Bodroux-Chichibabin aldehyde synthesis
- Bodroux-Chichibabin aldehyde synthesis
The Bodroux-Chichibabin aldehyde synthesis is a chemical reaction whereby a Grignard reagent is converted to an aldehyde one carbon longer.
Reaction of a Grignard reagent with triethyl orthoformate gives an acetal, which can be hydrolyzed to an aldehyde.
References
*Bodroux, F.; "Compt. Rend." 1904, "138", 92.
*Chichibabin, A. E.; "Ber." 1904,"37", 186, 850.
*Smith, L. I. "et al."; "J. Org. Chem." 1941, "6", 437, 489.
ee also
*Bouveault aldehyde synthesis
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