Rodrigues equation

Rodrigues equation

The Rodrigues equation is an equation used in chromatography to describe the efficiency of a bed of permeable (large-pore) particles. It is thus an extension of Van Deemter's equation. It was developed by Alirio E. Rodrigues "et al"cite journal
title = Permeable packings and perfusion chromatography in protein separation
journal = Journal of Chromatography B: Biomedical Sciences and Applications
author = Alirio E. Rodrigues
volume = 699
issue = 1-2
date = 10 October 1997
year = 1997
pages = 47-61
doi = 10.1016/S0378-4347(97)00197-7
] .

----

HETP = A + frac{B}{u} + C cdot f( lambda ) cdot u

Where

* HETP is the height equivalent to a theoretical plate
* A = Eddy diffusion
* B = Longitudinal diffusion
* C = Resistance to mass transfer
* u = Flow rate
* f( lambda ) = frac{3}{ lambda } left [ frac{1}{tanh( lambda )} - frac{1}{ lambda } ight ]
* lambda = Intraparticular Péclet number

References


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