- Tellurium tetrabromide
Chembox new
Name = Tellurium tetrabromide
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ImageName = Tellurium tetrabromide
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Section1 = Chembox Identifiers
CASNo = 10031-27-3
Section2 = Chembox Properties
Formula = TeBr4
MolarMass = 447.22 g/mol
Appearance = yellow-orange crystals
Density = 4.3 g/cm³, solid
MeltingPt = 388°C
BoilingPt = decomposes @420°C
Section3 = Chembox Structure
CrystalStruct = monoclinic
Section7 = Chembox Hazards
EUClass = not listedTellurium tetrabromide (TeBr4) is an
inorganic chemical compound . It has a similar tetrameric structure to TeCl4."Inorganic Chemistry",Egon Wiberg, Arnold Frederick Holleman Elsevier 2001 ISBN 0123526515] It can be made by reacting bromine and tellurium. [Greenwood&Earnshaw] . In the vapour TeBr4 dissociates ::TeBr4→ TeBr2 + Br2It is a conductor when molten, dissociating into the ions TeBr3+ and Br− Solutions in benzene and toluene are non conducting and TeBr4 is present as the tetramer, Te4Br16.. In solvents with donor properties such asacetonitrile , CH3CN ionic complexes are formed which make the solution conducting::TeBr4 + 2CH3CN→ (CH3CN)2TeBr3+ + Br−References
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