Polypropylene glycol

Polypropylene glycol or polypropylene oxide is the polymer of propylene glycol. Chemically it is a polyether. The term polypropylene glycol or PPG is reserved for low to medium range molar mass polymer when the nature of the end-group, which is usually a hydroxyl group, still matters. The term "oxide" is used for high molar mass polymer when end-groups no longer affect polymer properties. In 2003, 60% of the annual production of propylene oxide of 6.6×10⁶ tonnes was converted into the polymer. ["A Highly Active, Isospecific Cobalt Catalyst for Propylene Oxide Polymerization" Kathryn L. Peretti, Hiroharu Ajiro, Claire T. Cohen, Emil B. Lobkovsky, and Geoffrey W. Coates J. Am. Chem. Soc., 127 (33), 11566 -11567, 2005. [http://pubs.acs.org/cgi-bin/abstract.cgi/jacsat/2005/127/i33/abs/ja053451y.html Abstract] ]

Polymerization

Polypropylene glycol is produced by anionic ring-opening polymerization of propylene oxide. The initiator is an alcohol and the catalyst a base, usually potassium hydroxide. When the initiator is ethylene glycol or water the polymer is linear. With a multifunctional initiator like glycerine, pentaerythritol or sorbitol the polymer branches out.

Conventional polymerization of propylene oxide results in an atactic polymer. The isotactic polymer can be produced from optically active propylene oxide, but at a high cost. A salen cobalt catalyst has recently been reported to provide isotactic polymerization of the racemic propylene oxide ¹.

Properties

PPG has many properties in common with polyethylene glycol. The polymer is a liquid at room temperature. Solubility in water decreases rapidly with increasing molar mass. Secondary hydroxyl groups in PPG are less reactive than primary hydroxyl groups in polyethylene glycol.

Uses

PPG is used in many formulations for polyurethanes. It is used as a rheology modifier.

References