BOP reagent

BOP reagent

Chembox new
ImageFile = BOP reagent.png ImageSize =
IUPACName = Benzotriazole-1-yl-oxy-tris-(dimethylamino)-phosphonium hexafluorophosphate
OtherNames = Castro's reagent
Section1 = Chembox Identifiers
CASNo = 56602-33-6
PubChem =
SMILES = CN(C) [P+] (N(C)C)(N(C)C)ON1C2=CC=CC=C2N=N1. [F-] .FP(F)(F)(F)F
Section2 = Chembox Properties
Formula = C12H22F6N6OP2
MolarMass = 442.281 g/mol
Appearance = White crystalline powder
Density =
MeltingPt = 136 - 140 °C
BoilingPt =
Solubility = Partially soluble in cold water
Section3 = Chembox Hazards
MainHazards =
FlashPt =
Autoignition =

BOP-reagent is a reagent commonly used in the synthesis of peptides. Its use is discouraged because coupling using BOP liberates HMPA, which is carcinogenic.

ee also

* PyBOP, a related reagent


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