Wetting is the contact between a liquid and a solid surface, resulting from intermolecular interactions when the two are brought together. The amount of wetting depends on the energies (or surface tensions) of the interfaces involved such that the total energy is minimized. The degree of wetting is described by the contact angle, the angle at which the liquid-vapor interface meets the solid-liquid interface. If the wetting is very favorable, the contact angle will be low, and the fluid will spread to cover a larger area of the surface. If the wetting is unfavorable, the fluid will form a compact droplet on the surface. Regardless of the amount of wetting, the shape of a drop wetted to a rigid surface is roughly a truncated sphere. Various degrees of wetting are depicted in Figure 1.

A contact angle of 90° or greater generally characterizes a surface as not-wettable, and one less than 90° as wettable. In the context of water, a wettable surface may also be termed hydrophilic and a non-wettable surface hydrophobic. Superhydrophobic surfaces have contact angles greater than 150°, showing almost no contact between the liquid drop and the surface. This is sometimes referred to as the "Lotus effect". Wetting is also important in the bonding or adherence of two materials. Wetting and the surface forces that control wetting are also responsible for other related effects, including so-called capillary effects.

Minimization of energy, three phases

Consider the line of contact where three phases meet, as shown in Figure 2. In equilibrium, the net force per unit length acting along the boundary line between the three phases must be zero. The components of net force in the direction along each of the interfaces are given by:

:gamma_{alpha heta}+gamma_{ hetaeta}cos{ heta}+gamma_{alphaeta}cos{alpha} = 0:gamma_{alpha heta}cos{ heta}+gamma_{ hetaeta}+gamma_{alphaeta}cos{eta} = 0:gamma_{alpha heta}cos{alpha}+gamma_{ hetaeta}cos{eta}+gamma_{alphaeta} = 0

where alpha, eta, and heta are the angles shown and gamma_{ij} is the surface energy between the two indicated phases. These relations can also be expressed by an analog to a triangle known as Neumann’s triangle, shown in Figure 3. Neumann’s triangle is consistent with the geometrical restriction that alpha+eta+ heta=2pi, and applying the law of sines and law of cosines to it produce relations that describe how the interfacial angles depend on the ratios of surface energies. [cite book | first = J.S.| last = Rowlinson | Coauthors = Widom, B. | title = Molecular Theory of Capillarity | publisher = Clarendon Press | location = Oxford, UK | year = 1982]

Because these three surface energies form the sides of a triangle, they are constrained by the triangle inequalities, gamma_{ij}meaning that no one of the surface tensions can exceed the sum of the other two. If three fluids with surface energies that do not follow these inequalities are brought into contact, no equilibrium configuration consistent with Figure 2 will exist.

implification to planar geometry, Young's relation

If the eta phase is replaced by a flat rigid surface, as shown in Figure 4, then eta=pi, and the second net force equation simplifies to the Young equation, [cite journal | first = T. | last = Young | title = An Essay on the Cohesion of Fluids | journal = Phil. Trans. R. Soc. Lond. | volume = 95 | pages = 65–87 | year = 1805 | doi = 10.1098/rstl.1805.0005]

:gamma_{SG} =gamma_{SL}+gamma_{LG}cos{ heta} [cite journal | author = T. S. Chow | title = Wetting of rough surfaces | year = 1998 | journal = | volume = 10 | issue = 27 | pages = L445 | doi = 10.1088/0953-8984/10/27/001]

which relates the surface tensions between the three phases solid, liquid and gas, and which predicts the contact angle of a liquid droplet on a solid surface from knowledge of the three surface energies involved. This equation also applies if the "gas" phase is another liquid, immiscible with the droplet of the first "liquid" phase.

The Young–Dupre equation dictates that neither gamma_{SG} nor gamma_{SL} can be larger than the sum of the other two surface energies. The consequence of this restriction is the prediction of complete wetting when gamma_{SG} > gamma_{SL}+gamma_{LG} and zero wetting when gamma_{SL} > gamma_{SG}+gamma_{LG}. The lack of a solution to the Young–Dupre equation is an indicator that there is no equilibrium configuration with a contact angle between 0 and 180 degrees for those situations.

A useful parameter for gauging wetting is the "spreading parameter S",: S = gamma_{SG}-(gamma_{SL}+gamma_{LG})

When "S" > 0, the liquid wets the surface completely (complete wetting).When "S" < 0, there is partial wetting.

Combining the spreading parameter definition with the Young relation, we obtain the Young-Dupre equation:: S = gamma_{LG}(cos heta-1)

which only has physical solutions for heta when S < 0.

Dynamic wetting

The above derivations all apply only to the state in which the interfaces are not moving and the phase boundary line exists in equilibrium. When a phase boundary is in motion, such as in the case of a spreading droplet or advancing contact edge, different mechanics apply. Many aspects of dynamic wetting are not fully understood, and the subject is an area of great interest to many scientists.

When a contact line such as the one in figure 4 is displaced, by either expansion or retraction of the droplet, there is a hysteresis observed in the contact angle. The static contact angle that results after expansion of a droplet is higher than that observed after a contraction. It is also often observed that the contact line does not move smoothly at the microscale. Rather, it is seen to jump abruptly in increments, by an apparent stick-slip mechanism. This has often been attributed to imperfections in the surface causing the contact line to be momentarily pinned, but this description is not complete.

When a contact line advances, covering more of the surface with liquid, the contact angle is increased and generally is related to the velocity of the contact line. [cite book | first = P. G. | last = De Gennes | title = Soft Interfaces | year = 1994 | publisher = Cambridge University Press | location = Cambridge, UK] A receding interface likewise has a contact angle that is reduced from the static contact angle. The limits of contact angle as velocity approaches zero in the forward and backward directions are not equal, and the range between them defines a range of contact angles that are observed as static contact angles in hysteresis experiments.

If the velocity of a contact line is increased without bound, the contact angle increases, and as it approaches 180° the gas phase will become entrained in a thin layer between the liquid and solid. This is a kinetic non-equilibrium effect which results from the contact line moving at such a high speed that complete wetting cannot occur.

Dynamic wetting is of great importance in industrial processes, where surfaces often must be coated uniformly and quickly with a liquid. Entrainment of air is unacceptable for the quality of products, but the volume demanded necessitates coating at as high a speed as possible.Blake, Terence D. (1993) in "Wettability" Ed. Berg, John. C. New York, NY: Marcel Dekker, Inc.]

Molecular theories

Several molecular theories of dynamic wetting have been proposed. The determination of a theory that describes dynamic wetting observations is complicated by the apparent contradiction with established theories of wetting. For example, in the standard model of viscous flow, there is no slippage of the surface layer of liquid atoms along the surface, but in the immediate vicinity of a progressing contact line, it is necessary to relax this restriction to prevent the prediction of infinite shear.

When a contact line advances, it is seen to be preceded by a thin “precursor film” of submicrometer thickness, that advances ahead of the motion of the droplet. Initially, the precursor film was thought to be an artifact of volatility, but its observation in systems with no vapor presence requires a new theory. Measurements of the precursor film have been made by optical ellipsometry and also by sensitive electrical measurements. These experiments have all suffered from limitations on the liquids used and transient effects in droplet spreading, and have failed to provide any basis for a useful model of precursor film formation. [cite journal | first = P.G. | last = De Gennes | title = Wetting: Statics and Dynamics | journal = Rev. Mod. Phys. | volume = 57 | issue = 3 | pages = 827–863 | year = 1985 | doi = 10.1103/RevModPhys.57.827]

See also

* Adsorption
* Dewetting
* Sessile drop technique
* Anti-fog
* Flotation
* Electrowetting


Wikimedia Foundation. 2010.

Игры ⚽ Поможем написать реферат

Look at other dictionaries:

  • Wetting — Wetting. См. Смачивание. (Источник: «Металлы и сплавы. Справочник.» Под редакцией Ю.П. Солнцева; НПО Профессионал , НПО Мир и семья ; Санкт Петербург, 2003 г.) …   Словарь металлургических терминов

  • wetting —  Wetting  Смачивание   Поверхностное явление, наблюдаемое при контакте жидкости с твердым телом в присутствии третьей фазы газа (пара) или др. жидкости, которая не смешивается с первой (т. н. избирательное смачивание) …   Толковый англо-русский словарь по нанотехнологии. - М.

  • Wetting — Wet Wet, v. t. [imp. & p. p. {Wet} (rarely {Wetted}); p. pr. & vb. n. {Wetting}.] [AS. w[=ae]tan.] To fill or moisten with water or other liquid; to sprinkle; to cause to have water or other fluid adherent to the surface; to dip or soak in a… …   The Collaborative International Dictionary of English

  • wetting — vilgymas statusas T sritis Standartizacija ir metrologija apibrėžtis Skysčio paskleidimas kietojo kūno paviršiuje. atitikmenys: angl. wetting vok. Benetzen, n; Benetzung, f rus. смачивание, n pranc. mouillage, m …   Penkiakalbis aiškinamasis metrologijos terminų žodynas

  • wetting — vilgymas statusas T sritis chemija apibrėžtis Skysčio paskleidimas kietojo kūno paviršiuje. atitikmenys: angl. wetting rus. смачивание …   Chemijos terminų aiškinamasis žodynas

  • wetting — drėkinimas statusas T sritis fizika atitikmenys: angl. humidification; wetting vok. Anfeuchtung, f; Befeuchtung, f; Feuchten, n rus. увлажнение, n pranc. humectage, m; humidification, f …   Fizikos terminų žodynas

  • wetting — vilgymas statusas T sritis fizika atitikmenys: angl. wetting vok. Benetzen, n; Benetzung, f rus. смачивание, n pranc. mouillage, m …   Fizikos terminų žodynas

  • wetting — drėkinimas statusas T sritis ekologija ir aplinkotyra apibrėžtis Hidrotechninės melioracijos rūšis – dirbtinis viršutinio dirvožemio sluoksnio drėgmės išteklių papildymas. atitikmenys: angl. moistening; wetting vok. Befeuchtung, f; Benetzung, f… …   Ekologijos terminų aiškinamasis žodynas

  • wetting — смачивающий wetting agent смачивающий реагент …   English-Russian travelling dictionary

  • wetting agent — n a substance that promotes the spreading of a liquid on a surface or the penetration of a liquid into a material esp. by becoming adsorbed in such a way that the liquid is no longer repelled * * * a substance that lowers the surface tension of… …   Medical dictionary

Share the article and excerpts

Direct link
Do a right-click on the link above
and select “Copy Link”