- Steven Ittel
Steven Dale Ittel was born (November, 1946) and raised in
Hamilton, Ohio .He attended
Miami University in Oxford, Ohio, where he received a Bachelors Degree in chemistry in 1968. He then was a commissioned officer in the United SatesPublic Health Service , studyingphotochemical smog in theNew York City metropolitan area. He attendedNorthwestern University where he received hisPhD in chemistry under the direction ofJames A. Ibers in 1974. He then joinedDuPont ’sCentral Research Department at theExperimental Station inWilmington ,Delaware . He is married with two children.Ittel is best known for his contributions to
organometallic chemistry andhomogeneous catalysis . He discoveredfluxional processes in bothdiamagnetic [Jack M. Williams, Richard K. Brown, Arthur J. Schultz, Galen D. Stucky, and Steven D. Ittel, "Interaction of an Aliphatic Hydrogen Atom with a Transition Metal. The First Direct Observation of a Strong C-H...Metal Interaction Derived from a Single Crystal Neutron Diffraction Study of Fe [P(OCH3)3] 3(3-C8H13)] + [BF4] -," J. Am. Chem. Soc., 100, 7407 (1978).] andparamagnetic [S. D. Ittel. P. J. Krusic, and P. Meakin, "An Electron Spin Resonance Study of the Fluxional Nature of Paramagnetic (π-Alkenyl)tris(trimethyl phosphite)iron Complexes," J. Am. Chem. Soc., 100, 3264 (1978).] π-allyl organometallic complexes bearing M-H-Cagostic interactions and was responsible for a series ofC-H activation reactions. [a) S. D. Ittel, C. A. Tolman, A. D. English, and J. P. Jesson, "The Chemistry of 2-Naphthyl bis [bis(dimethylphosphino)ethane] Hydride Complexes of Fe, Ru, and Os. 2. Cleavage of sp and sp3 C-H, C-O, and C-X Bonds. Coupling of Carbon Dioxide and Acetonitrile," J. Am. Chem. Soc., 100, 7577 (1978). b) C. A. Tolman, S. D. Ittel, A. D. English, and J. P. Jesson, "Chemistry of 2-Naphthyl- bis [bis(dimethylphosphino)ethane] Hydride Complexes of Iron, Ruthenium, and Osmium. 3. Cleavage of sp2 C-H Bonds," J. Am. Chem. Soc., 101, 1742 (1979).] He contributed to DuPont’s technology for cobalt-catalyzedchain transfer in acrylicradical polymerization . [Alexei A. Gridnev and Steven D. Ittel, “Catalytic Chain Transfer in Free-Radical Polymerizations,” Chem. Rev., 101(12), 3611-3659 (2001).] As a manager at DuPont, he directed the work of almost 100 DuPont scientists, including DuPont’s effort on Versipolpost-metallocene catalyst s forethylene coordination polymerization andcopolymerization . [Steven D. Ittel, Lynda K. Johnson, and Maurice Brookhart, "Late Metal Catalysts for Ethylene Homo- and Copolymerization," Chem. Rev. (Washington, D. C.), 100(4), 1169-1203 (2000).] Ittel coauthored the definitive textbook on “Homogeneous Catalysis” ["Homogeneous Catalysis," 2nd Edition, George W. Parshall and Steven D. Ittel, Wiley Interscience, New York (1992).] withGeorge Parshall and his work is recorded in 136citations inChemical Abstracts .Ittel practices the art of
bonsai and has displayed trees atLongwood Gardens and theBrandywine River Museum . He maintains a website on [http://www.gobbs.org/Potters.htm North American Bonsai Potters] .External links
* [http://www.ittel.org/steven_dale_ittel.htm Ittels of the World]
References
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