(1,1'-Bis(diphenylphosphino)ferrocene)palladium(II) dichloride

The correct title of this article is [1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) dichloride. The substitution or omission of any < > [ ] { } is due to technical restrictions.

(1,1'-Bis(diphenylphosphino)ferrocene)palladium(II) dichloride
Identifiers
CAS number	72287-26-4 Y, 95464-05-4 complex with DCM) Y
ChemSpider	24602493
InChI InChI=1S/2C17H14P.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*1-14H;2*1H;;/q;;;;;+2/p-2 Key: JCWIWBWXCVGEAN-UHFFFAOYSA-L
Properties
Molecular formula	C34H28Cl2FeP2Pd
Molar mass	731.7 g mol−1
Y (verify) (what is: Y/N?) Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Infobox references

[1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) dichloride is an palladium complex containing the iron-containing dppf ligand. Commercially available, this compound is popularly used for palladium-catalyzed coupling reactions.

Commercially available, this compound may be prepared from dppf and nitrile complexes of palladium dichloride:^[1]

dppf + PdCl₂(RCN)₂ → (dppf)PdCl₂ + 2 RCN (RCN = acetonitrile or benzonitrile)

References

1. ^ Nataro, Chip; Fosbenner, Stephanie M. (2009). "Synthesis and Characterization of Transition-Metal Complexes Containing 1,1’-Bis(diphenylphosphino)ferrocene". J. Chem. Ed. 86: 1412. doi:10.1021/ed086p1412.