Copper(I)-thiophene-2-carboxylate

Copper(I)-thiophene-2-carboxylate
Copper(I)-thiophene-2-carboxylate[1]
Identifiers
CAS number 68986-76-5
PubChem 11194830
ChemSpider 9369899 YesY
Jmol-3D images Image 1
Image 2
Properties
Molecular formula C5H3CuO2S
Molar mass 190.69 g mol−1
Hazards
R-phrases R36/37/38
S-phrases S26
Main hazards Irritant (Xi)
 YesY (verify) (what is: YesY/N?)
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Infobox references

Copper(I)-thiophene-2-carboxylate or CuTC is a thiophene and a reagent in organic chemistry that especially promotes the Ullmann reaction between aryl halides.[2]


CuTC catalyzed Ullmann coupling

References

  1. ^ Copper(I) thiophene-2-carboxylate at Sigma-Aldrich
  2. ^ Jwanro Hassan, Marc Sévignon, Christel Gozzi, Emmanuelle Schulz, and Marc Lemaire (2002). "Aryl-Aryl Bond Formation One Century after the Discovery of the Ullmann Reaction". Chem. Rev. 102 (5): 1359–1470. doi:10.1021/cr000664r. PMID 11996540. http://pubs.acs.org/spotlight/july2002/cr000664r.pdf. 

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