Wiswesser's rule

Wiswesser's rule

The Wiswesser rule gives a simple method to determine the energetic sequence of the atomic subshells (n,l). n is the principal quantum number and l is the azimuthal quantum number. The energetic sequence of the subshells characterized by the quantum numbers (n,l) is the sequence that leads to a monotonous increasing row of function values for the Wiswesser-function.

:W(n,l)=n+l-left ( frac{l}{l+1} ight )

For example: if n=2 and l=1, this correspondents with an 2p-orbital.

The results are : 1s, 2s, 2p, 3s, 3p, 4s, 3d, 4p, 5s, 4d, 5p, 6s, 4f, 5d, 6p, 7s, 5f, 6d, 7p,...

ee also

*Atomic orbital energy


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