Film base

A film base is a transparent substrate which acts as a support medium for the photosensitive emulsion that lies atop it. Despite the numerous layers and coatings associated with the emulsion layer, the base generally accounts for the vast majority of the thickness of any given film stock. Historically there have been three major types of film base in use: cellulose nitrate, cellulose acetate (cellulose diacetate, cellulose acetate propionate, cellulose acetate butyrate, and cellulose triacetate), and polyethylene trephthalate polyester (Kodak trade-name: ESTAR).

Nitrate

Nitrate film base was the first transparent flexible plasticized base commercially available, thanks to celluloid developments by John Carbutt, Hannibal Goodwin, and Eastman Kodak in the 1880s. Eastman was the first to manufacture this for public sale, in 1889. Unfortunately, nitrate also had the drawback that it was extremely flammable (being essentially the same chemically as guncotton) and decomposed after several decades into a no less flammable gas, leaving the film sticky and goo-like. As this happened, the likelihood of auto-ignition increased even further. Projection booth fires were not uncommon in the early decades of cinema if a film managed to be exposed to too much heat while passing through the gate, and several incidents of this type resulted in audience deaths by flames, smoke, or the resulting stampede. While an accident of this sort was famously recreated in "Cinema Paradiso", the risk was certainly not fictional; in one instance, at the Laurier Palace Cinema in Montreal on January 9, 1927, a fire broke out during a children's film program and resulted in the deaths of 77 children between the ages of 4 and 18. 1978 was a particularly devastating year for film archives when both the National Archives and George Eastman House had their nitrate film vaults auto-ignite. Eastman House lost the original camera negatives for 329 films, while the National Archives lost 12.6 million feet of newsreel footage. Because the ignition of cellulose nitrate creates its own oxygen, nitrate fires can be very difficult to extinguish. The US Navy has produced an instructional movie about the safe handling and usage of nitrate films which includes footage of a full reel of nitrate film burning underwater. The base is so flammable that intentionally igniting the film for test purposes is recommended in quantities no greater than one frame without extensive safety precautions. Most nitrate films have been converted in recent decades to polyester copies, and original nitrate prints are generally stored separately to prevent a nitrate fire from destroying other non-nitrate films. Sometimes nitrate collections are even split up into several different fireproof rooms to minimize damage to an entire collection should a fire occur in one part. Usually a theater today needs to pass rigorous safety standards and precautions before being certified to run nitrate films; this includes a fireproof projection booth, fire chambers surrounding the feed and take-up reels, and several fire extinguishers built into the projector and aimed at the film gate should a trigger piece of fabric ignite. Nitrate film is classified as "dangerous goods", which requires licenses for storage and transportation.

Acetate

Despite the dangers of the nitrate film base being known practically since its development, it was used in virtually all major motion pictures prior to 1952, when Kodak completed a four year conversion program to the sole manufacturing of acetate base film stocks. Kodak actually began working with acetate "safety film" as early as 1909, and started selling it in 1910 for 22 mm film. Acetate has always been used with 8 mm and 16 mm formats, as they were originally created for amateur home movie usage, and generally was used for most sub-35 mm formats to minimize risk to the general public. (Several formats, such as 17.5 mm, which were often re-slit from 35 mm were nitrate, however. One of Kodak's reasons for choosing 16 mm instead of 17.5 mm for a standard amateur format width was specifically to prevent nitrate re-slits from being used in home movies.) Acetate also is the only base which has been used with color negatives. All motion picture camera negatives are now shot on acetate film because it is safer than nitrate but not as strong as polyester bases, which may damage the camera rather than the film should a jam occur. Acetate can also be spliced with film cement, while polyester can only be spliced with tape or an ultrasonic splicer, so polyester would be hard to edit. Acetate film does not burn under intense heat, but rather melts, causing a bubbling burn-out effect - this can be seen simulated in films such as "Persona" or "Velvet Goldmine", or, if one is unlucky, in real life during a film screening when a frame becomes stuck in the projector's film gate. Acetate films are also subject to degradation over time. With exposure to heat, moisture or acids the acetyl groups which are attached to long chains of cellulose which form the film base are broken from their molecular bonds and free acetic acid is released with a characteristic smell of vinegar. This is known as vinegar syndrome. As the degradation progresses the film base becomes brittle and shrinks.

Polyester

Polyester is the most recent film base to have been developed, and was first used for specialized photography applications in 1955, but it was only in the 1990s that it became overwhelmingly popular for motion picture prints. It is highly preferable for post-production, exhibition, and archival purposes because of its flexibility, strength, and stability. Its strength is sometimes also seen as a disadvantage, however, in that polyester-base films are so resistant to breakage that they are often more likely to break the film equipment should a jam or extra tension occur. Movie cameras therefore do not use this base for shooting the original camera negative, as it is vastly preferable and less costly in time and money for the film to break instead.

Identifying a film base

There are several factors which can aid in identification of the film base of a roll of film. Many are not 100% conclusive, and it is best to use a selection of these to positively verify a film base.

* Printing along the edge of the film:
** for older films, will often say "nitrate" or "safety" on it, however this text may print through from a negative or other intermediate stock.
** may include a date code [ [http://www.kodak.com/US/en/motion/support/h1/identificationP.shtml#135427 Kodak H-1: Film Identification] , retrieved 28 March 2007.] (Kodak print films prior to 2001) or an actual printed 4-digit year.
** may include an emulsion number uniquely identifying the print stock (newer stocks, only)
* No Kodak film manufactured after 1951 is nitrate, and no film of any kind is polyester before 1955.
* Deterioration artifacts are distinct between nitrate (noxious nitric acid gas; amber discoloration; soft, sticky, or powdery film) and acetate (acetic acid gas, red or blue discoloration, shrinkage, brittleness, presence of bubbles or crystals).
* Polyester shows red and green interference colors when viewed through cross-polarized filters.
* A solution of diphenylalanine and sulfuric acid will turn nitrate deep blue.
* A highly controlled burn of one frame of nitrate will result in a bright yellow flame which consumes the film almost completely. (ONLY PERFORM WITH THE HIGHEST OF CAUTION)
* Nitrate film is soluble in a variety of solvents - namely methyl alcohol, ethyl, and ether.
* Float testing of the specific gravity of the base in trichloroethylene should cause nitrate to sink, acetate to float, and polyester to remain around the middle. However, this can be complicated by impurities and deterioration factors.
* Light aimed through the side of a roll of film will shine through if it is polyester, but will not if it is acetate.

References

* Wilhelm, Henry and Carol Brower. " [http://www.wilhelm-research.com/pdf/HW_Book_19_of_20_HiRes_v1a.pdf The Permanence and Care of Color Photographs: Traditional and Digital Color Prints, Color Negatives, Slides, and Motion Pictures, Chapter 19] ". Grinnell, Iowa : Preservation Publishing Company, 1993.
* [http://www.seapavaa.org/FilmPreservationHandbook/BaseDecomp/Base.htm Film Preservation Handbook]
* [http://www.kodak.com/US/en/motion/about/chrono1.shtml Kodak Chronology of Motion Picture Films]
* [http://www.nedcc.org/leaflets/nitrate.htm NEDCC Technical Leaflet - A Short Guide to Film Base Photographic Materials: Identification, Care, and Duplication]