Isotopes of caesium

Caesium (Cs) has 40 known isotopes. The atomic masses of these isotopes range from 112 to 151. Only one isotope, ¹³³Cs, is stable. The longest-lived radioisotopes are ¹³⁵Cs with a half-life of 2.3 million years, ¹³⁷Cs with a half-life of 30.1671 years and ¹³⁴Cs with a half-life of 2.0652 years. All other isotopes have half-lives less than 2 weeks, most under an hour.

Beginning in 1945 with the commencement of nuclear testing, caesium isotopes were released into the atmosphere where it is absorbed readily into solution and is returned to the surface of the earth as a component of radioactive fallout. Once caesium enters the ground water, it is deposited on soil surfaces and removed from the landscape primarily by particle transport. As a result, the input function of these isotopes can be estimated as a function of time.

Standard atomic mass: 132.9054519(2) u

Caesium-133

Caesium-133 is the only naturally occurring and only stable isotope of caesium. It is also produced by nuclear fission in nuclear reactors. One specific quantum transition in the Caesium-133 atom is used to define the second, a unit of time.

Caesium-134

Caesium-134 has a half-life of 2.0652 years. It is produced both directly (at a very small yield because ¹³⁴Xe is stable) as a fission product and via neutron capture from nonradioactive Cs-133 (neutron capture cross section 29 barns), which is a common fission product. Caesium 134 is not produced via beta decay of other fission product nuclides of mass 134 since beta decay stops at stable ¹³⁴Xe. It is also not produced by nuclear weapons because ¹³³Cs is created by beta decay of original fission products only long after the nuclear explosion is over.

The combined yield of ¹³³Cs and ¹³⁴Cs is given as 6.7896%. The proportion between the two will change with continued neutron irradiation. ¹³⁴Cs also captures neutrons with a cross section of 140 barns, becoming long-lived radioactive ¹³⁵Cs.

Caesium-135

Long-lived
fission products

Prop: Unit:	t½ Ma	Yield %	Q * KeV	βγ *
99Tc	0.211	6.1385	294	β
126Sn	0.230	0.1084	4050	βγ
79Se	0.327	0.0447	151	β
93Zr	1.53	5.4575	91	βγ
135Cs	2.3	6.9110	269	β
107Pd	6.5	1.2499	33	β
129I	15.7	0.8410	194	βγ

Caesium-135 is a mildly radioactive isotope of caesium, undergoing low-energy beta decay to barium-135 with a half-life of 2.3 million years. It is one of the 7 long-lived fission products and the only alkaline one. In nuclear reprocessing, it stays with Cs-137 and other medium-lived fission products rather than with other long-lived fission products. The low decay energy, lack of gamma radiation, and long half-life of ¹³⁵Cs make this isotope much less hazardous than ¹³⁷Cs or ¹³⁴Cs.

Its precursor ¹³⁵Xe has a high fission product yield (e.g. 6.3333% for ²³⁵U and thermal neutrons) but also has the highest known thermal neutron neutron capture cross section of any nuclide. Because of this, much of the ¹³⁵Xe produced in current thermal reactors (as much as >90% at steady-state full power)^[1] will be converted to stable ¹³⁶Xe before it can decay to ¹³⁵Cs. Little or no ¹³⁵Xe will be destroyed by neutron capture after a reactor shutdown, or in a molten salt reactor that continuously removes xenon from its fuel, a fast neutron reactor, or a nuclear weapon.

A nuclear reactor will also produce much smaller amounts of ¹³⁵Cs from the nonradioactive fission product Cs-133 by successive neutron capture to ¹³⁴Cs and then ¹³⁵Cs.

The thermal neutron capture cross section and resonance integral of ¹³⁵Cs are 8.3 ± 0.3 and 38.1 ± 2.6 barns respectively.^[2] Disposal of Cs-135 by nuclear transmutation is difficult, because of the low cross section as well as because neutron irradiation of mixed-isotope fission caesium produces more Cs-135 from stable Cs-133. In addition, the intense medium-term radioactivity of Cs-137 makes handling of nuclear waste difficult.^[3]

• ANL factsheet

Caesium-137

Main article: Caesium-137

¹³⁷Cs with a half-life of 30.17 years is one of the two principal medium-lived fission products, along with ⁹⁰Sr, which are responsible for most of the radioactivity of spent nuclear fuel after several years of cooling, up to several hundred years after use. It constitutes most of the radioactivity still left from the Chernobyl accident. ¹³⁷Cs beta decays to barium-137m (a short-lived nuclear isomer) then to nonradioactive barium-137, and is also a strong emitter of gamma radiation. ¹³⁷Cs has a very low rate of neutron capture and cannot be feasibly disposed of in this way, but must be allowed to decay. ¹³⁷Cs has been used as a tracer in hydrologic studies, analogous to the use of ³H.

Other isotopes of caesium

The other isotopes have half-lives from a few days to fractions of a second. Almost all caesium produced from nuclear fission comes from beta decay of originally more neutron-rich fission products, passing through isotopes of iodine then isotopes of xenon. Because these elements are volatile and can diffuse through nuclear fuel or air, caesium is often created far from the original site of fission.

Table

nuclide symbol	Z(p)	N(n)	isotopic mass (u)	half-life	decay mode(s)[4][n 1]	daughter isotope(s)[n 2]	nuclear spin	representative isotopic composition (mole fraction)	range of natural variation (mole fraction)
	excitation energy
112Cs	55	57	111.95030(33)#	500(100) µs	p	111Xe	1+#
					α	108I
113Cs	55	58	112.94449(11)	16.7(7) µs	p (99.97%)	112Xe	5/2+#
					β+ (.03%)	113Xe
114Cs	55	59	113.94145(33)#	0.57(2) s	β+ (91.09%)	114Xe	(1+)
					β+, p (8.69%)	113I
					β+, α (.19%)	110Te
					α (.018%)	110I
115Cs	55	60	114.93591(32)#	1.4(8) s	β+ (99.93%)	115Xe	9/2+#
					β+, p (.07%)	114I
116Cs	55	61	115.93337(11)#	0.70(4) s	β+ (99.67%)	116Xe	(1+)
					β+, p (.279%)	115I
					β+, α (.049%)	112Te
116mCs	100(60)# keV			3.85(13) s	β+ (99.48%)	116Xe	4+,5,6
					β+, p (.51%)	115I
					β+, α (.008%)	112Te
117Cs	55	62	116.92867(7)	8.4(6) s	β+	117Xe	(9/2+)#
117mCs	150(80)# keV			6.5(4) s	β+	117Xe	3/2+#
118Cs	55	63	117.926559(14)	14(2) s	β+ (99.95%)	118Xe	2
					β+, p (.042%)	117I
					β+, α (.0024%)	114Te
118mCs	100(60)# keV			17(3) s	β+ (99.95%)	118Xe	(7-)
					β+, p (.042%)	117I
					β+, α (.0024%)	114Te
119Cs	55	64	118.922377(15)	43.0(2) s	β+	119Xe	9/2+
					β+, α (2×10−6%)	115Te
119mCs	50(30)# keV			30.4(1) s	β+	119Xe	3/2(+)
120Cs	55	65	119.920677(11)	61.2(18) s	β+	120Xe	2(-#)
					β+, α (2×10−5%)	116Te
					β+, p (7×10−6%)	118I
120mCs	100(60)# keV			57(6) s	β+	120Xe	(7-)
					β+, α (2×10−5%)	116Te
					β+, p (7×10−6%)	118I
121Cs	55	66	120.917229(15)	155(4) s	β+	121Xe	3/2(+)
121mCs	68.5(3) keV			122(3) s	β+ (83%)	121Xe	9/2(+)
					IT (17%)	121Cs
122Cs	55	67	121.91611(3)	21.18(19) s	β+	122Xe	1+
					β+, α (2×10−7%)	118Te
122m1Cs	45.8 keV			>1 µs			(3)+
122m2Cs	140(30) keV			3.70(11) min	β+	122Xe	8-
122m3Cs	127.0(5) keV			360(20) ms			(5)-
123Cs	55	68	122.912996(13)	5.88(3) min	β+	123Xe	1/2+
123m1Cs	156.27(5) keV			1.64(12) s	IT	123Cs	(11/2)-
123m2Cs	231.63+X keV			114(5) ns			(9/2+)
124Cs	55	69	123.912258(9)	30.9(4) s	β+	124Xe	1+
124mCs	462.55(17) keV			6.3(2) s	IT	124Cs	(7)+
125Cs	55	70	124.909728(8)	46.7(1) min	β+	125Xe	1/2(+)
125mCs	266.6(11) keV			900(30) ms			(11/2-)
126Cs	55	71	125.909452(13)	1.64(2) min	β+	126Xe	1+
126m1Cs	273.0(7) keV			>1 µs
126m2Cs	596.1(11) keV			171(14) µs
127Cs	55	72	126.907418(6)	6.25(10) h	β+	127Xe	1/2+
127mCs	452.23(21) keV			55(3) µs			(11/2)-
128Cs	55	73	127.907749(6)	3.640(14) min	β+	128Xe	1+
129Cs	55	74	128.906064(5)	32.06(6) h	β+	129Xe	1/2+
130Cs	55	75	129.906709(9)	29.21(4) min	β+ (98.4%)	130Xe	1+
					β- (1.6%)	130Ba
130mCs	163.25(11) keV			3.46(6) min	IT (99.83%)	130Cs	5-
					β+ (.16%)	130Xe
131Cs	55	76	130.905464(5)	9.689(16) d	EC	131Xe	5/2+
132Cs	55	77	131.9064343(20)	6.480(6) d	β+ (98.13%)	132Xe	2+
					β- (1.87%)	132Ba
133Cs[n 3][n 4]	55	78	132.905451933(24)	Observationally Stable[n 5]			7/2+	1.0000
134Cs[n 4]	55	79	133.906718475(28)	2.0652(4) a	β-	134Ba	4+
					EC (3×10−4%)	134Xe
134mCs	138.7441(26) keV			2.912(2) h	IT	134Cs	8-
135Cs[n 4]	55	80	134.9059770(11)	2.3(3)×106 a	β-	135Ba	7/2+
135mCs	1632.9(15) keV			53(2) min	IT	135Cs	19/2-
136Cs	55	81	135.9073116(20)	13.16(3) d	β-	136Ba	5+
136mCs	518(5) keV			19(2) s	β-	136Ba	8-
					IT	136Cs
137Cs[n 4]	55	82	136.9070895(5)	30.1671(13) a	β- (95%)	137mBa	7/2+
					β- (5%)	137Ba
138Cs	55	83	137.911017(10)	33.41(18) min	β-	138Ba	3-
138mCs	79.9(3) keV			2.91(8) min	IT (81%)	138Cs	6-
					β- (19%)	138Ba
139Cs	55	84	138.913364(3)	9.27(5) min	β-	139Ba	7/2+
140Cs	55	85	139.917282(9)	63.7(3) s	β-	140Ba	1-
141Cs	55	86	140.920046(11)	24.84(16) s	β- (99.96%)	141Ba	7/2+
					β-, n (.0349%)	140Ba
142Cs	55	87	141.924299(11)	1.689(11) s	β- (99.9%)	142Ba	0-
					β-, n (.091%)	141Ba
143Cs	55	88	142.927352(25)	1.791(7) s	β- (98.38%)	143Ba	3/2+
					β-, n (1.62%)	142Ba
144Cs	55	89	143.932077(28)	994(4) ms	β- (96.8%)	144Ba	1(-#)
					β-, n (3.2%)	143Ba
144mCs	300(200)# keV			<1 s	β-	144Ba	(>3)
					IT	144Cs
145Cs	55	90	144.935526(12)	582(6) ms	β- (85.7%)	145Ba	3/2+
					β-, n (14.3%)	144Ba
146Cs	55	91	145.94029(8)	0.321(2) s	β- (85.8%)	146Ba	1-
					β-, n (14.2%)	145Ba
147Cs	55	92	146.94416(6)	0.235(3) s	β- (71.5%)	147Ba	(3/2+)
					β-, n (28.49%)	147Ba
148Cs	55	93	147.94922(62)	146(6) ms	β- (74.9%)	148Ba
					β-, n (25.1%)	147Ba
149Cs	55	94	148.95293(21)#	150# ms [>50 ms]	β-	149Ba	3/2+#
					β-, n	148Ba
150Cs	55	95	149.95817(32)#	100# ms [>50 ms]	β-	150Ba
					β-, n	149Ba
151Cs	55	96	150.96219(54)#	60# ms [>50 ms]	β-	151Ba	3/2+#
					β-, n	150Ba

1. ^ Abbreviations:
   EC: Electron capture
   IT: Isomeric transition
2. ^ Bold for stable isotopes, bold italics for near-stable isotopes (half-life longer than the age of the universe)
3. ^ Used to define the second
4. ^ ^{a b c d} Fission product
5. ^ Believed to be capable of spontaneous fission

Notes

• Values marked # are not purely derived from experimental data, but at least partly from systematic trends. Spins with weak assignment arguments are enclosed in parentheses.
• Uncertainties are given in concise form in parentheses after the corresponding last digits. Uncertainty values denote one standard deviation, except isotopic composition and standard atomic mass from IUPAC which use expanded uncertainties.

References

1. ^ John L. Groh (2004). "Supplement to Chapter 11 of Reactor Physics Fundamentals". CANTEACH project. http://canteach.candu.org/library/20041204.pdf. Retrieved 14 May 2011. 
2. ^ Hatsukawa, Y.; Shinohara, N; Hata, K. et al. (1999). "Thermal neutron cross section and resonance integral of the reaction of135Cs(n,γ)136Cs: Fundamental data for the transmutation of nuclear waste". Journal of Radioanalytical and Nuclear Chemistry 239 (3): 455–458. doi:10.1007/BF02349050. http://www.springerlink.com/content/t155749703tr4244/. 
3. ^ Ohki, Shigeo; Takaki, Naoyuki (2002). "Transmutation of Cesium-135 With Fast Reactors". Proc. of The Seventh Information Exchange Meeting on Actinide and Fission Product Partitioning & Transmutation, Cheju, Korea. http://www.nea.fr/html/pt/docs/iem/jeju02/session6/SessionVI-08.pdf. 
4. ^ http://www.nucleonica.net/unc.aspx

• Isotope masses from:
  • G. Audi, A. H. Wapstra, C. Thibault, J. Blachot and O. Bersillon (2003). "The NUBASE evaluation of nuclear and decay properties". Nuclear Physics A 729: 3–128. Bibcode 2003NuPhA.729....3A. doi:10.1016/j.nuclphysa.2003.11.001. http://www.nndc.bnl.gov/amdc/nubase/Nubase2003.pdf. 
• Isotopic compositions and standard atomic masses from:
  • J. R. de Laeter, J. K. Böhlke, P. De Bièvre, H. Hidaka, H. S. Peiser, K. J. R. Rosman and P. D. P. Taylor (2003). "Atomic weights of the elements. Review 2000 (IUPAC Technical Report)". Pure and Applied Chemistry 75 (6): 683–800. doi:10.1351/pac200375060683. http://www.iupac.org/publications/pac/75/6/0683/pdf/. 
  • M. E. Wieser (2006). "Atomic weights of the elements 2005 (IUPAC Technical Report)". Pure and Applied Chemistry 78 (11): 2051–2066. doi:10.1351/pac200678112051. http://iupac.org/publications/pac/78/11/2051/pdf/. Lay summary. 
• Half-life, spin, and isomer data selected from the following sources. See editing notes on this article's talk page.
  • G. Audi, A. H. Wapstra, C. Thibault, J. Blachot and O. Bersillon (2003). "The NUBASE evaluation of nuclear and decay properties". Nuclear Physics A 729: 3–128. Bibcode 2003NuPhA.729....3A. doi:10.1016/j.nuclphysa.2003.11.001. http://www.nndc.bnl.gov/amdc/nubase/Nubase2003.pdf. 
  • National Nuclear Data Center. "NuDat 2.1 database". Brookhaven National Laboratory. http://www.nndc.bnl.gov/nudat2/. Retrieved September 2005. 
  • N. E. Holden (2004). "Table of the Isotopes". In D. R. Lide. CRC Handbook of Chemistry and Physics (85th ed.). CRC Press. Section 11. ISBN 978-0849304859. 

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