Diethyl tartrate

Diethyl tartrate: Diethyl tartrate

Identifiers

CAS number 87-91-2^Y

PubChem 62333

ChemSpider 104927^Y

Jmol-3D images Image 1

SMILES

O=C(OCC)[C@@H](O)[C@H](O)C(=O)OCC

InChI

InChI=1S/C8H14O6/c1-3-13-7(11)5(9)6(10)8(12)14-4-2/h5-6,9-10H,3-4H2,1-2H3/t5-,6-/m0/s1
Key: YSAVZVORKRDODB-WDSKDSINSA-N
InChI=1/C8H14O6/c1-3-13-7(11)5(9)6(10)8(12)14-4-2/h5-6,9-10H,3-4H2,1-2H3/t5-,6-/m0/s1
Key: YSAVZVORKRDODB-WDSKDSINBN

Properties

Molecular formula C₈H₁₄O₆

Molar mass 206.19 g mol⁻¹

Y tartrate (verify) (what is: Y/N?)
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)

Infobox references

Diethyl tartrate is the ethyl ester of tartaric acid. It is chiral, showing both left- and right-handed forms, as well as a meso stereoisomer.

In the Sharpless epoxidation, diethyl tartrate and titanium isopropoxide form a chiral catalyst in situ.

Categories:
Ethyl esters
Tartrates
Hydroxy acids

Diethyl tartrate

Identifiers
CAS number	87-91-2^Y
PubChem	62333
ChemSpider	104927^Y
Jmol-3D images	Image 1
SMILES O=C(OCC)[C@@H](O)[C@H](O)C(=O)OCC
InChI InChI=1S/C8H14O6/c1-3-13-7(11)5(9)6(10)8(12)14-4-2/h5-6,9-10H,3-4H2,1-2H3/t5-,6-/m0/s1 Key: YSAVZVORKRDODB-WDSKDSINSA-N InChI=1/C8H14O6/c1-3-13-7(11)5(9)6(10)8(12)14-4-2/h5-6,9-10H,3-4H2,1-2H3/t5-,6-/m0/s1 Key: YSAVZVORKRDODB-WDSKDSINBN
Properties
Molecular formula	C₈H₁₄O₆
Molar mass	206.19 g mol⁻¹
Y tartrate (verify) (what is: Y/N?) Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Infobox references

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Sharpless epoxidation — The Sharpless epoxidation reaction is an enantioselective chemical reaction to prepare 2,3 epoxyalcohols from primary and secondary allylic alcohols. [Katsuki, T.; Sharpless, K. B. J. Am. Chem. Soc. 1980, 102 , 5974. (DOI|10.1021/ja00538a077)]… … Wikipedia
Asymmetric catalytic oxidation — is a technique of oxidizing various substrates to give an enantiopure product using a catalyst.Reactions*Jacobsen epoxidation of alkenes using manganese salen complex and NaOCl *Sharpless epoxidation of allyl alcohols using titanium isopropoxide … Wikipedia
List of named inorganic compounds — Well known inorganic and organometallic compounds and reagents that are named after individuals include Adams catalyst (proposed to be PtOx) Adamsite (NH(C6H4)2AsCl) Adkins catalyst (Cu2Cr2O5) Attenburrow s Oxide (MnO2) Arduengo carbene (class of … Wikipedia
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Diethyl tartrate

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