- Strain energy
In a
molecule , strain energy is released when the constituentatoms are allowed to rearrange themselves in achemical reaction or a change ofchemical conformation in a way that:*
angle strain ,
*torsional strain ,
*ring strain and/orsteric strain ,
*Allylic strain , and
*pentane interference are reduced [March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure Michael B. Smith, Jerry March Wiley-Interscience, 5th edition, 2001, ISBN 0-471-58589-0] .For example, the
heat of combustion ofcyclopropane (696 kJ/mol) is higher than that ofpropane (657 kJ/mol) permethylene unit.Compounds with unusually large strain energy include
tetrahedrane s,propellane s,cubane s,fenestrane s andcyclophane s.In view aspect of Mechanics: Strain Energy
The external work done on an elastic member in causing it to distort from its unstressed state is transformed into strain energy which is a form of potential energy. The strain energy in the form of elastic deformation is mostly recoverable in the form of mechanical work.
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References
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