Quercitron

Quercitron is a yellow dye obtained from the bark of the Eastern Black Oak ("Quercus velutina"), a fine forest tree indigenous in North America. The name is a shortened form of quercicitron, from Latin "quercus", oak, and "citron", lemon, and was invented by Dr Edward Bancroft (1744-1821), who by act of parliament in 1785 was granted special privileges in regard to the importation and use of the substance. The dyestuff is prepared by grinding the bark in mills after it has been freed from its black epidermal layer, and sifting the product to separate the fibrous matter, the fine yellow powder which remains forming the quercitron of commerce. The ruddy-orange decoction of quercitron contains quercitannic acid, whence its use in tanning, and an active dyeing principle, quercitrin, C₂₁H₂₀O₁₂. The latter substance is a glycoside, and in aqueous solution under the influence of mineral acids it yields quercetin, C₁₅H₁₀O₇, which is precipitated, and the methyl-pentose rhamnose. Quercetin is a crystalline powder of a brilliant citron yellow color, entirely insoluble in cold water and dissolving only sparingly in hot water, but quite soluble in alcohol. Either by itself or in some form of its glucoside quercitrin, quercetin is found in several vegetable substances, among others in cutch, in Persian berries ("Rhamnus cathartica"), buckwheat leaves ("Fagopyrum esculentum"), Zante fustic wood ("Rhus cotinus"), and in rose petals. Quercitron was first introduced as yellow dye in 1775, but it is principally used in the form of flavin, which is the precipitate from a boiling decoction of quercitron and sulfuric acid. Chemically, quercetin is a member of a fairly extensive class of natural coloring matters derived from phenyl benzoyl-pyrone or flavone, the constitution of which followed on the researches of St von Kostanecki, A. G. Perkin, Herzig, Goldschmidt and others. Among the related, coloring matters are: chrysin from poplar buds, apigenin from parsley, luteolin from mignonette and dyer's broom, fisetin from young fustic and yellow cypress, galangin from galangal root, and myricetin from "Nageia nagi".

References

*1911