- Mesoporous silicates
Mesoporous silicates are
silicate s with a special morphology.Background
Porous inorganic solids have found great utility as
catalysts and sorption media because of their large internalsurface area , i.e. the presence of voids of controllable dimensions at the atomic, molecular, and nanometer scales. With increasing environmental concerns worldwide,nanoporous materials have become more important and useful for the separation of polluting species and the recovery of useful ones. In recent years there has been great progress in applying environmentally friendlyzeolites in heterogeneous reactioncatalysis . The reason for their success is related to their specific features in converting molecules havingkinetic diameter below 1 nm, but they become inadequate when reactants with sizes above the dimensions of the pores have to be processed. Research efforts to synthesize zeolites with larger pore diameter, high structural stability and catalytic activity have not given the expected results yet.Characteristics
The discovery of a new family of
mesoporous molecular sieve s in the early 1990’s opened new possibilities to prepare catalysts for reactions of relatively large molecules. The most important member of the family, known as MCM-41, possesses regular, hexagonal array of pores with pore diameter in the 1.5-10 nm range. Thesilicate wall of the pores isamorphous . Mesoporous silicates such as MCM-41 and SBA-15 are porous silicates with huge surface areas (normally ≥1000 m²/g), large pore sizes (2 nm ≤ size ≤ 20 nm) and ordered arrays of cylindrical mesopores with very regular pore morphology. The large surface areas of these solids increase the probability that a reactant molecule in solution will come into contact with the catalyst surface and react. The large pore size and ordered pore morphology allow one to be sure that the reactant molecules are small enough to diffuse into the pores.ee also
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HPLC
*Gas-liquid chromatography
*Silica gel
*nanotechnology
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