Bromoiodomethane

Bromoiodomethane

Chembox new
ImageFile = Bromoiodomethane.png ImageSize = 120px
IUPACName = Bromoiodomethane
OtherNames = Bromo(iodo)methane, Bromomethyl iodide, Iodobromomethane
Section1 = Chembox Identifiers
CASNo = 557-68-6
PubChem = 68407
SMILES = C(Br)I
InChI = 1/CH2BrI/c2-1-3/h1H2

Section2 = Chembox Properties
Formula = CH2BrI
MolarMass = 220.84 g/mol
Appearance = Liquid
Density = 2.926 g/cm3 at 17 °C
MeltingPt = 1 °C
BoilingPt = 139.5 °C
Solubility =

Section3 = Chembox Hazards
EUClass = Irritant (Xi)
MainHazards =
FlashPt =
Autoignition =
RPhrases = R37/38 R41
SPhrases = S26 S36/39

Bromoiodomethane is a liquid mixed halomethane very soluble in chloroform.

Its critical point is at 367.85 °C and 6.3 MPa and refractive index is 1.6382 (20 °C, D).

See also

* Haloalkane
* Halomethane
* Bromomethane
* Iodomethane
* Dibromomethane
* Diiodomethane

References

*cite journal | author = Tarnovsky A. N., Wall M., Gustafsson M., Lascoux N., Sundström V., Åkesson E. | date = March 2002 | title = Ultrafast Study of the Photodissociation of Bromoiodomethane in Acetonitrile upon 266 nm Excitation | journal = J. Phys. Chem. A | volume = 106 | issue = 25 | pages = 5999–6005(7) | pmid = | doi = 10.1021/jp014306j | url = http://pubs.acs.org/cgi-bin/abstract.cgi/jpcafh/2002/106/i25/abs/jp014306j.html | accessdate = 2007-06-29
*cite journal | author = Liu Y.-J., Ajitha D., Krogh J. W., Tarnovsky A. N., Lindh R. | date = December 2005 | title = Spin-Orbit Ab Initio Investigation of the Photolysis of Bromoiodomethane | journal = ChemPhysChem | volume = 7 | issue = 4 | pages = 955–963(9) | pmid = 16596616 | doi = 10.1002/cphc.200500654 | url = http://www3.interscience.wiley.com/cgi-bin/abstract/112580100/ABSTRACT?CRETRY=1&SRETRY=0 | accessdate = 2007-06-29
*cite journal | author = Zheng, X.; Phillips, D. L. | date = August 2000 | title = Photoisomerization reaction of CH2BrI following A-band and B-band photoexcitation in the solution phase: Transient resonance Raman observation of the iso-CH2I-Br photoproduct | journal = J. Chem. Phys. | volume = 113 | issue = 8 | pages = 3194–3203(10) | pmid = | doi = 10.1063/1.1286920 | url = http://adsabs.harvard.edu/abs/2000JChPh.113.3194Z | accessdate = 2007-06-29
*cite journal | author = Liu K., Zhao H., Wang C., Zhang A., Ma S., Li Z. | date = January 2005 | title = A theoretical study of bond selective photochemistry in CH2BrI | journal = J. Chem. Phys. | volume = 122 | issue = | pages = | pmid = | doi = 10.1063/1.1835955 | url = http://scitation.aip.org/getabs/servlet/GetabsServlet?prog=normal&id=JCPSA6000122000004044310000001&idtype=cvips&gifs=yes | accessdate = 2007-06-29

External links

* [http://www.atmosphere.mpg.de/enid/0,aa609a5350454b5452554d5f7375626b6174092d09496f646f616c6b616e6573253238432532434825324346253243436c253243427225324349253239093a095350454b5452554d5f6b6174092d0948616c6f67656e6f2d616c6b616e65732532432b2d616c6b796c2b7261646963616c73093a095350454b5452554d5f73746f66666e616d65092d0962726f6d6f696f646f6d657468616e65093a095f7472636964092d093531363935/Spectra/Catalogue_5p4.html UV Spectra data]


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