Acylsilane

Acylsilane

Acylsilanes are a group of chemical compounds sharing a common functional group with the general structure R(CO)-SiR3. Acylsilanes are starting compounds in the Brook rearrangement with vinyl lithium compounds to silyl enol ethers Ref|Innocenti.

References

*Note|Innocenti "The reactivity of α- and β-iodo propenoylsilanes: an alternative access to polyunsaturated acylsilanes" Alessandro Degl’Innocenti, Antonella Capperucci, Patrizia Scafato,Antonella Telesca Arkivoc 0-005A 2000 [http://www.arkat-usa.org/ark/journal/2000/I04_General/0-005A/0051.asp Article]


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Look at other dictionaries:

  • acylsilane — noun Any acyl silane, of general formula R CO SiR …   Wiktionary

  • Brook rearrangement — The Brook rearrangement in organic chemistry is a rearrangement reaction in which a organosilyl group switches position with a hydroxyl proton over a carbon to oxygen covalent bond under the influence of a base [cite journal | author = A. G.… …   Wikipedia

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