Autoxidation is any oxidation that occurs in open air or in presence of oxygen and/or UV radiation and forms peroxides and hydroperoxides. A classic example of autoxidation is that of simple ethers like diethyl ether, whose peroxides can be dangerously explosive. It can be considered to be a slow, flameless combustion of materials by reaction with oxygen. Autoxidation is important because it is a useful reaction for converting compounds to oxygenated derivatives, and also because it occurs in situations where it is not desired (as in the destructive cracking of the rubber in automobile tires).

Although virtually all types of organic materials can undergo air oxidation, certain types are particularly prone to autoxidation, including unsaturated compounds that have allylic hydrogens or benzylic hydrogens; these materials are converted to hydroperoxides by autoxidation.

Autoxidation is a free radical chain process. Such reactions can be divided into three stages: chain initation, propagation, and termination. In the initiation process, some event causes free radicals to be formed. For example, free radicals can be produced purposefully by the decomposition of a radical initiator, such as benzoyl peroxide. In some cases, initiation occurs by a process that is not well understood but is thought to be the spontaneous reaction of oxygen with a material with a readily abstractable hydrogen. Destructive autoxidation processes also are initiated by pollutants such as those in smog.

Once free radicals are formed, they react in a chain to convert the material to a hydroperoxide. The chain is ended by termination reactions in which free radicals collide and combine their odd electrons to form a new bond.

Autoxidation is a process of enormous economic impact, since all foods, plastics, gasolines, oils, rubber, and other materials that must be exposed to air undergo continuous destructive reactions of this type. All plastics and rubber and most processed foods contain antioxidants to protect them against the attack of oxygen.

Autoxidations in industry

In the chemical industry many chemicals are produced by autoxidation:
* in the cumene process phenol and acetone are made from benzene and propylene
* the autoxidation of cyclohexane yields cyclohexanol and cyclohexanone
* "p"-xylene is oxidized to terephthalic acid
* ethylbenzene is oxidized to ethylbenzene hydroperoxide, an epoxidizing agent in the propylene oxide/styrene process POSM.

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Look at other dictionaries:

  • Autoxidation — bezeichnet eine Oxidation durch Luftsauerstoff. Die Autoxidation verläuft sehr langsam und ohne merkliche Wärmeentwicklung oder Flammenerscheinung, im Gegensatz zur Verbrennung. Dabei werden aus Kohlenwasserstoffen zunächst Hydroperoxide gebildet …   Deutsch Wikipedia

  • autoxidation — [ô täks΄ə dā′shən] n. [ AUT(O) + OXIDATION] Chem. the oxidation of a substance by its exposure to air autoxidative [ô täks′ə dā΄tiv] adj …   English World dictionary

  • Autoxidation — Aut|oxi|da|ti|on 〈f. 20; Chem.〉 Oxidation eines Stoffes (Akzeptors) mithilfe eines anderen Stoffes (Autoxidators), der leicht mit Sauerstoff reagiert u. diesen Sauerstoff auf den ersten überträgt, der für sich allein mit Sauerstoff nicht… …   Universal-Lexikon

  • autoxidation — SYN: auto oxidation. * * * au·tox·i·da·tion ȯ .täk sə dā shən also au·to ox·i·da·tion .ȯt ō .äk sə dā shən n oxidation by direct combination with oxygen (as in air) at ordinary temperatures <the rancidity of fats and oils is caused by… …   Medical dictionary

  • autoxidation — noun Date: 1883 oxidation by direct combination with oxygen (as in air) at ordinary temperatures …   New Collegiate Dictionary

  • autoxidation — /aw tok si day sheuhn/, n. Chem. 1. the oxidation of a compound by exposure to air. 2. an oxidation reaction in which another substance, in addition to air and the compound being oxidized, must be present. Also, autooxidation. [AUT + OXIDATION] * …   Universalium

  • Autoxidation — Самоокисление …   Краткий толковый словарь по полиграфии

  • Autoxidation — Aut|o|xi|da|ti|on 〈f.; Gen.: , Pl.: en〉 durch Einwirkung von Luftsauerstoff bei nur wenig erhöhten Temperaturen ablaufende Oxidationsvorgänge in manchen Stoffen, z. B. das Rosten von Eisen od. das Vermodern organischer Stoffe [Etym.: <Auto… +… …   Lexikalische Deutsches Wörterbuch

  • Autoxidation — Aut|oxi|da|ti|on*, auch Autoxydation die; , en <zu ↑auto... u. ↑Oxidation> nur unter ↑katalytischer Mitwirkung sauerstoffreicher Verbindungen erfolgende ↑Oxidation eines Stoffes (z. B. Rosten, Vermodern; Chem.) …   Das große Fremdwörterbuch

  • autoxidation — n. self oxidation (Chemistry) …   English contemporary dictionary

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