Benzotriazole

Benzotriazole

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ImageFile = Benzotriazole_-_numbered.png ImageSize = 200px
IUPACName =
OtherNames = 1H-Benzotriazol, 1,2,3-Benzotriazol
Section1 = Chembox Identifiers
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CASNo = 95-14-7
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PubChem = 7220
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Section2 = Chembox Properties
C=6|H=5|N=3
Appearance = solid
Density = 1,36 g·cm−3 " [http://de.chemdat.info/mda/de chemdat.info] "]
MeltingPt = 100 °C SRC PhysProp Database: " [http://esc.syrres.com/interkow/webprop.exe?CAS=95-14-7 1H-Benzotriazole] "]
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BoilingPt = 350 °C
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Solubility = soluble in water (20 g/l)
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pKa = 8,37
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Section5 = Chembox Pharmacology
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Section6 = Chembox Explosive
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MainHazards = XN
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RPhrases = R20/22 R36 R52/53
SPhrases = –
RSPhrases = –
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OtherCpds = Benzimidazole

Benzotriazole is an aromatic azole containing two fused rings. Benzotriazoles are also a class of compounds containing the benzotriazole skeleton.

Production

Benzotriazole is produced by reaction of o-phenylenediamine, sodium nitrite and acetic acid. [ [http://www.google.com/patents?id=CzICAAAAEBAJ U.S. Patent 4299965] ]

Uses

Benzotriazole is a complexing agent. It is used as a corrosion inhibitor, an aircraft deicer and anti-icer fluid as well as for silver protection in dishwashing detergents. Benzotriazole skeletons are found in pharmaceuticals such as antifungal, antibacterial, and anthelmintic drugs.

Environmental relevance

Benzotriazole is fairly well water-soluble, not readily degradable and has a limited sorption tendency. Hence, it is only partly removed in wastewater treatment plants and a substantial fraction reaches surface water like rivers and lakes. [W. Giger, C. Schaffner, HP. Kohler (2006): "Benzotriazole and Tolyltriazole as Aquatic Contaminants. 1. Input and Occurrence in Rivers and Lakes". Environ. Sci. Technol. 40,7186-7192. PMID 17180965]

References


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