Rotation operator (quantum mechanics)

Rotation operator (quantum mechanics)

This article concerns the rotation operator, as it appears in quantum mechanics.

The translation operator

The rotation operator ,mbox{R}(z, t), with the first argument ,z indicating the rotation axis and the second ,t = heta the rotation angle, is based on the translation operator ,mbox{T}(a), which is acting on the state |x angle in the following manner:

:mbox{T}(a)|x angle = |x + a angle

We have:

:,mbox{T}(0) = 1

:,mbox{T}(a) mbox{T}(da)|x angle = mbox{T}(a)|x + da angle = |x + a + da angle = mbox{T}(a + da)|x angle Rightarrow

:,mbox{T}(a) mbox{T}(da) = mbox{T}(a + da)

Taylor development gives:

:,mbox{T}(da) = mbox{T}(0) + frac{dmbox{T{da(0)} da + ... = 1 - frac{i}{h} p_x da

with

:,p_x = i h frac{dmbox{T{da(0)}

From that follows:

:,mbox{T}(a + da) = mbox{T}(a) mbox{T}(da) = mbox{T}(a)left(1 - frac{i}{h} p_x da ight) Rightarrow

:, [mbox{T}(a + da) - mbox{T}(a)] /da = frac{dmbox{T{da} = - frac{i}{h} p_x mbox{T}(a)

This is a differential equation with the solution ,mbox{T}(a) = mbox{exp}left(- frac{i}{h} p_x a ight).

Additionally, suppose a Hamiltonian ,H is independent of the ,x position. Because the translation operator can be written in terms of ,p_x, and , [p_x,H] =0, we know that , [H,mbox{T}(a)] =0. This result means that linear momentum for the system is conserved.

In relation to the orbital angular momentum

Classically we have ,l = r imes p. This is the same in quantum mechanics considering ,r and ,p as operators. An infinitesimal rotation ,dt about the z-axis can be expressed by the following infinitesimal translations:

:,x' = x - y dt

:,y' = y + x dt

From that follows:

:,mbox{R}(z, dt)|r angle= mbox{R}(z, dt)|x, y, z angle= |x - y dt, y + x dt, z angle= mbox{T}_x(-y dt) mbox{T}_y(x dt)|x, y, z angle= mbox{T}_x(-y dt) mbox{T}_y(x dt)|r angle

And consequently:

:,mbox{R}(z, dt) = mbox{T}_x (-y dt) mbox{T}_y(x dt)

Using ,T_k(a) = expleft(- frac{i}{h} p_k a ight) with ,k = x,y and Taylor development we get:

:,mbox{R}(z, dt) = expleft [- frac{i}{h} (x p_y - y p_x) dt ight] = expleft(- frac{i}{h} l_z dt ight) = 1 - i/h l_z dt + ...

To get a rotation for the angle ,t, we construct the following differential equation using the condition mbox{R}(z, 0) = 1:

:,mbox{R}(z, t + dt) = mbox{R}(z, t) mbox{R}(z, dt) Rightarrow:, [mbox{R}(z, t + dt) - mbox{R}(z, t)] /dt = dmbox{R}/dt,= mbox{R}(z, t) [mbox{R}(z, dt) - 1] /dt,= - frac{i}{h} l_z mbox{R}(z, t) Rightarrow:,mbox{R}(z, t) = expleft(- frac{i}{h} t l_z ight)

Similar to the translation operator, if we are given a Hamiltonian ,H which rotationally symmetric about the z axis, , [l_z,H] =0 implies , [mbox{R}(z,t),H] =0. This result means that angular momentum is conserved.

For the spin angular momentum about the y-axis we just replace ,l_z with ,s_y = frac{h}{2} sigma_y and we get the spin rotation operator ,mbox{D}(y, t) = expleft(- i frac{t}{2} sigma_y ight).

Effect upon the spin operator and upon states

Operators can be represented by matrices. From linear algebra one knows that a certain matrix ,A can be represented in another base through the basis transformation

:,A' = P A P^{-1}

where ,P is the transformation matrix. If ,b and ,c are perpendicular to the y-axis and the angle ,t lies between them, the spin operator ,S_b can be transformed into the spin operator S_c through the following transformation:

:,S_c = mbox{D}(y, t) S_b mbox{D}^{-1}(y, t)

From standard quantum mechanics we have the known results ,S_b |b+ angle = frac{h}{2} |b+ angle and ,S_c |c+ angle = frac{h}{2} |c+ angle. So we have:

:,frac{h}{2} |c+ angle = S_c |c+ angle = mbox{D}(y, t) S_b mbox{D}^{-1}(y, t) |c+ angle Rightarrow

:,S_b mbox{D}^{-1}(y, t) |c+ angle = frac{h}{2} mbox{D}^{-1}(y, t) |c+ angle

Comparison with ,S_b |b+ angle = frac{h}{2} |b+ angle

yields ,|b+ angle = D^{-1}(y, t) |c+ angle.

This can be generalized to arbitrary axes.


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