Glucal

Glucal

Chembox new
Reference= [ [http://www.sigmaaldrich.com/catalog/search/ProductDetail/ALDRICH/464058 Glucal] at Sigma-Aldrich]
ImageFile=Glucal.pngImageSize=120px
IUPACName=("2R,3S,4R")-2-(Hydroxymethyl)-3,4-dihydro-2H-pyran-3,4-diol
OtherNames=
Section1= Chembox Identifiers
CASNo=13265-84-4
PubChem=2734736
SMILES=C1=COC(C(C1O)O)CO
Section2= Chembox Properties
Formula=C6H10O4
MolarMass=146.1412
Appearance=
Density=
MeltingPt=58-60 °C
BoilingPt=
Solubility=
Section3= Chembox Hazards
MainHazards=
FlashPt=
Autoignition=
SPhrases=S22 S24/25

Glucal is the glycal formed from glucose. It is a chemical intermediate in the synthesis of a variety of oligosaccharides. [Seeberger, P.H., et al. "Aldrichimica Acta" 30, 75, (1997)]

Glucal and its derivatives can be converted to other chemically useful sugars using the Ferrier rearrangement.

References


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Look at other dictionaries:

  • Glucal — Nombre IUPAC (2R,3S,4R) 2 (Hidroximetil) 3,4 dihidro 2H pirano 3,4 diol Otros nombres 1,5 Anhidro 2 desoxi D arabino hexa 1 enitol …   Wikipedia Español

  • glucal — noun The glycal derived from glucose …   Wiktionary

  • glucal — SYN: glycal. * * * glu·cal (glooґkal) a glycal of glucose …   Medical dictionary

  • Ferrier rearrangement — The Ferrier rearrangement is an organic reaction that involves a nucleophilic substitution reaction combined with an allylic shift in a 2,3 Unsaturated glycoside (see glycals).In this example of a Ferrier rearrangement tri O acetyl D glucal (OAc… …   Wikipedia

  • Glical — Estructura del glucal, la forma glical proveniente de la glucosa. El glical es la denominación dada a todos aquellos derivados enol y éter de azúcares cíclicos que presentan un doble enlace entre los átomos de carbono 1 y 2 del anillo. El nombre… …   Wikipedia Español

  • TAG — Contracción de 3,4,6 tri O acetil D glucal. Diccionario Mosby Medicina, Enfermería y Ciencias de la Salud, Ediciones Hancourt, S.A. 1999 …   Diccionario médico

  • glycal — An unsaturated sugar derivative in which the adjacent hydroxyl groups are removed, one of which is that upon the carbon 1 of the aldose (or carbon 2 of the ketose), yielding a CH=CH between these two positions. SYN: glucal. * * * gly·cal… …   Medical dictionary

  • -αλη — Χημ. κατάληξη οργανικών ενώσεων που περιέχουν αλδεϋδομάδα ( CH = Ο) στο μόριό τους. [ΕΤΥΜΟΛ. Ξενικής προελεύσεως κατάληξη, με την οποία σχηματίζονται στην επιστημονική ορολογία όροι χημικών συστατικών, σύνθετων με αλδεΰδες, απ όπου αποσπάστηκε το …   Dictionary of Greek

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