Riemschneider thiocarbamate synthesis

Riemschneider thiocarbamate synthesis

The Riemschneider thiocarbamate synthesis produces aromatic thiocarbamates starting with the corresponding aromatic thiocyanate. [cite journal
title = Die Schmelzpunkte primärer Monothiocarbamidsäure-S-n-alkyl-ester Thiocarbamate. VI. Mitteilung
author = Randolph Riemschneider, G. Orlick
journal = Angewandte Chemie
volume = 64
issue = 15
pages = 429
year = 1952
url =
doi = 10.1002/ange.19520641506
] [cite journal
title = Thiocarbamates. III.1 Aryl Thiocarbamates from Aryl Thiocyanates
author = R. Riemschneider, F. Wojahn, and G. Orlick
journal = Journal of the American Chemical Society
volume = 73
issue = 12
pages = 5905 - 5907
year = 1951
url =
doi = 10.1021/ja01156a552
]

The thiocyanate is treated with sulfuric acid and then hydrolyzed with ice water. ["Merck Index of Chemicals and Drugs, 9th ed." Organic name reactions section]

The reaction was discovered by the German chemist Randolph Riemschneider.

References


Wikimedia Foundation. 2010.

Игры ⚽ Поможем написать курсовую

Look at other dictionaries:

  • Thiocyanate — L anion thiocyanate Les thiocyanates aussi connus sous les noms de sulphocyanates, thiocyanures et rhodanures[1] sont des composés intégrant l anion [SCN]− qui est la base conjuguée de l acide thiocyanique (HSCN). Les sels incolores …   Wikipédia en Français

  • List of organic reactions — Well known reactions and reagents in organic chemistry include Contents: A B C D E F G H I J K L M N O P Q R S T U V W X Y Z    See also   Ext …   Wikipedia

  • Thiocyanate — (also known as sulphocyanate or thiocyanide or rhodanide) is the anion, [SCN] −. Common compounds include the colourless salts potassium thiocyanate and sodium thiocyanate. Organic compounds containing the functional group SCN are also called… …   Wikipedia

Share the article and excerpts

Direct link
Do a right-click on the link above
and select “Copy Link”