Fluoronium

Fluoronium

thumb|right|200px|The estimated [">Citation
last =Diercksen
first =G. H. F.
last2 =von Niessen
first2 =W.
last3 =Kraemer
first3 =W. P.
title =SCF LCGO MO studies on the fluoronium ion FH2+ and its hydrogen bonding interaction with hydrogen fluoride FH
journal =Theoretical Chemistry Accounts: Theory, Computation, and Modeling (Theoretica Chimica Acta)
volume =31
issue =3
pages =205-214
date =September
year =1973
url = http://www.springerlink.com/content/v517wg14w47676r4/
doi =10.1007/BF00526510
id = ] structure and dimensions of H2F+

The fluoronium cation, H2F+, is a polyatomic ion formed by protonation or self-ionic dissociation of hydrogen fluoride:

:HF + H+ → H2F+

or

:3HF unicode|⇌ H2F+ + HF2−

Unlike for halonium ions based on chlorine, bromine or iodine (chloronium, H2Cl+, bromonium, H2Br+, iodonium, H2I+), hydrocarbyl derivatives of fluoronium, i.e. R2F+, remain unknown.

References


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