- Single displacement reaction
A single-displacement reaction, also called single-replacement reaction, is when an element or ion moves out of one compound and into another. (One element is replaced by another in a compound.) This is usually written as :A + BX → AX + BThis will occur if A is more reactive than B. You can refer to the
reactivity series to be sure of this.A and B must be either:
*different metals (hydrogen's behavior as acation renders it as a metal here), in which case X represents ananion ; or
*halogen s, in which case X represents a cation.In either case, when AX and BX are aqueous compounds (which is usually the case), X is aspectator ion .Due to the free state nature of A and B, all single displacement reactions are also
oxidation-reduction reactions. When A and B are metals, A is always oxidized and B is always reduced. Since halogens prefer to gain electrons, A is reduced (from a 0 to −1) and B is oxidized (from −1 to 0) when A and B represent those elements.A and B may not have the same charge when ions are formed therefore some balancing of the equation may be necessary. For example the reaction between
silver nitrate , AgNO3, andzinc , Zn, formssilver , Ag, andzinc nitrate , Zn(NO3)2.:2AgNO3(aq) + Zn(s) → 2Ag(s) + Zn(NO3)2(aq)
All simple metal with acid reactions are single displacement reactions. For example the reaction between
magnesium , Mg, andhydrochloric acid , HCl, formsmagnesium chloride , MgCl2, andhydrogen , H2.:Mg(s) + 2HCl(aq) → MgCl2(aq) + H2(g)
Cation replacement
One
cation replaces another. A cation is a positively charged ion or a metal. When it is written in generic symbols, it isAX + Y → YX + A
Element Y has replaced A (in the compound AX) to form a new compound YX and the free element A. This is an oxidation-reduction reaction wherein element A is reduced from a cation into the elemental form and element Y is oxidized from the elemental form into a cation.Some examples are:
# Cu + 2AgNO3 → 2Ag + Cu(NO3)2
# Fe + Cu(NO3)2 → Fe(NO3)2 + Cu
# Ca + 2H2O → Ca(OH)2 + H2
# Zn + 2HCl → ZnCl2 + H2Anion replacement
One
anion replaces another. An anion is a negatively charged ion or a nonmetal. Written using generic symbols, it is:A + XY → XA + Y
Element A has replaced Y (in the compound XY) to form a new compound XA and the free element Y. This is an oxidation-reduction reaction wherein element A is reduced from the elemental form into an anion and element Y is oxidized from an anion into the elemental form.
Some of the only examples that involve
halogen s are here, so here are the two examples:
# Cl2 + 2NaBr → 2NaCl + Br2
# Br2 + 2KI → 2KBr + I2ee also
*
Double displacement reaction
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