Baudisch reaction

Baudisch reaction

The Baudisch Reaction was discovered by Baudish in 1939 and further developed by Cronheim. In the reaction a solution containing aqueous hydroxylamine hydrochloride and hydrogen peroxide reacts with benzene or phenol, with the assistance of a copper(II) ion to give "o"-nitrosophenols. [ [http://pubs.acs.org/cgi-bin/abstract.cgi/joceah/1967/32/i08/f-pdf/f_jo01283a033.pdf Maruyama et al., J. Org. Chem. ] 32, 2516, 2520 (1967)] These nitrosophenols can then be used in the manufacture of dyes. [ [http://www.britannica.com/eb/topic-174980/dye Encyclopædia Britannica] page on dyes]

References

Other References

*Baudisch et al., Naturwissenschaften 27, 768, 769 (1939)
*Baudisch et al.,Science 92, 336 (1940)
*Baudisch et al.,J. Am. Chem. Soc. 63, 622 (1941)
*G. Cronheim J. Org. Chem. 12, [http://pubs.acs.org/cgi-bin/abstract.cgi/joceah/1947/12/i01/f-pdf/f_jo01165a001.pdf 1] , [http://pubs.acs.org/cgi-bin/abstract.cgi/joceah/1947/12/i01/f-pdf/f_jo01165a002.pdf 7] , [http://pubs.acs.org/cgi-bin/abstract.cgi/joceah/1947/12/i01/f-pdf/f_jo01165a003.pdf 20] (1947)
*Konecny, J. Am. Chem. Soc. 77, 5748 (1955)
*Maruyama et al., Tettahedron Letters 1966, 5889.

External links

[http://www.chempensoftware.com/reactions/RXN042.htm Source of References]


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