- Uranium-236
Infobox isotope
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isotope_name = Uranium-236
isotope_filename =
alternate_names =
mass_number =236
symbol =U
num_neutrons =144
num_protons =92
abundance =< 10^-10
halflife = 2.348 x10^7 years
error_halflife =
decay_product = Thorium-232
decay_mass = 232
decay_symbol =Th
parent = Protactinium-236
parent_mass = 236
parent_symbol =Pa
parent_decay =
parent2 = Neptunium-236
parent2_mass = 236
parent2_symbol = Np
parent2_decay =
parent3 = Plutonium-240
parent3_mass = 240
parent3_symbol = Pu
parent3_decay =
mass = 236.045568(2) u
spin = 0+
excess_energy =
error1 =
binding_energy = 1783870.285 ± 1.996 keV
error2 =
decay_mode1 = Alpha 4.572
decay_energy1 =
decay_mode2 =
decay_energy2 =
decay_mode3 =
decay_energy3 =
decay_mode4 =
decay_energy4 =Uranium-236 is an isotope of Uranium that is neither
fissile withthermal neutron s, nor very goodfertile material , but is generally considered a nuisance and long-livedradioactive waste . It is found inspent nuclear fuel and thereprocessed uranium contains it.Creation and yield
The
fissile isotopeuranium-235 which fuels mostnuclear reactors will fission after absorbing athermal neutron about 82% of the time. About 18% of the time, it merely emitsgamma radiation and remains U-236. Thus, the yield of U-236 per 100 U-235+n reactions is about 18%, and the yield per 100 fissions is about 22%. In comparison, the yields of the most abundant individualfission products likeCs-137 ,Sr-90 ,Tc-99 are between 6% and 7% per 100 fissions, and the combined yield of medium-lived (10 years and up) andlong-lived fission product s is about 32%, or a few percent less as some are destroyed byneutron capture .The second most used fissile isotope
plutonium-239 can also fission or not fission on absorbing a thermal neutron. The productplutonium-240 makes up a large proportion of "reactor-grade plutonium" (plutonium recycled from spent fuel that was originally made with enriched natural uranium and then used once in anLWR ). Pu-240 decays with a half-life of 6561 years into U-236. In a closednuclear fuel cycle , most Pu-240 will be fissioned (possibly after more than one neutron capture) before it decays, but Pu-240 discarded asnuclear waste will decay over thousands of years.Destruction and decay
236U, on absorption of a thermal
neutron , does not fission, but becomes 237U, which quicklybeta decay s to 237Np. However, theneutron capture cross section of 236U is low, and this process does not happen quickly in athermal reactor . Spent nuclear fuel typically contains about .4% U-236.236U and most other
actinides are fissionable byfast neutron s in anuclear bomb or afast neutron reactor . A small number of fast reactors have been in research use for decades, but widespread use for power production is still in the future.Uranium-236
alpha decay s with ahalf-life of 23.420 million years toThorium-232 . It is longer-lived than any other artificialactinides orfission products produced in thenuclear fuel cycle .(Plutonium-244 which has a half-life of 80 million years is not produced in significant quantity by thenuclear fuel cycle , and the longer-livedU-235 ,U-238 , andThorium-232 occur in nature.)Difficulty of separation
Unlike
plutonium ,minor actinides ,fission products , or activation products, chemical processes cannot separate U-236 fromU-238 , U-235,U-232 or other uranium isotopes. It is even difficult to remove withisotopic separation , as low enrichment will concentrate not only the desirable U-235 andU-233 but the undesirable U-236, U-234 and U-232. On the other hand, U-236 in the environment cannot separate from U-238 and concentrate separately , which limits its radiation hazard in any one place.Contribution to radioactivity of reprocessed uranium
U-238's halflife is about 190 times as long as U-236; therefore U-236 should have about 190 times as much
specific activity . That is, in reprocessed uranium with 0.5% U-236, the U-236 and U-238 will produce about the same level ofradioactivity . (U-235 contributes only a few percent.)The ratio is less than 190 when the
decay products of each are included. U-238's decay chain toUranium-234 and eventuallyLead-206 involves emission of 8alpha particles in a time (hundreds of thousands of years) short compared to the halflife of U-238, so that a sample of U-238 in equilibrium with its decay products (as in naturaluranium ore ) will have 8 times the alpha activity of U-238 alone. Even purifiednatural uranium where the post-uranium decay products have been removed will contain an equilibrium quantity of U-234 and therefore about twice the alpha activity of pure U-238. Enrichment to increase U-235 content will increase U-234 to an even greater degree, and roughly half of this U-234 will survive in the spent fuel. On the other hand, U-236 decays toThorium-232 which has a halflife of 14 billion years, equivalent to a decay rate only 31.4% as great as that of U-238.Depleted uranium
Depleted uranium used inkinetic energy penetrator s, etc. is supposed to be made fromuranium enrichment tailings that have never been irradiated in anuclear reactor , notreprocessed uranium . However, there have been claims that some DU has contained small amounts of U-236. [http://www.un.org/News/Press/docs/2001/unep81.doc.htm]Isotope|element=Uranium
lighter=Uranium-235
heavier=Uranium-238
before=Protactinium-236 Neptunium-236 Plutonium-240
after=Thorium-232 See also
*
Depleted uranium
*Uranium market
*Nuclear reprocessing
*United States Enrichment Corporation
*Nuclear fuel cycle
*Nuclear power External links
* [http://www.epa.gov/radiation/radionuclides/uranium.htm Uranium | Radiation Protection Program | US EPA]
* [http://toxnet.nlm.nih.gov/cgi-bin/sis/search/r?dbs+hsdb:@term+@na+@rel+uranium,+radioactive NLM Hazardous Substances Databank - Uranium, Radioactive]
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