°^[1]

Cell parameters for the pseudo-orthorhombic cell:

• a = 13.595 to 13.69 Å, b = 18.197 to 18.31 Å, c = 17.775 to 17.86 Å, β = 90.00 to 90.91°^[6]
• a = 13.595 to 13.657 Å, b = 18.197 to 18.309 Å, c = 17.775 to 17.842 Å, β = 90:05 to 90.91°^[4] (Z is doubled to Z = 4 because the formula unit halved to NaCa₂Al₅Si₁₃O₃₆.14H₂O)
• a=13.69 Å, b=18.25 Å, c=11.31 Å, β =128.2°^[9]
• a = 13.60 to 13.69 Å, b = 18.20 to 18.31 Å, c = 17.78 to 17.86 Å, β = 90.0 to 90.91°^[1]

The framework of stilbite is pseudo-orthorhombic with the open channels typical of zeolites. It has 10-member rings and 8-member rings forming channels parallel to a and pseudo-orthorhombic c respectively.^[9]

Uses

The open channels in the stilbite structure act like a molecular sieve, enabling it to separate hydrocarbons in the process of petroleum refining.

Environment

Stilbite is a low-temperature secondary hydrothermal mineral. It occurs in the amygdaloidal cavities of basaltic volcanic rocks, in andesites, gneiss and hydrothermal veins. It also forms in hot springs deposits, and as a cementing agent in some sandstones and conglomerates.^[4] Stilbite has not been found in sedimentary tuff deposits or deep-sea deposits.^[1] Associated minerals are other zeolites, prehnite, calcite and quartz.^[4]

Localities

Stilbite is abundant in the volcanic rocks of Iceland, Faroe Islands, Isle of Skye, Bay of Fundy, Nova Scotia, northern New Jersey and North Carolina. Salmon-pink crystals occur with pale green apophyllite in the Deccan Traps near Mumbai (Bombay) and Pune, India; white sheaf-like groups encrust the calcite (Iceland-spar) of Berufjord near Djupivogr in Iceland; brown sheafs are found near Paterson, New Jersey in the United States; and crystals of a brick-red color are found at Old Kilpatrick, Scotland.^[10]

Iceland is generally considered to be the type locality for stilbite-Ca. It is presumed to be the Helgusta Iceland Spar Mine, along Reydarfjordur. Excellent white bow ties of stilbite are found here on calcite and quartz, associated with heulandite and laumontite in cavities.^[1]

The type locality for stilbite-Na is Cape Pula, Pula, Cagliari Province, Sardinia, Italy. Small, lustrous, white or pink, pointed blades of stilbite-Na, and formless masses, up to 5 cm in diameter, have been found there, covering a thin crust of reddish heulandite in large fractures and cavities in the highly weathered volcanic andesite or rhyolite.

The Tertiary Deccan basalts of western India are the most prolific sources of stilbite in the world. Stilbite is the most abundant zeolite in the tholeiitic basalt plateaux near Nasik and Pune and decreases in abundance toward the coast at Mumbai.^[1]

Photo gallery

• 

  Intergrown, doubly terminated stilbite crystals from the Pune District of India.

• 

  Intergrown pinkish stilbite crystals showing the "bow-tie" habit from Jalgaon District, Maharashtra, India.

• 

  Stilbite crystals aggreagates in fans shapes from Wassons Bluff, Nova Scotia.

References

1. ^ ^{a b c d e f g h i j} Rudy W. Tschernich (1992) Zeolites of the World. Geoscience Press
2. ^ ^{a b c d} http://webmineral.com/data/Stilbite-Ca.shtml
3. ^ ^{a b c d} http://www.mindat.org/min-7313.html stilbite-Ca
4. ^ ^{a b c d e f} http://www.handbookofmineralogy.org/pdfs/stilbiteca.pdf
5. ^ ^{a b} Klein, Cornelis and Cornelius S. Hurlbut, 1985, Manual of Mineralogy, Wiley, pp. 465–466 ISBN 0-471-80580-7
6. ^ ^{a b c d} Gaines et al (1997) Dana’s New Mineralogy Eighth Edition. Wiley
7. ^ ^{a b} http://www.mindat.org/min-7314.html stilbite-Na
8. ^ ^{a b} http://webmineral.com/data/Stilbite-Na.shtml
9. ^ ^{a b} American Mineralogist (1970) 55: 387–397
10. ^ Spencer 1911.

Attribution

•  This article incorporates text from a publication now in the public domain: Spencer, Leonard James (1911). "Stilbite". In Chisholm, Hugh. Encyclopædia Britannica (11th ed.). Cambridge University Press. 

External links

• Jmol: http://rruff.geo.arizona.edu/AMS/viewJmol.php?id=00200