Dithiolane

Dithiolane: Dithiolane

IUPAC name

Dithiolane

Other names

1,2-dithiolane, 1,3-dithiolane

Identifiers

PubChem 79045

ChemSpider 71377^Y

ChEBI CHEBI:38226^Y

Jmol-3D images Image 1

SMILES

S1SCCC1

InChI

InChI=1S/C3H6S2/c1-2-4-5-3-1/h1-3H2^Y
Key: MUZIZEZCKKMZRT-UHFFFAOYSA-N^Y
InChI=1/C3H6S2/c1-2-4-5-3-1/h1-3H2
Key: MUZIZEZCKKMZRT-UHFFFAOYAH

Properties

Molecular formula C₃H₆S₂

Related compounds

Related compounds 1,2-Ethanedithiol

Y (verify) (what is: Y/N?)
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)

Infobox references

A dithiolane is a sulfur heterocycle derived from cyclopentane by replacing two CH₂ groups with thioether groups. The parent compounds are 1,2-dithiolane and 1,3-dithiolane.

1,2-Dithiolanes, such as lipoic acid, are cyclic disulfides.

1,3-Dithiolanes are important as protecting groups for carbonyl compounds, since they are inert to a wide range of conditions. Reacting a carbonyl group with 1,2-ethanedithiol converts it to a 1,3-dithiolane, as detailed below.

External links

1,3-Dithiolane Reactions

Categories:
Dithiolanes

Dithiolane


IUPAC name Dithiolane
Other names 1,2-dithiolane, 1,3-dithiolane
Identifiers
PubChem	79045
ChemSpider	71377^Y
ChEBI	CHEBI:38226^Y
Jmol-3D images	Image 1
SMILES S1SCCC1
InChI InChI=1S/C3H6S2/c1-2-4-5-3-1/h1-3H2^Y Key: MUZIZEZCKKMZRT-UHFFFAOYSA-N^Y InChI=1/C3H6S2/c1-2-4-5-3-1/h1-3H2 Key: MUZIZEZCKKMZRT-UHFFFAOYAH
Properties
Molecular formula	C₃H₆S₂
Related compounds
Related compounds	1,2-Ethanedithiol
Y (verify) (what is: Y/N?) Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Infobox references

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dithiolane — noun Either of two isomeric saturated heterocycles containing three carbon atoms and two sulfur atoms … Wiktionary
AMG-3 — Drugbox IUPAC name = (6aR,10aR) 3 (2 hexyl 1,3 dithiolan 2 yl) 6,6,9 trimethyl 6a,7,10,10a tetrahydrobenzo [c] chromen 1 ol width= 240 CAS number= ATC prefix= ATC suffix= PubChem= 10002952 DrugBank= C=25 | H=36 | O=2 | S=2 molecular weight =… … Wikipedia
Acide asparagusique — Général … Wikipédia en Français
Asparagusic acid — Chembox new Reference= [cite journal | author=Yanagawa, H.; Kato, T.; Sagami, H.; Kitahara, Y. |journal = Synthesis |title =Convenient procedure for the synthesis of asparagusic acids |year =1973 |volume = 10 |pages=607–608 | doi=10.1055/s 1973… … Wikipedia
Acide lipoïque — Général Nom IUPAC … Wikipédia en Français
Hétérocycle/tableaux — Nomenclature des hétérocycles (nombre de côtés ou de sommets du cycle, nombre de double liaison à l intérieur du cycle) = (X,Y) + nom de l analogue hydrocarbure à chaque (X,Y), tableau avec le type de l hétéroatome en colonne et nombre d… … Wikipédia en Français
Nomenclature des hétérocycles — Demande de traduction Heterocyclen#Nomenklatur, Stammsysteme und Verbindungen → … Wikipédia en Français
organosulfur compound — ▪ chemical compound Introduction also spelled organosulphur compound , also called organic sulfur compound a subclass of organic substances that contain sulfur and that are known for their varied occurrence and unusual properties. They are… … Universalium
Heterocyclic compound — Heterocyclic compounds are organic compounds containing at least one atom of carbon, and at least one element other than carbon, such as sulfur, oxygen or nitrogen within a ring structure .cite book author = Eicher, T.; Hauptmann, S. title = The… … Wikipedia
1,2-Ethanedithiol — 1,2 Ethanedithiol … Wikipedia

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Dithiolane

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Dithiolane

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