Anharmonicity is the deviation of a system from being a
harmonic oscillator. An oscillator that is not oscillating in simple harmonic motionis known as an anharmonic oscillator where the system can be approximated to a harmonic oscillator and the anharmonicity can be calculated using perturbation theory. If the anharmonicity is large then other numerical techniques have to be used.
A generalized version of harmonic oscillator in which the relationship between force and displacement is nonlinear. The harmonic oscillator is a highly idealized system that oscillates with a single frequency, irrespective of the amount of pumping or energy injected into the system. Consequently, the harmonic oscillator's fundamental frequency of vibration is independent of the amplitude of the vibrations. Applications of the harmonic oscillator model abound in various fields, but perhaps the most commonly studied system is the Hooke's law mass-spring system. In the Hooke's law system the restoring force exerted on the mass is proportional to the displacement of the mass from its equilibrium position. This linear relationship between force and displacement mandates that the oscillation frequency of the mass will be independent of the amplitude of the displacement.
In a mechanical anharmonic oscillator, the relationship between force and displacement is not linear but depends upon the amplitude of the displacement. The nonlinearity arises from the fact that the spring is not capable of exerting a restoring force that is proportional to its displacement because of, for example, stretching in the material comprising the spring. As a result of the nonlinearity, the vibration frequency can change, depending upon the system's displacement. These changes in the vibration frequency result in energy being coupled from the fundamental vibration frequency to other frequencies through a process known as parametric coupling. .
There are many systems throughout the physical world that can be modeled as anharmonic oscillators in addition to the nonlinear mass-spring system. For example, an atom, which consists of a positively charged nucleus surrounded by a negatively charged electronic cloud, experiences a displacement between the center of mass of the nucleus and the electronic cloud when an electric field is present. The amount of that displacement, called the electric dipole moment, is related linearly to the applied field for small fields, but as the magnitude of the field is increased, the field-dipole moment relationship becomes nonlinear, just as in the mechanical system.
Further examples of anharmonic oscillators include the large-angle pendulum, which exhibits chaotic behavior as a result of its anharmonicity; nonequilibrium semiconductors that possess a large hot carrier population, which exhibit nonlinear behaviors of various types related to the effective mass of the carriers; and ionospheric plasmas, which also exhibit nonlinear behavior based on the anharmonicity of the plasma. In fact, virtually all oscillators become anharmonic when their pump amplitude increases beyond some threshold, and as a result it is necessary to use nonlinear equations of motion to describe their behavior.
Anharmonicity plays a role in lattice and molecular vibrations, in quantum oscillations [http://jchemed.chem.wisc.edu/Journal/issues/2005/Aug/abs1263_2.html] , and in
Quantum harmonic oscillator
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