William Robert Grove

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birth_date = 11 July, 1811
birth_place = Swansea in Wales
death_date = 1 August, 1896
death_place = London
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field = physics
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known_for = conservation of energy
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Sir William Robert Grove PC QC FRS (11 July, 1811 – 1 August, 1896) was a British lawyer, judge and Welsh physical scientist who anticipated the general theory of the conservation of energy and was a pioneer of fuel cell technology.

Early life

Born Swansea in Wales, Grove was the only child of John, a magistrate and deputy lieutenant of Glamorgan, and his wife, Anne "née" Bevan. His early education was in the hands of private tutors before he attended Brasenose College, Oxford to study classics though his scientific interests may have been cultivated by mathematician Baden Powell. Otherwise, his taste for science has no clear origin though his circle in Swansea was broadly educated. He graduated in 1832 and was called to the bar by Lincoln's Inn in 1835. In the same year, Grove joined the Royal Institution and was a founder of the Swansea Literary and Philosophical Society, an organisation with which he maintained close links.Morus (2004)]

cientific work

At the Royal Institution, Grove met Emma Maria Powles (died 1879) and married her in 1837. Groves's health was never strong and the couple embarked on a tour of the continent for their honeymoon. This sabbatical offered Groves an opportunity to pursue his scientific interests and resulted in his first scientific paper [ cite journal | author=Grove, W. R. | title=On a new voltaic combination | journal=Philosophical Magazine and Journal of Science | year=1838 | volume=13 | pages=430 ] suggesting some novel constructions for electric cells.

In 1839, Grove developed a novel form of electric cell, the "Grove cell", which used zinc and platinum electrodes exposed to two acids and separated by a porous ceramic pot. Grove announced the latter development to the "Académie des Sciences" in Paris in 1839. [" [http://gallica.bnf.fr/ark:/12148/bpt6k2967c/f503.table Note sur une pile voltaïque d'une grande énergie, construite par M. Grove; communication de M. Becquerel] ", "Comptes Rendus" (1839), 8 497] Later that year, he gave another account of his development at the British Association for the Advancement of Science meeting in Birmingham where it aroused the interest of Michael Faraday. On Faraday's invitiation, Grove presented his discoveries at the prestigious Royal Institution Friday Discourse on 13 March, 1840.

Grove's presentation made his reputation and he was soon proposed for Fellowship of the Royal Society by such distinguished men as William Thomas Brande, William Snow Harris and Charles Wheatstone. Grove also attracted the attention of John Peter Gassiot, a relationship that resulted in Grove becoming the first professor of experimental philosophy at the London Institution in 1841. Grove's inaugural lecture in 1842 was the first announcement of what Grove called the "correlation of physical forces", in modern terms, the conservation of energy.

In 1842, Grove developed the first fuel cell (which he called the "gas voltaic battery"), which produced electrical energy by combining hydrogen and oxygen, and described it using his correlation theory. In developing the cell and showing that steam could be disassociated into oxygen and hydrogen, and the process reversed, he was the first person to demonstrate the thermal dissociation of molecules into their constituent atoms. The first demonstration of this effect, he gave privately to Faraday, Gassiot and Edward William Brayley, his scientific editor. [Hays, J. N. (2004) " [http://www.oxforddnb.com/view/article/3303 Brayley, Edward William (1801/2–1870)] ", "Oxford Dictionary of National Biography", Oxford University Press, accessed 8 August 2007 (subscription required)] His work also led him to early insights into the nature of ionisation. [ cite journal | title= [http://dbhs.wvusd.k12.ca.us/webdocs/AtomicStructure/Proton.pdf The proton] | author=Moore, C. E. "et al." | journal=Journal of Chemical Education | volume=62(10) | year=1985 | pages=859–860 ] [ cite journal | author=Grove, W. R. | title=VII. On the electro-chemical polarity of gases | journal=Philosophical Transactions of the Royal Society | volume=142(I) | pages=87 | year=1852 ]

Also in the 1840s, Grove collaborated with Gassiot at the London Institution on photography and the Daguerreotype [ cite journal | author=Grove, W. B. [sic] | title=On a voltaic process for etching Daguerreotype plates | journal=Proceedings of the London Electrical Society | year=1843 | pages=94–99 ] and calotype [Grove, W. G. "On photography", "British Association Report, for 1844", part 2, 37] processes.Wood (1975)] Inspired by his legal practice, he presciently observed:

In 1852, he discovered striae, dark bands that occur in electrical breakdown, and investigated their character, presenting his work in an 1858 Bakerian lecture. [Harrison, W. J. (2004) " [http://www.oxforddnb.com/view/article/10439 Gassiot, John Peter (1797–1877)] ", rev. Iwan Rhys Morus, "Oxford Dictionary of National Biography", Oxford University Press, accessed 5 August 2007 (subscription required)]

"On the Correlation of Physical Forces"

In 1846, Grove published "On The Correlation of Physical Forces" [ cite book | author=Grove, W. R. | title=The Correlation of Physical Forces | location=London | publisher=Longmans, Green | year=1874 | edition=6th ed. ] [Early science terminology warning] in which he anticipated the general theory of the conservation of energy that was more famously put forward in Hermann von Helmholtz' "Über die Erhaltung der Kraft" ("On the Conservation of Force") published the following year. His 1846 Bakerian lecture relied heavily on his theory. ["On certain phenomena of voltaic ignition and the decomposition of water into its constituent gases by heat"]

James Prescott Joule had been inspired to his investigations into the mechanical equivalent of heat by comparing the mass of coal consumed in a steam engine with the mass of zinc consumed in a Grove battery in performing a common quantity of mechanical work. Grove was certainly familiar with William Thomson's theoretical analysis of Joule's experimental results and Thomson's immature suggestions of conservation of energy. Thomson's public champion, Peter Guthrie Tait was initially a supporter of Grove's ideas but later dismissed them with some coolness. [Smith (1998) "pp"60, 176]

Though Groves's ideas were forerunners of the theory of the conservation of energy, they were qualitative, unlike the quantitative investigations of Joule or Julius Robert von Mayer. His ideas also shaded into broader speculation, such as the nature of Olbers's paradox, which he may have discovered for himself rather than through a direct knowledge.Crowther (1965) "pp"92-93]

Grove also speculated that other forms of energy were yet to be discovered "as far certain as certain can be of any future event."

Royal Society politics

Straight from his becoming a Fellow in 1840, Grove was a critic of the Royal Society, deprecating its cronyism and the "de facto" rule of a few influential Council members. In 1843, he published an anonymous attack on the scientific establishment in "Blackwood's Magazine" [ cite journal | author= [Anon. - Grove, W. R.] | title= [http://www.bodley.ox.ac.uk/cgi-bin/ilej/image1.pl?item=page&seq=1&size=1&id=bm.1843.10.x.54.336.x.514 Physical Science in England] | journal=Blackwood’s Magazine | volume=54 | year=1843 | pages=514–25 ] and called for reform. Grove was elected to the Council of the Royal Society in 1846 and was heavily involved in the ongoing campaign to modernise its charter in addition to campaigning for the public funding of science.

A charter committee had already been established and Grove joined it. Groves's fellow campaigners included Gassiot, Leonard Horner and Edward Sabine and their principal objectives were for the number of new Fellows to be subject to an annual limit and limitation of the power of nomination to the Council. The reformers' success in 1847 led to the resignation of several key conservatives and the establishment of Grove and his associates with domination of the Council. To celebrate, the reformers founded the Philosophical Club.

Though the Philosophical Club succeeded in ensuring that William Parsons, 3rd Earl of Rosse was appointed next President, they failed to get Grove appointed as Secretary. Grove continued to campaign for a single home for all the scientific institutions at Burlington House.

Legal career

From 1846, Grove started to reduce his scientific work in favour of his professional practice at the bar, his young family providing the financial motivation, becoming a QC in 1853. The bar provided him with the opportunity to combine his legal and scientific knowledge, in particular in patent law [Anon.] (2001) "Grove, Sir William Robert", "Encyclopaedia Britannica" Deluxe edition, CD-ROM] and in the unsuccessful defence of poisoner William Palmer in 1856. [cite book | author=Knott, G. H. | title=The Trial of William Palmer | year=1912 | edition=Notable English Trials | location=Edinburgh | publisher=William Hodge & Co. | pages=319 ] He was especially involved in the photography patent cases of "Beard v. Egerton" (1845-1849), [(1849) 8 CB 165, 19 LJCP 36, 13 Jur 1004, 13 LTOS 426] on behalf of Egerton, and of "Talbot v. Laroche" (1854). In the latter case, Grove appeared for William Fox Talbot in his unsuccessful attempt to assert his calotype patent.

Grove served on a Royal Commission on patent law and on the Metropolitan Commission of Sewers.Crowther (1965) "p."98]

He was made judge of the Court of Common Pleas in 1871 and appointed to the Queen's Bench in 1880. He was to have presided at the Cornwall and Devon winter assizes of 1884 which would have entailed him trying the notorious survival cannibalism case of "R v. Dudley and Stephens". However, at the last minute he was substituted by Baron Huddleston, possibly because Huddleston was seen as more reliable in ensuring the guilty verdict that the judiciary required. Grove did sit as one of five judges on the final determination of the case in the Divisional Court of the Queen's Bench. [* cite book | title=Cannibalism and the Common Law: The Story of the Tragic Last Voyage of the Mignonette and the Strange Legal Proceedings to Which It Gave Rise | author=Simpson, A. W. B. | publisher=University of Chicago Press | location=Chicago | year=1984 | id=ISBN 9780226759425 | pages="p."198 ]

He was a careful, painstaking and accurate judge, courageous and not afraid to assert an independent judicial opinion. However, he was fallible in patent cases where he was prone to become over interested in the technology in question and to be distracted by questioning the litigants as to potential improvements in their devices, even going so far as to suggest his own innovations. He retired from the bench in 1887. His portrait was painted by Helen Donald-Smith 1890s.

Family

Groves's daughter Imogen Emily (died 1886) married William Edward Hall in 1866. [ Holland, T. E. (2004) " [http://www.oxforddnb.com/view/article/11997 Hall, William Edward (1835–1894)] ", rev. Catherine Pease-Watkin, "Oxford Dictionary of National Biography", Oxford University Press, , accessed 17 August 2007] His daughter Anna married Herbert Augustus Hills (1837–1907) and was mother to Edmond Herbert Grove-Hills ("Colonel Rivers"), [ Hutchins, R. (2006) " [http://www.oxforddnb.com/view/article/57907 Hills, Edmond Herbert Grove- (1864–1922)’] ", "Oxford Dictionary of National Biography", Oxford University Press, online edn, accessed 17 August 2007] and John Waller Hills [Green, E. H. H. (2004) " [http://www.oxforddnb.com/view/article/45568 Hills, John Waller (1867–1938)] ", "Oxford Dictionary of National Biography", Oxford University Press, accessed 17 August 2007]

Grove, his health perpetually troubled, died at home in London after a long illness. He was buried at Kensal Green Cemetery.Fact|date=December 2007

Honours

*Royal Society:
**Fellow, (1840);
**Royal Medal, (1847);
*Vice-President of the Royal Institution (1844);
*Knighthood, (1872);
*Privy Councillor (1887);
*The lunar crater "Grove" is named for him. [cite book | author=Cocks, E. E. & Cocks, J. C. | year=1995 | title=Who's Who on the Moon: A Biographical Dictionary of Lunar Nomenclature | publisher=Tudor Publishers | id=ISBN 0-936389-27-3 ]
* [http://www.grovefuelcell.com The Grove Fuel Cell Symposium and Exhibition] is organised by Elsevier

ee also

*Timeline of hydrogen technologies

Notes

Bibliography

*Obituaries:
**"The Times", 3 August 1896
**"Nature", 27 August 1896
**"Law Journal", 8 August 1896----
* cite book | author=Bonney, T. G. | year=1919 | title=Annals of the Philosophical Club of the Royal Society Written from its Minute Books | location=London | publisher=Macmillan
* cite journal | author=Cantor, G. | year=1976 | title=William Robert Grove, the Correlation of Forces, and the conservation of energy | journal=Centaurus | volume=19 | pages= 273–90 | doi=10.1111/j.1600-0498.1975.tb00327.x
* cite journal | author=Cooper, M. L. & Hall, V. M. D. | title=William Robert Grove and the London Institution, 1841–1845 | journal=Annals of Science | volume=39 | year=1982 | pages=229–54 | doi=10.1080/00033798200200221
* cite book | title=Statesmen of Science | author=Crowther, J. G. | location=London | year=1965 | publisher=Cresset Press | pages=77-101
* cite book | author=Edwards, E. | title=Portraits of Men of Eminence in Literature, Science and the Arts, with Biographical Memoirs | editor=L. Reeve and E. Walford | edition=6 vols | year=1863–7
*Lyons, H. G. (1938) "Notes and Records of the Royal Society London", 1:28–31
* cite journal | author=Morus, I. R. | title=Correlation and control: William Robert Grove and the construction of a new philosophy of scientific reform | journal=Studies in the History and Philosophy of Science | volume=22 | year=1991 | pages=589–621 | doi=10.1016/0039-3681(91)90035-Q
*— (2004) " [http://www.oxforddnb.com/view/article/11685 Grove, Sir William Robert (1811–1896)] ", "Oxford Dictionary of National Biography", Oxford University Press, online edn, May 2005, accessed 25 July 2007 ODNBsub
*
*Vernon, K. D. C. (1966) "Proceedings of the Royal Institution of Great Britain", 41:250–80
* cite journal | author=Webb, R. K. | title=Sir William Robert Grove (1811–1896) and the origins of the fuel cell | journal=Journal of the Royal Institute of Chemistry | volume=85 | year=1961 | pages=291 | doi=10.1039/ji9618500291
* cite book | title=The Calotype Patent Lawsuit of Talbot v. Laroche 1854 | author=Wood, R. D. | publisher=privately published | location=Bromley, Kent | year=1975 | url=http://www.midleykent.fsnet.co.uk/laroche/TalbotvLaroche.htm | id=ISBN 0-9504377-0-0

External links

* [http://www.corrosion-doctors.org/Biographies/GroveBio.htm Sir William Grove (1811–1896)]
* [http://www.aim25.ac.uk/cgi-bin/search2?coll_id=3282&inst_id=17 Archive of the Royal Institution]
* [http://www.darwinproject.ac.uk/darwinletters/namedefs/namedef-2007.html Darwin Correspondence Project] - correspondence with Charles Darwin