Albumen print

The albumen print, also called albumen silver print, was invented in 1850 by Louis Désiré Blanquart-Evrard, and was the first commercially exploitable method of producing a photographic print on a paper base from a negative. It used the albumen found in egg whites to bind the photographic chemicals to the paper and became the dominant form of photographic positives from 1855 to the turn of the century, with a peak in the 1860-90 period. During the mid-1800s, the carte de visite became one of the more popular uses of the albumen method. In the 19th century, E. & H. T. Anthony & Company were the largest makers and distributors of the Albumen photographic prints and paper in the United States. [Welling, William. Photography in America (1978 & 1987)]

The process of making an albumen print

# A piece of paper, usually 100% cotton, is coated with an emulsion of egg white (albumen) and salt (sodium chloride or ammonium chloride), then dried. The albumen seals the paper and creates a slightly glossy surface for the sensitizer to rest on.
# The paper is then dipped in a solution of silver nitrate and water which renders the surface sensitive to UV light.
# The paper is then dried in the absence of UV light.
# The dried, prepared paper is placed in a frame in direct contact under a negative, often a glass negative with collodion emulsion but can be done with a digital negative, and exposed to light until the image achieves the desired level of darkness, which is typically a little lighter than the end product. While direct sunlight was used long ago, a UV exposure unit is preferable because it is more predictable, as the paper is most sensitive to ultraviolet light.
# A bath of sodium thiosulfate fixes the print’s exposure, preventing further darkening.
# Optional gold or selenium toning improves the photograph’s tone and stabilises against fading, depending on the toner this may be done before or after fixing the print.

Since the image emerges as a direct result of exposure to light, without the aid of a developing solution, an albumen print may be said to be a "printed" rather than a developed photograph.

The table salt (sodium chloride) in the albumen emulsion forms silver chloride when in contact with silver nitrate. Silver chloride is unstable when exposed to light, which makes it decompose into silver and chlorine. The silver is oxidized into silver oxide during the development process and the remaining silver chloride is washed out during fixing. The black parts of the image are formed by silver oxide.

ee also

* Collodion process

A piece of paper, usually 100% cotton, is coated with an emulsion of egg white (albumen) and salt (sodium chloride or ammonium chloride), then dried. The albumen seals the paper and creates a slightly glossy surface for the sensitizer to rest on.The paper is then dipped in a solution of silver nitrate and water which renders the surface sensitive to UV light.The paper is then dried in the absence of UV light.The dried, prepared paper is placed in a frame in direct contact under a negative, often a glass negative with collodion emulsion but can be done with any negative with decent dencity, and exposed to light until the image achieves the desired level of darkness, which is typically a little lighter than the end product. While direct sunlight was used long ago, a UV exposure unit is preferable because it is more predictable, as the paper is most sensitive to ultraviolet light.A bath of sodium thiosulfate fixes the print’s exposure, preventing further darkening.Optional gold or selenium toning improves the photograph’s tone and stabilises against fading, depending on the toner this may be done before or after fixing the print.Since the image emerges as a direct result of exposure to light, without the aid of a developing solution, an albumen print may be said to be a printed rather than a developed photograph.The table salt (sodium chloride) in the albumen emulsion forms silver chloride when in contact with silver nitrate. Silver chloride is unstable when exposed to light, which makes it decompose into silver and chlorine. The silver is oxidized into silver oxide during the development process and the remaining silver chloride is washed out during fixing. The black parts of the image are formed by silver oxide.

References

* Marshall, F.A.S. "Photography: the importance of its applications in preserving pictorial records. Containing a practical description of the Talbotype process" (London: Hering & Remington; Peterborough, T Chadwell & J Clarke, 1855).
* [http://albumen.stanford.edu Stanford University - Albumen Photographs: history, science and preservation]
* [http://www.alternativephotography.com/process_albumen_paper.html Alternative Photography - Make Albumen Paper]
* [http://www.kiwisunphoto.com/albumen.php Kiwi Sun Photography: Albumen Printing]