Bromoacetic acid

Bromoacetic acid
Bromoacetic acid
Identifiers
CAS number 79-08-3 YesY
PubChem 6227
EC number 201-175-8
ChEMBL CHEMBL60851 YesY
RTECS number AF5950000
Beilstein Reference 506167
Jmol-3D images Image 1
Properties
Molecular formula C2H3BrO2
Molar mass 138.95 g mol−1
Appearance White to light yellow crystalline solid
Density 1.934 g/mL
Melting point

49 - 51 °C

Boiling point

206 - 208 °C

Solubility in water polar organic solvents
Acidity (pKa) 2.86[1]
Refractive index (nD) 1.4804 (50 °C, D)
Structure
Crystal structure Hexagonal or orthorhombic
Hazards
R-phrases R23/24/25, R36
S-phrases S36/37/39, S45
Main hazards Toxic (T), Corrosive {C)
NFPA 704
NFPA 704.svg
1
3
0
Flash point 110 °C
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Infobox references

Bromoacetic acid is the chemical compound with the formula CH2BrCO2H. This colorless solid is a relatively strong alkylating agent. Bromoacetic acid and its esters are widely used building blocks in organic synthesis, for example in pharmaceutical chemistry.

The compound is prepared by bromination of acetic acid.[2]

CH3CO2H + Br2 → CH2BrCO2H + HBr

See also

References

  1. ^ Dippy, J.F.J., Hughes, S.R.C., Rozanski, A., J. Chem Soc., 1959, 2492.
  2. ^ Natelson, S.; Gottfried, S. (1955), "Ethyl Bromoacetate", Org. Synth., http://www.orgsyn.org/orgsyn/orgsyn/prepContent.asp?prep=cv3p0381 ; Coll. Vol. 3: 381 

External links


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