- Alunite
Alunite, or alumstone, is a
mineral that was first observed in the15th century inMonti della Tolfa , north toRome , where it was mined for the manufacture ofalum . First called "aluminilite" by J.C. Delametherie in 1707, this name was contracted by François Beudant in 1824 to alunite.Distinct
crystal s of alunite are rarely found in cavities in the massive material. Alunite crystallizes in thehexagonal system with crystals formingtrigonal pyramids that resemble rhombohedra with interfacial angles of 90 50', so that they resemble cubes in appearance. Minute glistening crystals have also been found loose in cavities in alteredrhyolite . Alunite varies in color from white to yellow gray. Thehardness is 4 and thespecific gravity is between 2.6 and 2.8. The mineral is a hydratedaluminium potassium sulfate , KAl3(SO4)2(OH)6. Sodium substitutes for potassium and when high in sodium it is called natroalunite. It is insoluble in water or weak acids, but soluble insulfuric acid .Jarosite is an iron analogue in which Fe3+ replaces the aluminium. It occurs as a secondary mineral on iron sulfate ores.Alunite occurs as veins and replacement masses in
trachyte ,rhyolite , and similar potassium rich volcanic rocks It is formed by the action ofsulfuric acid bearing solutions on these rocks during theoxidation and leaching of metal sulfide deposits. Alunite also is found near volcanicfumarole s. The white, finely granular masses closely resemble finely granularlimestone ,dolomite ,anhydrite , andmagnesite in appearance. The more compact kinds from Hungary are so hard and tough that they have been used for millstones.Historically extensive deposits were mined in
Tuscany andHungary , and at Bulahdelah,Australia . Currently found at Tolfa,Italy . In the United States it is found in the San Juan district ofColorado ;Goldfield, Nevada ; theghost town ofAlunite, Utah near Marysvale; and Red Mountain inPatagonia, Arizona . The Arizona occurrence lies appropriately above a canyon named "Alum Gulch". Alunite is mined as an ore of both potassium and aluminium at Marysvale. Some of theore deposits were located by airborne and satellitemultispectral imaging .References
*cite book|last=Hurlbut|first=Cornelius S.|year=1966 |title=Dana's Manual of Mineralogy|edition=17th ed.|id=ISBN 0-471-03288-3
*cite book|last=Hurlbut|first=Cornelius S.|coauthors =Cornelis Klein|year=1985|title=Manual of Mineralogy|edition=20th ed.|id=ISBN 0-471-80580-7External links
* [http://mineral.galleries.com/minerals/sulfates/alunite/alunite.htm Mineral Galleries]
* [http://webmineral.com/data/Alunite.shtml Webmineral]
* [http://www.mindat.org/min-161.html Mindat]
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