- Thorianite
Infobox mineral
name = Thorianite
category =
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formula =Thorium oxide , ThO2
molweight =
color = Dark gray, brown-black
habit = Rounded grains
system = Isometric
twinning = Penetration twins on {111} very common
cleavage = Poor/Indistinct
fracture = Irregular/Uneven,Sub-Conchoidal
mohs = 6½ - 7
luster = Resinous,Sub-Metallic
refractive =
opticalprop =
birefringence =
pleochroism =
streak = Grey, Grey green to black
gravity =
density = 9.7 g/cm3
melt =
fusibility =
diagnostic =
solubility =
diaphaneity = Translucent on thin edges
other =
var1Thorianite is a rare mineral, [Cite book
publisher = United States Government Printing Office
last = Frondel
first = C.
title = Systematic Mineralogy of Uranium and Thorium
date = 1958] originally discovered byAnanda Coomaraswamy in 1904 as uraninite, [Cite journal
volume = Pt. 6
issue = 2
pages = 57
last = Coomaraswamy
first = A.K.
title = Uraninite
journal = Spolia Zeylanica
date = 1904] but recognized as a new species byW. R. Dunston . [Cite journal
volume = 69
pages = 510–511
last = Dunston
first = W.R.
title = The occurrence of Thorium in Ceylon
journal = Nature
date = 1904-03-31
doi = 10.1038/069510d0] It was so named on account of its high percentage ofthorium (about 70% ThO2); it also contains the oxides ofuranium ,lanthanum ,cerium anddidymium (praseodymium andneodymium ).Helium is present, and the mineral is slightly lessradioactive thanpitchblende but harder to shield due its high energy gamma rays. It is relatively more common in thealluvial gem-gravels ofSri Lanka , where it occurs mostly as water worn, small, heavy, black, cubic crystals. The largest crystals (sizes usually up to around 1.5 cm; very rare are sizes greater than 2.5 cm; largest is 6 cm and 2.2 kilos) came fromMadagascar .Chemistry
Based on color, specific gravity and composition three types of thorianite are distinguished: [Cite journal
volume = 1
issue = Ist Ser
pages = 201–206
last = Kobayashi
first = M.
title = On the composition of thorianite
journal = Tohuku Imp. Univ. Sci. Repts.
date = 1912]
*α - thorianite
*β - thorianite
*γ - thorianiteThorianite anduraninite form a completesolid solution series in synthetic and natural material. [Cite journal
volume = 1
pages = 478–480
last = Palache
first = C.
coauthors = H. Berman, C. Frondel
title = Dana's System of Mineralogy
journal = John Wiley and Sons, New York
date = 1944] The division between the two species is at Th:U = 1:1 with U up to 46.50% and Th 45.3% to 87.9%. [Cite book
publisher = McGraw-Hill
last = Heinrich
first = E. W.
title = Mineralogy and Geology of Radioactive Raw Materials
date = 1958]Rare earths , chiefly Ce, substitute for Th in amounts up to 8% by weight. [Cite journal
volume = 1
pages = 478–480
last = Palache
first = C.
coauthors = H. Berman, C. Frondel
title = Dana's System of Mineralogy
journal = John Wiley and Sons, New York
date = 1944] [Cite journal
volume = 40
last = Graham
first = A. R.
title = CERIANITE CeO2: A NEW RARE-EARTH OXIDE MINERAL
journal = Am. Mineralogist
date = 1955] Ce is probably present as Ce4+. Complete series is known in synthetic material between CeO2 - PrO2 - ThO2 - UO2. Small amounts of Fe3+ and Zr also may be isomorphous with Th. Pb present is probably radiogenic.Varieties
*"Aldanite" - a variety of thorianite containing 14.9% to 29.0% UO2 and 11.2% to 12.5% PbO. [Cite journal
volume = II
issue = 6
pages = 105–107
last = Bespalov
first = M.M.
title = On discovery of a new mineral of the thorianite group [in Russian]
journal = Sovietskaya Geologiya
date = 1941]
*"Uranothorianite" [Cite web
title = Uranothorianite mineral information and data
accessdate = 2007-06-28
url = http://www.mindat.org/min-4114.html]
*"Thorianite Cerian"Cite web
title = Minerals with crystal structure determined
accessdate = 2007-06-27
url = http://sdpd.univ-lemans.fr/minknown.html#T] [Cite web
title = ICSD for WWW : Details (Thorianite Cerian)
accessdate = 2007-06-27
url = http://icsdweb.fiz-karlsruhe.de/details.php?id%5B%5D=24439&PHPSESSID=734118bb8]
*"Thorianite La bearing"Occurrence
Usually found in alluvial deposits, beach sands heavy mineral placers and
pegmatites .*Sri Lanka - In stream gravels,
Galle district, Southern Province;Balangonda district; nearKodrugala ,S'abaragamuwa Province; and from a pegmatite inBambarabotuwa area.
*India - Reported from beach sands ofTravancore (Kerala ). [Cite journal
volume = 88
pages = 282
last = Viswanathan
first = P.
title = Thorianite in Travancore
journal = Mineralog. Mag.
date = 1953]
*Madagascar - Found in alluvial deposits ofBetroka andAndolobe . [Cite book
publisher = Augustin Challamel, éditeur, Librairie maritime et coloniale
last = Lacroix
first = A.
title = Minéralogie de Madagascar
date = 1923] Also as very large crystals from Tôlanaro (Fort Dauphin); atAndranondambo and other localities.
*Russia - In black sands of a gold placer onBoshogoch River ,Transbaikalia ,Siberia ; in theKovdor massif,Kola Peninsula ; in theYenisei Range , Siberia.
*United States - reported from Easton,Pennsylvania ; black sands inMissouri River , near Helena,Montana ;Scott River , Siskiyou County,California ; [Cite journal
pages = 198
last = George
first = D'Arcy
title = Mineralogy of Uranium and Thorium Bearing Minerals
journal = USAEC Technical Information Service, Oak Ridge, Tennessee
series = RMO-563
date = 1949] black sands in Nixon Fork and Wiseman districts,Alaska . [Cite book
publisher = GS-C-195, Geological Survey
last = White
first = M. G.
title = Radioactivity of Selected Rocks and Placer Concentrates from Northeastern Alaska
date = 1952] [Cite journal
publisher = TEI-192, Geological Survey
last = White
first = M. G.
coauthors = J. M. Stevens
title = Reconnaissance For Radioactive Deposits In The Ruby-Poorman District, Ruby Quadrangle, Central Alaska,1949
date = 1953]
*Canada - Reported with uraninite in a pegmatite onCharlebois Lake , east ofLake Athabasca ; [Cite book
publisher = Geological Survey of Canada
last = Lang
first = A. H.
coauthors = J. W. Griffith, H. R. Steacy
title = Canadian Deposits of Uranium and Thorium
date = 1962] Uranon variety reported frompegmatite and metesomatized zones in crystalline limestones from many locations inQuebec andOntario . [Cite journal
volume = 40
last = Robinson
first = S. C.
coauthors = A. P. Sabina
title = Uraninite And Thorianite From Ontario And Quebec
journal = Am. Mineralogist
date = 1955]
*South Africa - Occurs withbaddeleyite as an accessory incarbonatite atPhalaborwa ,Eastern Transvaal . [Cite journal
volume = 40
pages = 275–282
last = Hiemstra
first = S. A.
title = Baddeleyite from Phalaborwa, Eastern Transvaal
journal = American Mineralogist
date = 1955]
*Belgian Congo [Cite journal
volume = 40
pages = C177
last = Ledoux
first = A.
title = Les roches cristallines du Kasai
journal = Soc. Geol. Belgique Annales]ee also
*
Uraninite
*Thorite External links
* [http://www.uraniumminerals.com/UTh/Thorianite.htm Uraniumminerals.com]
* [http://www.mindat.org/min-3944.html Mindat.org]References
*1911
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