Trimethylsilyldiazomethane
- Trimethylsilyldiazomethane
chembox new
ImageFile=Trimethylsilyldiazomethane.pngImageSize=150px
IUPACName=diazomethyl-trimethylsilane
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Section1=Chembox Identifiers
CASNo=18107-18-1
PubChem=167693
SMILES=C [Si] (C)(C)C= [N+] = [N-]
Section2=Chembox Properties
Formula=C4H10N2Si
MolarMass=114.22 g/mol
Appearance=
Density=
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Section3=Chembox Hazards
MainHazards=
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Trimethylsilyldiazomethane, (CH3)3SiCHN2, is an organic compound.
It is a safer alternative to diazomethane for the methylation of carboxylic acids. It is commercially available. It has been employed widely in tandem with GC-MS for the analysis of various carboxylic compounds which are ubiquitous in nature. The fact that the reaction is rapid and occurs readily makes it attractive. However, it can form artifacts the complicate spectral interpretation.
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Doyle-Kirmse reaction — The Doyle Kirmse reaction is an organic reaction in which in the original scope an allyl sulfide reacts with trimethylsilyldiazomethane to form the homoallyl sulfide compound.[1] The reaction was first reported by W. Kirmse in 1968 [2] and… … Wikipedia
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