- Julius Robert von Mayer
name = Julius Robert von Mayer
caption = Julius Robert von Mayer
November 25, 1814
March 20, 1878
residence = |citizenship =
nationality = German
University of Tübingen
first law of thermodynamics
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Julius Robert von Mayer (
November 25, 1814– March 20, 1878) was a German physicianand physicistand one of the founders of thermodynamics. He is best known for enunciating in 1841 one of the original statements of the conservation of energyor what is now known as one of the first versions of the first law of thermodynamics, namely: [Mayer, Robert (1841). Paper: 'Remarks on the Forces of Nature"; as quoted in: Lehninger, A. (1971). Bioenergetics - the Molecular Basis of Biological Energy Transformations, 2nd. Ed. London: The Benjamin/Cummings Publishing Company.] ["30+ Variations of the 1st Law of Thermodynamics" - IoHT Publications.]cquote|Energy can be neither created nor destroyed
In 1842, Mayer described the vital chemical process now referred to as
oxidationas the primary source of energyfor any living creature. His achievements were overlooked and priority for the discovery of the " mechanical equivalent of heat" was attributed to James Joulein the following year. He also proposed that plants convert light into chemical energy.
Mayer grew up in
Heilbronn, as son of a pharmacist. After completing his " Abitur", he studied medicineat the University of Tübingen, where he was a member of the "Corps Guestphalia", a German Student Corps. In 1838 he attained his doctorateas well as passing the "Staatsexamen". After a stay in Paris(1839/40) he left as a ship's physicianon a Dutch three-mast sailing shipfor a journey to Jakarta.
Although he had hardly been interested up to the start of this journey in physical phenomena, his observation that
storm-whipped wavesare warmer than the calm seasparked deep thinking about the laws of nature, in particular about the physical phenomenon of warmth and the question: "whether the directly developed heat alone or whether the sum of the amounts of heat developed in direct and indirect ways contributes to the temperature". After his return in February 1841 Mayer dedicated all his effors to the solution of this problem.
In 1841 he settled in Heilbronn and married.
Development of ideas
Julius Robert von Mayer was born on
November 25, 1814in Heilbronn, Wurttemberg(modern day Germany). Even as a young child, Mayer showed an intense interest with various mechanical mechanisms. He was a young man who performed various experiments of the physical and chemical variety. In fact, one of his favorite hobbies was creating various types of electrical devices and air pumps. It was very obvious that he was indeed very gifted. Hence, Mayer attended Eberhard-Karls University in May 1832. He studied medicine during his time there.
In 1837, he and some of his friends were arrested for wearing the colors of a forbidden organization. The consequences for this arrest included a one year expulsion from the college and a brief period of incarceration. This diversion sent Mayer traveling to
Switzerland, France, and the Dutch East Indies. Mayer drew some additional interest in mathematics and engineering from his friend Carl Baur through private tutoring. In 1841, Mayer returned to Heilbronn to practice medicine, but physics became his new passion.
In June 1841, he completed his first scientific paper entitled "On the Quantitative and Qualitative Determination of Forces". It was largely ignored by other professionals in the area. Then, Mayer became interested in the area of heat and its motion. He presented a value in numerical terms for the mechanical equivalent of heat. He also was the first person to describe the vital chemical process now referred to as oxidation as the primary source of energy for any living creature.
In 1848 he calculated than in the absence of a source of energy the Sun would cool down in only 5000 years, and he suggested that the impact of meteorites kept it hot. [cite book|title=The Timetables of Science| first=Alexander| last=Hellemans| coauthors=Bryan Bunch| publisher=Simon and Schuster| location=New York, New York| year=1988| isbn=0671621300 |pages=316]
Since he was not taken seriously at the time, his achievements were overlooked and his well-deserved credit was given to
James Joule. Mayer almost committed suicide after he discovered this fact. He spent some time in mental institutions to recover from this and the loss of some of his children. Several of his papers were published due to the advanced nature of the physics and chemistry. He was awarded an honorary doctorate in 1859 by the philosophical faculty at the University of Tubingen. His overlooked work was revived in 1862 by fellow physicist John Tyndallin a lecture at the London Royal Institution. In July 1867, Mayer published "Die Mechanik der Warme." This publication dealt with the mechanics of heat and its motion. In November 1867, Mayer was awarded personal nobility (von Mayer) which is the German equivalent of a British knighthood. Julius Robert von Mayer died from tuberculosis on March 20, 1878 in Germany.
Mayer's place in the history of physics
Mayer was the first person to state the law of the conservation of energy, one of the most fundamental tenets of modern day physics. The law of the conservation of energy states that the total mechanical energy of a system remains constant in any isolated system of objects that interact with each other only by way of forces that are conservative.
Mayer's first attempt at stating the conservation of energy was a paper he sent to
Johann Christian Poggendorff's " Annalen der Physik", in which he postulated a "Erhaltungssatz der Kraft". However, owing to Mayer's lack of advanced training in physics, it contained some fundamental mistakes and was not published. Mayer continued to pursue the idea steadfastly and argued with the Tübingenphysics professor Johann Gottlieb Nörremberg, who rejected his hypothesis. Nörremberg did, however, give Mayer a number of valuable suggestions on how the idea could be examined experimentally; for example, if kinetic energytransforms into heatenergy, watershould be warmed by vibration.
Mayer not only performed this demonstration, but determined also the quantitative factor of the transformation, calculating the mechanical equivalent of heat. The result of his investigations was published 1842 in the May edition of
Justus von Liebig's " Annalen der Chemie und Pharmacie" (Annalen der Chemie und Pharmacie, 43, 233 (1842)) . In his booklet "Die organische Bewegung im Zusammenhang mit dem Stoffwechsel" ("The Organic Movement in Connection with the Metabolism" (1845) he could specified the numerical value of the mechanical equivalent of heat: at first as 365 kgf·m/kcal [The physical unitkgf·m/kcal measures mechanical energy, in kgf·m, against heat energy, in kcal. The mechanical energy is measured on the basis of raising a massof "m" kg to a height of "h" m against Earth's gravity. This is equivalent to an energy of "mgh" joules, where "g" is the standard gravity. Thus, 1 kgf·m/kcal = 9.80665 J/kcal.] , later as 425 kgf·m/kcal; the modern values are 4.184 kJ/kcal (426.6 kgf·m/kcal) for the thermochemical calorie and 4.1868 kJ/kcal (426.9 kgf·m/kcal) for the international steam table calorie.
This relation implies that, although work and heat are different forms of energy, they can be transformed into one another. This law is called the first law of the
caloric theoryand led to the formulation of the general principle of conservation of energy, definitively stated by Hermann von Helmholtzin 1847.
Mayer also derived what is now known as "Mayer's Relation":
:"Cp - Cv = R"
where "Cp" is the
specific heatof a gasat constant pressure, "Cv" is specific heat of a gas at constant volumeand "R" is the gas constant.
:"For dispute over priority with Joule, see main article ."
Mayer was aware of the importance of his discovery, but his inability to express himself scientifically led to degrading speculation and resistance from the scientific establishment. Contemporary physicists rejected his principle of conservation of energy. Even acclaimed physicists von Helmholtz and Joule viewed his ideas with hostility. The former doubted Mayer's qualifications in physical questions, and a bitter dispute over priority developed with the latter.
In 1848 two of his children died rapidly in succession, and Mayer's
mental healthdeteriorated. He attempted suicideon May 18, 1850and was committed to a mental institution. After he was released, he was a broken man and only timidly re-entered public life in 1860. However, in the meantime, his scientific fame had grown and he received a late appreciation of his achievement, although perhaps at a stage where he was no longer able to enjoy it.
He continuted to work vigorously as a physician until his death.
The "Robert-Mayer-Gymnasium" and the "Robert-Mayer-Volks- und Schulsternwarte" in
Heilbronnbear his name.
*Caneva, K.L. (1993) "Robert Mayer and the Conservation of Energy" ISBN 0-691-08758-X
* [http://vlp.mpiwg-berlin.mpg.de/people/data?id=per115 Short biography and bibliography] in the Virtual Laboratory of the
Max Planck Institute for the History of Science
* [http://www.rmg.hn.bw.schule.de/ Robert-Mayer-Gymnasium] (in German)
* [http://www.sternwarte.org/ Robert-Mayer-Volks- und Schulsternwarte] (in German)
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