Basic aromatic ring

Basic aromatic ring

Basic aromatic rings are aromatic rings in which the lone pair of electrons of a ring-nitrogen atom is not part of the aromatic system and extends in the plane of the ring. This lone pair is responsible for the basicity of these nitrogenous bases, similar to the nitrogen atom in amines. In these compounds the nitrogen atom is not connected to a hydrogen atom. Basic aromatic compounds get protonated and form aromatic cations (e.g. pyridinium) under acidic conditions. Typical examples of basic aromatic rings are pyridine or quinoline. Several rings contain basic as well as non-basic nitrogen atoms, e.g. imidazole and purine.

In non-basic aromatic rings the lone pair of electrons of the nitrogen atom is delocalized and contributes to the aromatic pi electron system. In these compounds the nitrogen atom is connected to a hydrogen atom. Examples of non-basic nitrogen-containing aromatic rings are pyrrole and indole.

The basic aromatic rings purines and pyrimidines are the nucleobases found in DNA and RNA.

See also

* Simple aromatic ring


Wikimedia Foundation. 2010.

Игры ⚽ Поможем написать курсовую

Look at other dictionaries:

  • Simple aromatic ring — Simple aromatic rings, also known as simple arenes or simple aromatics, are aromatic organic compounds that consist only of a conjugated planar ring system with delocalized pi electron clouds. Many simple aromatic rings have trivial names. They… …   Wikipedia

  • Nucleophilic aromatic substitution — A nucleophilic aromatic substitution is a substitution reaction in organic chemistry in which the nucleophile displaces a good leaving group, such as a halide, on an aromatic ring. There are 6 nucleophilic substitution mechanisms encountered with …   Wikipedia

  • Electrophilic aromatic substitution — or EAS is an organic reaction in which an atom, usually hydrogen, appended to an aromatic system is replaced by an electrophile. The most important reactions of this type that take place are aromatic nitration, aromatic halogenation, aromatic… …   Wikipedia

  • carboxylic acid — Chem. any organic acid containing one or more carboxyl groups. [1900 05; CARBOXYL + IC] * * * Any organic compound with the general chemical formula ―COOH in which a carbon (C) atom is bonded to an oxygen (O) atom by a double bond to make a… …   Universalium

  • Pyridine — Pyridine …   Wikipedia

  • petroleum refining — Introduction  conversion of crude oil into useful products. History Distillation of kerosene and naphtha       The refining of crude petroleum owes its origin to the successful drilling of the first oil well in Titusville, Pa., in 1859. Prior to… …   Universalium

  • Benzene — For other uses, see Benzene (disambiguation). See also: Benzole Benzene …   Wikipedia

  • Physical Sciences — ▪ 2009 Introduction Scientists discovered a new family of superconducting materials and obtained unique images of individual hydrogen atoms and of a multiple exoplanet system. Europe completed the Large Hadron Collider, and China and India took… …   Universalium

  • 5-HT3 antagonist — 5 HT3 receptor antagonists Drug class Skeletal formula of ondansetron, the prototypical 5 HT3 antagonist ATC code A04AA …   Wikipedia

  • Amine — For other uses, see Amine (disambiguation). Primary amine Secondary amine Tertiary amine …   Wikipedia

Share the article and excerpts

Direct link
… Do a right-click on the link above
and select “Copy Link”