- Rotation operator (quantum mechanics)
This article concerns the
rotation operator , as it appears inquantum mechanics .The translation operator
The rotation operator mbox{R}(z, t), with the first argument z indicating the rotation axis and the second t = heta the rotation angle, is based on the translation operator mbox{T}(a), which is acting on the state x angle in the following manner:
:mbox{T}(a)|x angle = |x + a angle
We have:
:mbox{T}(0) = 1
:mbox{T}(a) mbox{T}(da)|x angle = mbox{T}(a)|x + da angle = |x + a + da angle = mbox{T}(a + da)|x angle Rightarrow
:mbox{T}(a) mbox{T}(da) = mbox{T}(a + da)
Taylor development gives:
:mbox{T}(da) = mbox{T}(0) + frac{dmbox{T{da(0)} da + ... = 1 - frac{i}{h} p_x da
with
:p_x = i h frac{dmbox{T{da(0)}
From that follows:
:mbox{T}(a + da) = mbox{T}(a) mbox{T}(da) = mbox{T}(a)left(1 - frac{i}{h} p_x da ight) Rightarrow
:mbox{T}(a + da) - mbox{T}(a)] /da = frac{dmbox{T{da} = - frac{i}{h} p_x mbox{T}(a)
This is a differential equation with the solution mbox{T}(a) = mbox{exp}left(- frac{i}{h} p_x a ight).
Additionally, suppose a Hamiltonian H is independent of the x position. Because the translation operator can be written in terms of p_x, and p_x,H] =0, we know that H,mbox{T}(a)] =0. This result means that linear
momentum for the system is conserved.In relation to the orbital angular momentum
Classically we have l = r imes p. This is the same in
quantum mechanics considering r and p as operators. An infinitesimal rotation dt about the z-axis can be expressed by the following infinitesimal translations::x' = x - y dt
:y' = y + x dt
From that follows:
:mbox{R}(z, dt)|r anglembox{R}(z, dt)|x, y, z anglex - y dt, y + x dt, z anglembox{T}_x(-y dt) mbox{T}_y(x dt)|x, y, z anglembox{T}_x(-y dt) mbox{T}_y(x dt)|r angle
And consequently:
:mbox{R}(z, dt) = mbox{T}_x (-y dt) mbox{T}_y(x dt)
Using T_k(a) = expleft(- frac{i}{h} p_k a ight) with k = x,y and Taylor development we get:
:mbox{R}(z, dt) = expleft [- frac{i}{h} (x p_y - y p_x) dt ight] expleft(- frac{i}{h} l_z dt ight) = 1 - i/h l_z dt + ...
To get a rotation for the angle t, we construct the following differential equation using the condition mbox{R}(z, 0) = 1:
:mbox{R}(z, t + dt) = mbox{R}(z, t) mbox{R}(z, dt) Rightarrow:mbox{R}(z, t + dt) - mbox{R}(z, t)] /dt = dmbox{R}/dtmbox{R}(z, t) [mbox{R}(z, dt) - 1] /dtfrac{i}{h} l_z mbox{R}(z, t) Rightarrow:mbox{R}(z, t) = expleft(- frac{i}{h} t l_z ight)
Similar to the translation operator, if we are given a Hamiltonian H which rotationally symmetric about the z axis, l_z,H] =0 implies mbox{R}(z,t),H] =0. This result means that angular momentum is conserved.
For the spin angular momentum about the y-axis we just replace l_z with s_y = frac{h}{2} sigma_y and we get the spin rotation operator mbox{D}(y, t) = expleft(- i frac{t}{2} sigma_y ight).
Effect upon the spin operator and upon states
Operators can be represented by matrices. From
linear algebra one knows that a certain matrix A can be represented in another base through the basis transformation:A' = P A P^{-1}
where P is the transformation matrix. If b and c are perpendicular to the y-axis and the angle t lies between them, the spin operator S_b can be transformed into the spin operator S_c through the following transformation:
:S_c = mbox{D}(y, t) S_b mbox{D}^{-1}(y, t)
From standard quantum mechanics we have the known results S_b |b+ angle = frac{h}{2} |b+ angle and S_c |c+ angle = frac{h}{2} |c+ angle. So we have:
:frac{h}{2} |c+ angle = S_c |c+ angle = mbox{D}(y, t) S_b mbox{D}^{-1}(y, t) |c+ angle Rightarrow
:S_b mbox{D}^{-1}(y, t) |c+ angle = frac{h}{2} mbox{D}^{-1}(y, t) |c+ angle
Comparison with S_b |b+ angle = frac{h}{2} |b+ angle
yields b+ angle = D^{-1}(y, t) |c+ angle.
This can be generalized to arbitrary axes.
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