- Mordant Brown 33
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Mordant Brown 33 Mordant brown 33Systematic nameSodium 2,4-diamino-5-[2-(3-nitro-6-oxocyclohexa-2,4-dien-1-ylidene)hydrazin-1-yl]benzene-1-sulfonateOther namesChrome Brown RH
Sodium 2,4-diamino-5-[2-(3-nitro-6-oxocyclohexa-2,4-dien-1-ylidene)hydrazin-1-yl]benzenesulfonateIdentifiers Abbreviations MB33 PubChem 24186234 , 9575826 (1E) , 5483143 (1Z) ChemSpider 7850278 (1E) , 4588144 (1Z) Jmol-3D images Image 1 - [Na+].O=C2/C=C\C(=C/C2=N\Nc1cc(c(N)cc1N)S([O-])(=O)=O)[N+]([O-])=O
- InChI=1S/C12H11N5O6S.Na/c13-7-4-8(14)12(24(21,22)23)5-9(7)15-16-10-3-6(17(19)20)1-2-11(10)18;/h1-5,15H,13-14H2,(H,21,22,23);/q;+1/p-1
Key: CKWUOVPZRGZTSZ-UHFFFAOYSA-M
InChI=1S/C12H11N5O6S.Na/c13-7-4-8(14)12(24(21,22)23)5-9(7)15-16-10-3-6(17(19)20)1-2-11(10)18;/h1-5,15H,13-14H2,(H,21,22,23);/q;+1/p-1/b16-10+;
InChI=1S/C12H11N5O6S.Na/c13-7-4-8(14)12(24(21,22)23)5-9(7)15-16-10-3-6(17(19)20)1-2-11(10)18;/h1-5,15H,13-14H2,(H,21,22,23);/q;+1/p-1/b16-10+;
Key: CKWUOVPZRGZTSZ-QFHYWFJHSA-M
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) Infobox references Mordant brown 33 (MB33) is 2,4-diamino-5-(2-hydroxy-5-nitrophenylazo) benzene sulfonic acid sodium salt.
The UV-Visible spectra of MB33 in all mixtures investigated display three absorption bands in 50% ethanol within all the pH ranges 1.5-13.3 using Thiel buffer the maximum absorption of these bands is located at 438, 453 and a double head band at 410 and 475 nm . The band at 438 nm corresponds to absorption attributed to the cationic form (LH6) of MB33 (where as L indicates to the parent structure of ligand without hydrogen protons) and disappears at pH > 3.0. The band at 453 nm corresponds to the absorption of the neutral form of the reagent (LH5-). The double head bands at 410 and 475 nm correspond to the di-anionic (LH42-) of MB33
References
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