 Wigner–Seitz cell

The Wigner–Seitz cell, named after Eugene Wigner and Frederick Seitz, is a type of Voronoi cell used in the study of crystalline material in solidstate physics.
The unique property of a crystal is that its atoms are arranged in a regular 3dimensional array called a lattice. All the properties attributed to crystalline materials stem from this highly ordered structure. Such a structure exhibits discrete translational symmetry. In order to model and study such a periodic system, one needs a mathematical "handle" to describe the symmetry and hence draw conclusions about the material properties consequent to this symmetry. The Wigner–Seitz cell is a means to achieve this.
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Wigner–Seitz cell
A Wigner–Seitz cell is an example of another kind of Primitive cell. The primitive unit cell (or simply primitive cell) is a special case of unit cells which has only one lattice point combined and shared by eight other primitive cells. It is the most "primitive" cell one can construct, and it is a parallelepiped. The general unit cell has an integral number of lattice points. The simple cubic lattice is the only primitive unit cell conventionally. The body centered cubic (BCC) and face centered cubic (FCC) lattices are simply unit cells, not primitive.
The general mathematical concept behind the primitive cell is termed the fundamental domain or the Voronoi cell. The primitive cell of the reciprocal lattice in momentum space is called the Brillouin zone.
Definition
The Wigner–Seitz cell around a lattice point is defined as the locus of points in space that are closer to that lattice point than to any of the other lattice points.
It can be shown mathematically that a Wigner–Seitz cell is a primitive cell spanning the entire Bravais lattice without leaving any gaps or holes.
The Wigner–Seitz cell in the reciprocal lattice is known as the first Brillouin zone. It is made by drawing planes normal to the lines joining nearest lattice points to a particular lattice point.
Constructing the cell
The cell may be chosen by first picking a lattice point. Then, lines are drawn to all nearby (closest) lattice points. At the midpoint of each line, another line is drawn normal to each of the first set of lines.
In the case of a threedimensional lattice, a perpendicular plane is drawn at the midpoint of the lines between the lattice points. By using this method, the smallest area (or volume) is enclosed in this way and is called the Wigner–Seitz primitive cell. All area (or space) within the lattice will be filled by this type of primitive cell and will leave no gaps.
General mathematical concept
The general mathematical concept embodied in a Wigner–Seitz cell is more commonly called a Voronoi cell, and the partition of the plane into these cells for a given set of point sites is known as a Voronoi diagram. Though the Wigner–Seitz cell in itself is not of paramount importance in the direct space, it is extremely important in the reciprocal space. The Wigner–Seitz cell in the reciprocal space is called the Brillouin zone, which contains the information about whether a material will be a conductor, semiconductor or an insulator.
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