Azirine

Azirine

chembox new
ImageFile=Azarines.svg
ImageSize=100px
IUPACName=1"H"-Azirine
OtherNames=
Section1=Chembox Identifiers
CASNo=157-17-5
PubChem=5461042
SMILES=C1=CN1

Section2=Chembox Properties
Formula=C2H3N
MolarMass=41.05 g/mol
Appearance=
Density=
MeltingPt=
BoilingPt=
Solubility=

Section3=Chembox Hazards
MainHazards=
FlashPt=
Autoignition=

Azirines are three membered heterocyclic unsaturated (i.e. they contain a double bond) compounds containing a nitrogen atom and related to the saturated analogue aziridine. [cite journal | author = Teresa M. V. D. Pinho e Melo and Antonio M. d’A. Rocha Gonsalves | journal = Current Organic Synthesis | volume =1 | issue = 3 | year = 2004 | pages = 275–292 | title = Exploiting 2-Halo-2H-Azirine Chemistry | url = http://www.bentham.org/cos/contabs/cos1-3.htm#5 | doi = 10.2174/1570179043366729] They are highly reactive yet are found in a number of natural products such as the antibiotic azirinomycin, isolated from "Streptomyces auras".

The strained ring system undergoes reactions that favor ring opening and can act as a nucleophile or an electrophile. An azirine is an intermediate in the Neber rearrangement.

References


Wikimedia Foundation. 2010.

Игры ⚽ Поможем написать курсовую

Look at other dictionaries:

  • Azirine — Général Nom IUPAC 2H azirine No CAS …   Wikipédia en Français

  • azirine — noun An unsaturated heterocycle containing two carbon atoms and one nitrogen atom …   Wiktionary

  • 157-17-5 — Azirine Azirine Général Nom IUPAC azirène No CAS …   Wikipédia en Français

  • Alkylimino-de-oxo-bisubstitution — in organic chemistry is the organic reaction of carbonyl compounds with amines to imines [March Jerry; (1985). Advanced Organic Chemistry reactions, mechanisms and structure (3rd ed.). New York: John Wiley Sons, inc. ISBN 0 471 85472 7] . The… …   Wikipedia

  • Iodine monochloride — Chembox new Name = Iodine monochloride ImageFile = Iodine monochloride 2D.png ImageName = Iodine monochloride ImageFile1 = Iodine monochloride 3D vdW.png ImageName1 = Iodine monochloride IUPACName = iodine(I) chloride OtherNames = iodine chloride …   Wikipedia

  • Wenker synthesis — The Wenker synthesis is an organic reaction converting a beta amino alcohol to an aziridine with the aid of sulfuric acid. [cite journal title = The Preparation of Ethylene Imine from Monoethanolamine author = Henry Wenker journal = Journal of… …   Wikipedia

  • Neber rearrangement — The Neber rearrangement is an organic reaction in which an oxime is converted into an alpha aminoketone in a rearrangement reaction.[1][2] The oxime is first converted to a ketoxime tosylate by reaction with tosyl chloride. Added base forms a… …   Wikipedia

  • Heterocyclen — Struktur von Thiophen Heterocyclen (aus griechisch hetero = anders, fremd und lateinisch cyclus = Kreis; zulässig, aber zunehmend verdrängt: Heterozyklen) sind cyclische chemische Verbindungen mit ringbildenden Atomen aus mindestens zwei… …   Deutsch Wikipedia

  • Heterocyclische Verbindung — Struktur von Thiophen Heterocyclen sind cyclische chemische Verbindungen mit ringbildenden Atomen aus mindestens zwei verschiedenen chemischen Elementen. Der Name setzt sich zusammen aus griechisch hetero = anders, fremd und lateinisch cyclus =… …   Deutsch Wikipedia

  • Heterocyclische Verbindungen — Struktur von Thiophen Heterocyclen sind cyclische chemische Verbindungen mit ringbildenden Atomen aus mindestens zwei verschiedenen chemischen Elementen. Der Name setzt sich zusammen aus griechisch hetero = anders, fremd und lateinisch cyclus =… …   Deutsch Wikipedia

Share the article and excerpts

Direct link
Do a right-click on the link above
and select “Copy Link”