Trimethylsilanol

Trimethylsilanol

Chembox new
ImageFileL1 = Trimethylsilanol.png ImageSizeL1 = 100px
ImageFileR1 = Trimethylsilanol_(structure).png ImageSizeR1 = 160px
IUPACName = Hydroxytrimethylsilane
OtherNames = Trimethylhydroxysilane
Section1 = Chembox Identifiers
CASNo = 1066-40-6
PubChem = 66110
SMILES = C [Si] (C)(C)O

Section2 = Chembox Properties
Formula = C3H10OSi
MolarMass = 90.196 g/mol
Appearance =
Density =
MeltingPt =
BoilingPt = 98.6 - 99 °C
Solubility =

Section3 = Chembox Hazards
MainHazards =
FlashPt =
Autoignition =

Trimethylsilanol (TMS), also trimethylhydroxysilane, is an organosilicon chemical compound with the formula (CH3)3SiOH, or C3H10OSi. It is an organic derivate of silane substituted with three methyls and one hydroxyl group. It is a volatile organic liquid with boiling point between 98.6-99 °C.

TMS is used to apply hydrophobic coating on silicate surfaces. It reacts with the silicon atoms of the substrate, coating the surface with a layer of methyl groups. A commercial example is Magic Sand.

TMS is a common contaminant in spacecraft atmospheres, where it is present due to outgassing of silicone-based materials. [ [http://books.nap.edu/openbook.php?record_id=9062&page=177 Trimethylsilanol] , Harold L. Kaplan, Martin E. Coleman, and John T. James "Spacecraft Maximum Allowable Concentrations for Selected Airborne Contaminants", Volume 1 (1994)] It is a potential end group hydrolysis product of polydimethylsiloxane chains.

TMS, together with other silanols, is also being investigated as an antimicrobial agent. [cite journal| journal=Electronic Journal of Biotechnology |volume= 9 |issue= 2 |year=2006 |title=Silanol - A novel class of antimicrobial agent |author=Yun-mi Kim, Samuel Farrah, Ronald H. Baney |url=http://www.ejbiotechnology.info/content/vol9/issue2/full/4/index.html |doi=10.2225/vol9-issue2-fulltext-4 |pages=176]

References


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